Citation: Shuwen SUN, Gaofeng WANG. Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368 shu

Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties

Shuwen SUN ,
Gaofeng WANG ^,

Department of Applied Chemistry, Yuncheng University, Yuncheng, Shanxi 044000, China

Corresponding author: Gaofeng WANG, wgf1979@126.com
Received Date: 8 October 2023
Revised Date: 18 December 2023

Figures(4)

Based on Ⅴ-shaped auxiliary ligands, two novel coordination polymers, {[Cd(bipmo)(NDC)]·1.75H₂O}_n (1), {[Cd(bppmo)(NDC)(H₂O)]·H₂O}_n (2), where H₂NDC=2,6-naphthalenedicarboxylic acid, bipmo=bis(4-(1H-imidazol-1-yl)phenyl)methanone, bppmo=bis(4-(pyridin-4-yl)phenyl)methanone, have been synthesized under solvothermal conditions. They have been characterized by single-crystal X-ray diffraction, bond valence sum calculations, IR spectra, and elemental analyses. Complex 1 shows 2-fold interpenetrating sheets of {6³} topology, which interpenetrate in a 2D → 2D parallel manner. Complex 2 reveals a 3-fold interpenetrating {6³} network. The results indicate that the Ⅴ-shaped ligands have a great effect on the formation of the final structures. In addition, the luminescent properties of complexes 1 and 2 were investigated in detail.
- bond valence sum,
- coordination polymer,
- Ⅴ-shaped ligand,
- topology,
- fluorescence
1. [1]
  Sengupta D, Melix P, Bose S, Duncan J, Wang X, Mian M. R, Kirlikovali K O, Joodaki F, Islamoglu T, Yildirim T, Snurr R Q, Farha O K. Air-stable Cu(Ⅰ)metal-organic framework for hydrogen storage[J]. J. Am. Chem. Soc., 2023,145:20492-20502. doi: 10.1021/jacs.3c06393
2. [2]
  Chen L, Tan K, Lan Y Q, Li S L, Shao K Z, Su Z M. Unusual microporous polycatenane-like metal-organic frameworks for the luminescent sensing of Ln³⁺ cations and rapid adsorption of iodine[J]. Chem. Commun., 2012,48:5919-5921. doi: 10.1039/c2cc31257c
3. [3]
  KANG X Q, WANG J H, GU J Z. Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), nickel(Ⅱ) and cobalt(Ⅱ) coordination polymers constructed from 4,4'-(pyridin-3,5-diyl)dibenzoic acid[J]. Chinese J. Inorg. Chem., 2023,39(12):2385-2392.
4. [4]
  WANG G F, SUN S W, SONG S F, LÜ M. Synthesis of a Cd(Ⅱ)-based coordination polymer for luminescence detecting 2,4,6-trinitrophenol[J]. Chinese J. Inorg. Chem., 2023,39(12):2407-2414.
5. [5]
  Ingram C.W, Liao L, Bacsa J, Harruna I, Sabo D, Zhang Z J. Novel layered 2D and triply interpenetrating 3D cobalt-functionalized diaza-12-crown based coordination polymers: Synthesis, structure, and magnetic properties[J]. Cryst. Growth Des., 2013,13:1131-1139. doi: 10.1021/cg301480s
6. [6]
  Rao K P, Higuchi M, Duan J, Kitagawa S. pH-dependent interpenetrated, polymorphic, Cd²⁺- and BTB-based porous coordination polymers with open metal sites[J]. Cryst. Growth Des., 2013,13:981-985. doi: 10.1021/cg301476p
7. [7]
  XIA Y P, WANG C X, ZHENG J Y, LI N, CHANG Z, BU X H. Construction of a Fe-MOF based on carbazole-carboxylate ligand for CO₂/CH₄ separation[J]. Chem. J. Chinese Universities, 2020,41(11):2415-2420.
8. [8]
  Zhang X T, Fan L M, Sun Z, Zhang W, Li D C, Dou J M, Han L. Syntheses, structures, and properties of a series of multidimensional metal-organic polymers based on 3, 3', 5, 5'-biphenyltetracarboxylic acid and N-donor ancillary ligands[J]. Cryst. Growth Des., 2013,13:792-803. doi: 10.1021/cg301502u
9. [9]
  Wang G F, Zhang X, Sun S W, Sun H, Yang X, Li H, Yao C Z, Sun S G, Tang Y P, Meng L X. Syntheses, crystal structures, and characterization of two Mn(Ⅱ) coordination polymers with bis(4-(1H-imidazol-1-yl)phenyl)methanone ligands[J]. Z. Naturforsch. B, 2016,71:869-874.
10. [10]
  Wang G F, Zhang X, Sun S W, Sun H, Li H, Ma H X, Tang Y P, Gao X N, Yang L. Two copper(Ⅱ) coordination polymers constructed by bis(4-(1H-imidazol-1-yl)phenyl)methanone and dicarboxylate ligands[J]. Z. Naturforsch. B, 2017,72:257-261. doi: 10.1515/znb-2016-0225
11. [11]
  CrysAlis^Pro, Version 1.171.35.19. Santa Clara (CA, USA): Agilent Technologies Inc., 2011.
12. [12]
  Sheldrick G M. SHELXL 2014/7, Program for crystal structure refinement. University of Gö ttingen, Germany, 2014.
13. [13]
  Sheldrick G M. A short history of SHELX[J]. Acta Crystallogr. Sect. A, 2008,A64:112-122.
14. [14]
  Braga D, Polito M, D'Addario D, Tagliavini E, Proserpio D M, Grepioni F, Steed J W. Design, synthesis, and structural characterization of molecular and supramolecular heterobimetallic metallamacrocycles based on the 1, 1'-bis(4-pyridyl)ferrocene (Fe(η⁵-C₅H₄-1-C₅H₄N)₂) ligand[J]. Organometallics, 2003,22:4532-4538. doi: 10.1021/om030432t
15. [15]
  Cheng P C, Kuo P T, Liao Y H, Xie M Y, Hsu W, Chen J D. Ligand-isomerism controlled structural diversity of Zn(Ⅱ) and Cd(Ⅱ) coordination polymers from mixed dipyridyladipoamide and benzenedicarboxylate ligands[J]. Cryst. Growth Des., 2013,13:623-632. doi: 10.1021/cg301311m
16. [16]
  Mu Y J, Ran Y G, Zhang B B, Du J L, Jiang C Y, Du J. Dicarboxylate ligands modulated structural diversity in the construction of Cd(Ⅱ) coordination polymers built from N-heterocyclic ligand: Synthesis, structures, and luminescent sensing[J]. Cryst. Growth Des., 2020,20:6030-6043. doi: 10.1021/acs.cgd.0c00739
17. [17]
  Sharma C V K, Broker G A, Huddleston , J G, Baldwin J W, Metzger R M, Rogers R D. Design strategies for solid-state supramolecular arrays containing both mixed-metalated and freebase porphyrins[J]. J. Am. Chem. Soc., 1999,121:1137-1144. doi: 10.1021/ja983983x
18. [18]
  Altermatt D, Brown I D. The automatic searching for chemical bonds in inorganic crystal structures[J]. Acta Crystallogr. Sect. B, 1985,B41:240-244.
19. [19]
  Brown I D. Bond valence parameters. https://www.iucr.org/__data/assets/file/0011/150779/bvparm2020.cif
20. [20]
  He X, Lu C Z, Yuan D Q. Two 3D porous cadmium tetrazolate frameworks with hexagonal tunnels[J]. Inorg. Chem., 2006,45:5760-5766. doi: 10.1021/ic0520162
21. [21]
  Ouellette W, Hudson B S, Zubieta J. Hydrothermal and structural chemistry of the zinc(Ⅱ)- and cadmium(Ⅱ)-1,2,4-triazolate systems[J]. Inorg. Chem., 2007,46:4887-4904. doi: 10.1021/ic062269a
22. [22]
  Shi X, Zhu G S, Fang Q R, Wu G, Tian G, Wang R W, Zhang D L, Xue M, Qiu S L. Novel supramolecular frameworks self-assembled from one-dimensional polymeric coordination chains[J]. Eur. J. Inorg. Chem., 2004:185-191.
23. [23]
  Wang X L, Zhao D, Tian A X, Ying J. A series of 3D PW₁₂O₄₀^3--based Ag^Ⅰ-bis(triazole) complexes containing different multinuclear loops: Syntheses, structures and properties[J]. CrystEngComm, 2013,15:4516-4526. doi: 10.1039/c3ce40375k
24. [24]
  Zhang S Q, Jiang F L, Wu M Y, Ma J, Bu Y, Hong M C. Assembly of discrete one-, two-, and three-dimensional Zn(Ⅱ) complexes containing semirigid Ⅴ-shaped tricarboxylate ligands[J]. Cryst. Growth Des., 2012,12:1452-1463. doi: 10.1021/cg201556b
1. [1]
  Dongdong YANG , Jianhua XUE , Yuanyu YANG , Meixia WU , Yujia BAI , Zongxuan WANG , Qi MA . Design and synthesis of two coordination polymers for the rapid detection of ciprofloxacin based on triphenylpolycarboxylic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2466-2474. doi: 10.11862/CJIC.20240266
2. [2]
  Jing REN , Ruikui YAN , Xiaoli CHEN , Huali CUI , Hua YANG , Jijiang WANG . Synthesis and fluorescence sensing of a highly sensitive and multi-response cadmium coordination polymer. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 574-586. doi: 10.11862/CJIC.20240287
3. [3]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
4. [4]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
5. [5]
  Zhenzhong MEI , Hongyu WANG , Xiuqi KANG , Yongliang SHAO , Jinzhong GU . Syntheses and catalytic performances of three coordination polymers with tetracarboxylate ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1795-1802. doi: 10.11862/CJIC.20240081
6. [6]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
7. [7]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273
8. [8]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
9. [9]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
10. [10]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
11. [11]
  Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1615-1621. doi: 10.11862/CJIC.20240134
12. [12]
  Junying LI , Xinyan CHEN , Xihui DIAO , Muhammad Yaseen , Chao CHEN , Hao WANG , Chuansong QI , Wei LI . Chiral fluorescent sensor Tb³⁺@Cd-CP based on camphoric acid for the enantioselective recognition of R- and S-propylene glycol. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2497-2504. doi: 10.11862/CJIC.20240084
13. [13]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
14. [14]
  Ziyou Zhang , Te Ji , Hongliang Dong , Zhiqiang Chen , Zhi Su . Effect of coordination restriction on pressure-induced fluorescence evolution. Chinese Chemical Letters, 2024, 35(12): 109542-. doi: 10.1016/j.cclet.2024.109542
15. [15]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
16. [16]
  Chen LU , Qinlong HONG , Haixia ZHANG , Jian ZHANG . Syntheses, structures, and properties of copper-iodine cluster-based boron imidazolate framework materials. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 149-154. doi: 10.11862/CJIC.20240407
17. [17]
  Zhongxin YU , Wei SONG , Yang LIU , Yuxue DING , Fanhao MENG , Shuju WANG , Lixin YOU . Fluorescence sensing on chlortetracycline of a Zn-coordination polymer based on mixed ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2415-2421. doi: 10.11862/CJIC.20240304
18. [18]
  Guoying Han , Qazi Mohammad Junaid , Xiao Feng . Topology-driven directed synthesis of metal-organic frameworks. Chinese Journal of Structural Chemistry, 2025, 44(3): 100447-100447. doi: 10.1016/j.cjsc.2024.100447
19. [19]
  Tiankai Sun , Hui Min , Zongsu Han , Liang Wang , Peng Cheng , Wei Shi . Rapid detection of nanoplastic particles by a luminescent Tb-based coordination polymer. Chinese Chemical Letters, 2024, 35(5): 108718-. doi: 10.1016/j.cclet.2023.108718
20. [20]
  Ruike Hu , Kangmin Wang , Junxiang Liu , Jingxian Zhang , Guoliang Yang , Liqiu Wan , Bijin Li . Extended π-conjugated systems by external ligand-assisted C−H olefination of heterocycles: Facile access to single-molecular white-light-emitting and NIR fluorescence materials. Chinese Chemical Letters, 2025, 36(4): 110113-. doi: 10.1016/j.cclet.2024.110113

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(303)
HTML views(17)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142