Citation: Wenlong LI, Xinyu JIA, Jie LING, Mengdan MA, Anning ZHOU. Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421 shu

Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst

Wenlong LI ¹ ,
Xinyu JIA ^1,, ,
Jie LING ¹ ,
Mengdan MA ¹ ,
Anning ZHOU ^{1, 2,,}

1.
College of Chemistry & Chemical Engineering, Xi′an University of Science and Technology, Xi′an 710054, China
2.
Key Laboratory of Coal Resources Exploration and Comprehensive Utilization, Ministry of Natural Resources, Xi′an, Shaanxi 710054, China

Corresponding author: Xinyu JIA, xinyu25@xust.edu.cn Anning ZHOU, psu@139.com
Received Date: 4 November 2023
Revised Date: 19 January 2024

Figures(7)

To improve the catalytic activity of the photothermal CO₂ hydrogenation In₂O₃ catalyst, a Mg(OH)₂-In(OH)₃ precursor was prepared by the homogeneous hydrothermal method, and a Mg-doped In₂O_3-x (Mg-In₂O_3-x) catalyst enriched with oxygen vacancies was obtained by the following high-temperature calcination and H₂-reducing treatment. The catalyst was evaluated for its photothermal catalytic performance of CO₂ hydrogenation in a photothermal fixed -bed reactor. The results demonstrated that Mg-In₂O_3-x achieved an impressive CO₂ conversion rate of 31.20% with a CO production rate of 14.22 mmol·g_cat^-1·h^-1 and selectivity of 100% in the light reaction at 300 ℃. The characterization results confirmed that the Mg doping into the In₂O₃ lattice promotes the formation of more surface oxygen vacancies, which dramatically increases the response efficiency to visible light and slows down the recombination of photogenerated electron-hole. This is the main reason for the enhancement of the photothermal catalytic performance.
- indium oxide,
- photothermal catalysis,
- CO₂ hydrogenation,
- doping,
- oxygen vacancy
1. [1]
  Li Y G, Hao J C, Song H, Zhang F Y, Bai X H, Meng X G, Zhang H Y, Wang S F, Hu Y, Ye J H. Selective light absorber-assisted single nickel atom catalysts for ambient sunlight-driven CO₂ methanation[J]. Nat. Commun., 2019,10(1):4359-4368. doi: 10.1038/s41467-019-12328-w
2. [2]
  XU L M, HUANG H B, SHEN J H, YOU Q H. Synthesis of Zn-doped BiOBr with enhanced photoreduction CO₂ activity under visible light irradiation[J]. Chinese J. Inorg. Chem., 2020,36(12):2395-2403. doi: 10.11862/CJIC.2020.262
3. [3]
  Merkel T C, Lin H Q, Wei X T, Baker R. Power plant post-combustion carbon dioxide capture: An opportunity for membranes[J]. J. Membr. Sci., 2010,359(1/2):126-139.
4. [4]
  Assima G P, Larachi F, Molson J, Beaudong G. Comparative study of five Québec ultramafic mining residues for use in direct ambient carbon dioxide mineral sequestration[J]. Chem. Eng. J., 2014,245:56-64. doi: 10.1016/j.cej.2014.02.010
5. [5]
  Ling J, Zhou A N, Wang W Z, Jia X Y, Ma M D, Li Y Z. One-pot method synthesis of bimetallic MgCu-MOF-74 and its CO₂ adsorption under visible light[J]. ACS Omega, 2022,7(23):19920-19929. doi: 10.1021/acsomega.2c01717
6. [6]
  Wang L, Ghoussoub M, Wang H, Shao Y, Sun W, Tountas A A, Wood T E, Li H, Loh J Y Y, Dong Y C, Xia M K, Li Y, Wang S H, Jia J, Qiu C Y, Qian C X, Kherani N P, He L, Zhang X H, Ozin G A. Photocatalytic hydrogenation of carbon dioxide with high selectivity to methanol at atmospheric pressure[J]. Joule, 2018,2(7):1369-1381. doi: 10.1016/j.joule.2018.03.007
7. [7]
  DONG Y A, FENG Z, ZHU D R. Syntheses of two Mg-based metalorganic frameworks by a coordination competitive strategy and the selective CO₂ capture[J]. Chinese J. Inorg. Chem., 2023,39(1):181-190.
8. [8]
  Lingampalli S R, Ayyub M M, Rao C N R. Recent progress in the photocatalytic reduction of carbon dioxide[J]. ACS Omega, 2017,2(6):2740-2748. doi: 10.1021/acsomega.7b00721
9. [9]
  Ameta R, Panchal S, Ameta N, Ameta S C. Photocatalytic reduction of carbon dioxide[J]. Mater. Sci. Forum, 2013,764:83-96. doi: 10.4028/www.scientific.net/MSF.764.83
10. [10]
  DUAN F Y, ZHOU A N, CHEN F X, LING J, MA M D, JIA X Y. Controllable preparation and photocatalytic performance of graphitic carbon nitride nanosheets[J]. Journal of the Chinese Ceramic Society, 2021,49(10):2053-2060.
11. [11]
  MA M D, ZHOU A N, DUAN F Y, JIA X Y, LING J. Preparation of Ti₁Li₃Al₂-LDHs/g-C₃N₄ composites and its photocatalytic properties in CO₂-toluene reaction system[J]. Acta Materiae Compositae Sinica, 2023,40(3):1522-1533.
12. [12]
  XU L L, ZHOU M T, YANG A L, WANG J X, ZHOU T F, ZHANG Y. Preparation of dumbbell-like magnetic gold mesoporous silicon microspheres and determination of magnetic/photo thermo and catalytic performance[J]. Chinese J. Inorg. Chem., 2019,35(6):971-977.
13. [13]
  Li Z H, Liu J J, Zhao Y F, Shi R, Waterhouse G I N, Wang Y S, Wu L Z, Tung C H, Zhang T R. Photothermal hydrocarbon synthesis using alumina-supported cobalt metal nanoparticle catalysts derived from layered-double-hydroxide nanosheets[J]. Nano Energy, 2019,60:467-475. doi: 10.1016/j.nanoen.2019.03.069
14. [14]
  Wang J C, Qiao X, Shi W N, Gao H L, Guo L C. Enhanced photothermal selective conversion of CO₂ to CH₄ in water vapor over rod-like Cu and N co-doped TiO₂[J]. Chin. J. Struct. Chem., 2022,41(12):33-42.
15. [15]
  Deng B W, Song H, Wang Q, Hong J N, Song S, Zhang Y W, Peng K, Zhang H W, Kako T, Ye J H. Highly efficient and stable photothermal catalytic CO₂ hydrogenation to methanol over Ru/In₂O₃ under atmospheric pressure[J]. Appl. Catal. B-Environ., 2023,327122471. doi: 10.1016/j.apcatb.2023.122471
16. [16]
  Qi Y H, Song L Z, Ouyang S X, Liang X C, Ning S B, Zhang Q Q, Ye J H. Photoinduced defect engineering: Enhanced photothermal catalytic performance of 2D Black In₂O_3-x nanosheets with bifunctional oxygen vacancies[J]. Adv. Mater., 2019,32(6)1903915.
17. [17]
  Wang S, Wang P F, Qin Z F, Yan W J, Dong M, Li J F, Wang J G, Fan W B. Enhancement of light olefin production in CO₂ hydrogenation over In₂O₃-based oxide and SAPO-34 composite[J]. J. Catal., 2020,391:459-470. doi: 10.1016/j.jcat.2020.09.010
18. [18]
  Qin B, Zhou Z M, Li S G, Gao P. Understanding the structure-performance relationship of cubic In₂O₃ catalysts for CO₂ hydrogenation[J]. J. CO2 Util., 2021,49101543. doi: 10.1016/j.jcou.2021.101543
19. [19]
  Tao H C, Fan Q, Ma T, Liu S Z, Gysling H, Texter J, Guo F, Sun Z Y. Two-dimensional materials for energy conversion and storage[J]. Prog. Mater. Sci., 2020,111100637. doi: 10.1016/j.pmatsci.2020.100637
20. [20]
  Wang L, Dong Y C, Yan T J, Hu Z X, Ali F M, Meira D M, Duchesne P N, Loh J Y Y, Qiu C Y, Storey E E, Xu Y F, Sun W, Ghoussoub M, Kherani N P, Helmy A S, Ozin G A. Black indium oxide a photothermal CO₂ hydrogenation catalyst[J]. Nat. Commun., 2020,11(1)2432. doi: 10.1038/s41467-020-16336-z
21. [21]
  Yang Y X, Pan Y X, Tu X, Liu C J. Nitrogen doping of indium oxide for enhanced photocatalytic reduction of CO₂ to methanol[J]. Nano Energy, 2022,101107613. doi: 10.1016/j.nanoen.2022.107613
22. [22]
  Zhu X W, Yang J M, Zhu X L, Yuan J J, Zhou M, She X J, Yu Q, Song Y H, She Y B, Hua Y J, Li H M, Xu H. Exploring deep effects of atomic vacancies on activating CO₂ photoreduction via rationally designing indium oxide photocatalysts[J]. Chem. Eng. J., 2021,422129888. doi: 10.1016/j.cej.2021.129888
23. [23]
  Zheng M, Liu J N, Xiao X D, Wang H L, Jiang B J, Li Q, Liu M, Zhao C, Zhang L P, Zhou J. Creation of Mo active sites on indium oxide microrods for photocatalytic amino acid production[J]. Sci. China Mater., 2021,65(5):1285-1293.
24. [24]
  Sil A, Deck M J, Goldfine E A, Zhang C, Patel S V, Flynn S, Liu H Y, Chien P H, Poeppelmeier K R, Dravid V P, Bedzyk M J, Medvedeva J E, Hu Y Y, Facchetti A, Marks T J. Fluoride doping in crystalline and amorphous indium oxide semiconductors[J]. Chem. Mat., 2022,34(7):3253-3266. doi: 10.1021/acs.chemmater.2c00053
25. [25]
  YANG F F, ZHAO S X, ZHOU W, NI Z H. Sn doped In₂O₃ catalyst for selective hydrogenation of CO₂ to methanol[J]. CIESC J., 2023,74(6):3366-3374.
26. [26]
  Qi Y H, Jiang J W, Liang X C, Ouyang S X, Mi W B, Ning S B, Zhao L, Ye J H. Fabrication of black In₂O₃ with dense oxygen vacancy through dual functional carbon doping for enhancing photothermal CO₂ hydrogenation[J]. Adv. Funct. Mater., 2021,31(22)2100908. doi: 10.1002/adfm.202100908
27. [27]
  Das A, Liu D Y, Wary R R, Vasenko A S, Prezhdo O V, Nair R G. Enhancement of photocatalytic and photoelectrochemical performance of ZnO by Mg doping: Experimental and density functional theory insights[J]. J. Phys. Chem. Lett., 2023,14(18):4134-4141. doi: 10.1021/acs.jpclett.3c00736
28. [28]
  Wang J, Sun K Y, Jia X Y, Liu C J. CO₂ hydrogenation to methanol over Rh/In₂O₃ catalyst[J]. Catal. Today, 2021,365:341-348. doi: 10.1016/j.cattod.2020.05.020
29. [29]
  Guo C F, Li L, Chen F, Ning J Q, Zhong Y J, Hu Y. One-step phosphorization preparation of gradient-P-doped CdS/CoP hybrid nanorods having multiple channel charge separation for photocatalytic reduction of water[J]. J. Colloid Interface Sci., 2021,596:431-441. doi: 10.1016/j.jcis.2021.03.170
30. [30]
  Li R, Sun L M, Zhan W W, Li Y A, Wang X J, Han X G. Engineering an effective noble-metal-free photocatalyst for hydrogen evolution: Hollow hexagonal porous micro-rods assembled from In₂O₃@carbon core-shell nanoparticles[J]. J. Mater. Chem. A, 2018,6(32):15747-15754. doi: 10.1039/C8TA04916E
31. [31]
  Shen C Y, Sun K H, Zhang Z T, Rui N, Jia X Y, Mei D H, Liu C J. Highly active Ir/In₂O₃ catalysts for selective hydrogenation of CO₂ to methanol: Experimental and theoretical studies[J]. ACS Catal., 2021,11(7):4036-4046. doi: 10.1021/acscatal.0c05628
32. [32]
  Fan Y J, Wu S F. A graphene-supported copper-based catalyst for the hydrogenation of carbon dioxide to form methanol[J]. J. CO2 Util., 2016,16:150-156. doi: 10.1016/j.jcou.2016.07.001
33. [33]
  Rui N, Wang Z Y, Sun K H, Ye J Y, Ge Q F, Liu C J. CO₂ hydrogenation to methanol over Pd/In₂O₃: effects of Pd and oxygen vacancy[J]. Appl. Catal. B-Environ., 2017,218:488-497. doi: 10.1016/j.apcatb.2017.06.069
34. [34]
  Jia X Y, Sun K H, Wang J, Shen C Y, Liu C J. Selective hydrogenation of CO₂ to methanol over Ni/In₂O₃ catalyst[J]. J. Energy Chem., 2020,50:409-415. doi: 10.1016/j.jechem.2020.03.083
35. [35]
  Yan T J, Li N, Wang L L, Ran W G, Duchesne P N, Wan L L, Nguyen N T, Wang L, Xia M K, Ozin G A. Bismuth atom tailoring of indium oxide surface frustrated Lewis pairs boosts heterogeneous CO₂ photocatalytic hydrogenation[J]. Nat. Commun., 2020,11(1)6095. doi: 10.1038/s41467-020-19997-y
36. [36]
  Chen Y, Li Y G, Luo N D, Shang W K, Shi S S, Li H J, Liang Y D, Zhou A N. Kinetic comparison of photocatalysis with H₂O₂-free photoFenton process on BiVO₄ and the effective antibiotic degradation[J]. Chem. Eng. J., 2022,429132577. doi: 10.1016/j.cej.2021.132577
37. [37]
  He L, Wood T E, Wu B, Dong Y C, Hoch L B, Reyes L M, Wang D, Kübel C, Qian C X, Jia J, Liao K, Brien P G O', Sandhel A, Loh J Y Y, Szymanski P, Kherani N P, Sum T C, Mims C A, Ozin G A. Spatial separation of charge carriers in In₂O_3-x(OH)_y nanocrystal superstructures for enhanced gas-phase photocatalytic activity[J]. ACS Nano, 2016,10(5):5578-5586. doi: 10.1021/acsnano.6b02346
38. [38]
  Li L, Guo C F, Shen J L, Ning J Q, Zhong Y J, Hu Y. Construction of sugar-gourd-shaped CdS/Co_1-xS hollow hetero-nanostructure as an efficient Z-scheme photocatalyst for hydrogen generation[J]. Chem. Eng. J., 2020,400125925. doi: 10.1016/j.cej.2020.125925
39. [39]
  Sayed M, Xu F Y, Kuang P Y, Low J X, Wang S Y, Zhang L Y, Yu J G. Sustained CO₂-photoreduction activity and high selectivity over Mn, C-codoped ZnO core-triple shell hollow spheres[J]. Nat. Commun., 2021,12(1)4936. doi: 10.1038/s41467-021-25007-6
40. [40]
  Su T M, Men C Z, Chen L Y, Chu B X, Luo X, Ji H B, Chen J H, Qin Z Z. Sulfur vacancy and Ti₃C₂T_x cocatalyst synergistically boosting interfacial charge transfer in 2D/2D Ti₃C₂T_x/ZnIn₂S₄ heterostructure for enhanced photocatalytic hydrogen evolution[J]. Adv. Sci., 2022,92103715. doi: 10.1002/advs.202103715
41. [41]
  Yu X Y, Chen Y J, Zhang Q Y, Yin Y J, Sun D, Ru Y X, Tian G H. Carbon and nitrogen co-doped In₂O₃ porous nanosheets with oxygen vacancies for remarkable photocatalytic CO₂ conversion[J]. Surf. Interfaces, 2023,38102789. doi: 10.1016/j.surfin.2023.102789
42. [42]
  Bai S, Zhang N, Gao C, Xiong Y J. Defect engineering in photocatalytic materials[J]. Nano Energy, 2018,53:296-336. doi: 10.1016/j.nanoen.2018.08.058
43. [43]
  Pan R R, Liu J, Zhang J T. Defect engineering in 2D photocatalytic materials for CO₂ reduction[J]. ChemNanoMat, 2021,7(7):737-747. doi: 10.1002/cnma.202100087
44. [44]
  Sun K H, Rui N, Zang Z T, Sun Z Y, Ge Q F, Liu C J. A highly active Pt/In₂O₃ catalyst for CO₂ hydrogenation to methanol with enhanced stability[J]. Green Chem., 2020,22(15):5059-5066. doi: 10.1039/D0GC01597K
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Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst