Citation: Ning LI, Siyu DU, Xueyi WANG, Hui YANG, Tao ZHOU, Zhimin GUAN, Peng FEI, Hongfang MA, Shang JIANG. Preparation and efficient catalysis for olefins epoxidation of a polyoxovanadate-based hybrid[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(4): 799-808. doi: 10.11862/CJIC.20230372 shu

Preparation and efficient catalysis for olefins epoxidation of a polyoxovanadate-based hybrid

School of Chemistry and Chemical Engineering, Shanxi Datong University, Datong, Shanxi 037009, China

Corresponding author: Ning LI, lin224@nenu.edu.cn Hui YANG, yanghui091900@126.com
Received Date: 9 October 2023
Revised Date: 9 October 2023

Figures(7)

A new polyoxovanadate compound [Co(pIM)V₂O₆] (1) was hydrothermally synthesized, where pIM stands for 2-(2-pyridyl)imidazole. For its characterizations, an integration of X-ray single crystal diffraction, powder X-ray diffraction, Fourier transform infrared spectra, and elemental analysis was accomplished. The compound exhibited a 2D architecture composed of VO₄ tetrahedra and CoO₃N₂ square pyramids via both edge - and corner - sharing. Considering the excellent catalytic oxidation features of polyoxovanadate, compound 1 was used as an efficient heterogeneous catalyst for the epoxidation of olefins with H₂O₂ as an oxidant, and could be reused without consuming activity. Besides, the magnetic studies indicated the antiferromagnetic interactions in 1.
- polyoxovanadate,
- heterogeneous catalysts,
- olefins epoxidation,
- magnetism
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