Citation: Fan JIA, Wenbao XU, Fangbin LIU, Haihua ZHANG, Hongbing FU. Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473 shu

Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄

Fan JIA ^{1, #} ,
Wenbao XU ^{2, #} ,
Fangbin LIU ^1,, ,
Haihua ZHANG ^2,, ,
Hongbing FU ^{2, 3,,}

1.
School of Chemical and Environmental Engineering, Changchun University of Science and Technology, Changchun 130000, China
2.
Institute of Molecular Plus, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin University, Tianjin 300072, China
3.
Beijing Key Laboratory for Optical Materials and Photonic Devices, Department of Chemistry, Capital Normal University, Beijing 100048, China

Corresponding author: Fangbin LIU, liufangbin@cust.edu.cn Haihua ZHANG, zhanghaihua@tju.edu.cn Hongbing FU, hbfu@cnu.edu.cn
Received Date: 17 December 2023
Revised Date: 25 March 2024

Figures(6)

Mn²⁺-doped quasi-two-dimensional perovskite (PEA)₂Pb_yMn_1-yBr₄ (PEA is phenylethylamine, y is the fraction of Pb²⁺ in the total content of Mn²⁺ and Pb²⁺) thin films were prepared successfully with high photoluminescence quantum yield (PLQY). It constructed a dual-emissive excited state transfer system, while (PEA)₂PbBr₄ and impurity Mn²⁺ respectively act as the donor and acceptor. Mn²⁺ incorporation improved the luminescence properties and film morphologies. Using the femtosecond transient absorption (TA) measurement, we demonstrated the charge transfer processes between the host and the guest. To study the electroluminescence properties, (PEA)₂Pb_yMn_1-yBr₄ film was employed as the active layer to fabricate LED (light emitting diodes, LEDs) devices. The (PEA)₂Pb_yMn_1-yBr₄ LED device emitted a bright orange color, which demonstrated a maximum luminous intensity of 0.21 cd·m^-2 with an external quantum efficiency (EQE) of 0.002 5%.
- metal halide perovskite,
- doping,
- charge transfer,
- luminescence material,
- electroluminescence
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Synthesis and electroluminescence properties of Mn2+ doped quasi-two-dimensional perovskites (PEA)2PbyMn1-yBr4

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Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄