Citation: Ruolin CHENG, Haoran WANG, Jing REN, Yingying MA, Huagen LIANG. Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349 shu

Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst

Ruolin CHENG ^1,, ,
Haoran WANG ² ,
Jing REN ² ,
Yingying MA ³ ,
Huagen LIANG ^{1, 4,,}

1.
Jiangsu Key Laboratory of Coal-based Greenhouse Gas Control and Utilization, Carbon Neutrality Institute, China University of Mining and Technology, Xuzhou, Jiangsu 221008, China
2.
School of Information and Control Engineering, China University of Mining and Technology, Xuzhou, Jiangsu 221116, China
3.
Training Center, Jiangsu Provincial Xuzhou Pharmaceutical Vocational College, Xuzhou, Jiangsu 221116, China
4.
School of Materials Science and Physics, China University of Mining and Technology, Xuzhou, Jiangsu 221008, China

Corresponding author: Ruolin CHENG, ruolin.cheng@cumt.edu.cn Huagen LIANG, lianghg@cumt.edu.cn
Received Date: 18 September 2023
Revised Date: 22 December 2023

Figures(10)

Zr-based metal-organic framework (MOF) NH₂-UiO-66 was first synthesized by a solvothermal method using 2-amino terephthalic acid (H₂ATA) as the ligand. The efficient W₁₈O₄₉/NH₂-UiO-66 photocatalysts with a typical type Ⅱ heterojunction were then constructed by in-situ growth of the oxygen vacancy-rich defective tungsten oxide (W₁₈O₄₉) on NH₂-UiO-66, using tungsten chloride as the precursor. The composition and structure of the catalysts were characterized by a series of measurements, including powder X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy, and UV-Vis diffuse reflectance spectroscopy. At room temperature and atmospheric pressure, the photoactivity of all the catalysts was examined under simulated sunlight with styrene oxide as the model substrate. W₁₈O₄₉/NH₂-UiO-66 exhibited the highest yield of styrene carbonate (58 mmol·g^-1·h^-1). The introduction of NH₂-UiO-66 expanded the specific surface area, CO₂ adsorption capacity, light harvesting ability, and photogenerated charge carriers transfer of W₁₈O₄₉.
- CO₂ cycloaddition,
- photocatalysis,
- W₁₈O₄₉,
- metal-organic framework
1. [1]
  Chen L L, Lu S J, Zhang L, Zhang C J, Liu L, Kang G J, Tang H, Chen S M. Solid waste of fly ash toward energy-efficient CO₂ capture[J]. ACS Sustain. Chem. Eng., 2023,11:8281-8293. doi: 10.1021/acssuschemeng.3c00657
2. [2]
  Lv C C, Bai X H, Ning S B, Song C X, Guan Q Q, Liu B, Li Y G, Ye J H. Nanostructured materials for photothermal carbon dioxide hydrogenation: Regulating solar utilization and catalytic performance[J]. ACS Nano, 2023,17(3):1725-1738. doi: 10.1021/acsnano.2c09025
3. [3]
  LAN D H, TANG T, DAI W L, TAN N Y, WU S S, AU C T, YI B. Synergistic effects in multi-group functionalized graphene oxide for CO₂ cycloaddition reaction[J]. Chinese J. Inorg. Chem., 2019,35(3):442-448.
4. [4]
  ZHAO D, LIAO Z T, ZHANG W, CHEN Z Z, SUN W Y. Progress in functional metal-organic frameworks for catalytic conversion of carbon dioxide[J]. Chinese J. Inorg. Chem., 2021,37(7):1153-1176.
5. [5]
  Sharma N, Dhankhar S S, Nagaraja C M. A Mn(Ⅱ)-porphyrin based metal-organic framework (MOF) for visible-light-assisted cycloaddition of carbon dioxide with epoxides[J]. Microporous Mesoporous Mat., 2019,280:372-378. doi: 10.1016/j.micromeso.2019.02.026
6. [6]
  Zhai G Y, Liu Y Y, Lei L F, Wang J J, Wang Z Y, Zheng Z K, Wang P, Cheng H F, Dai Y, Huang B B. Light-promoted CO₂ conversion from epoxides to cyclic carbonates at ambient conditions over a Bi-based metal-organic framework[J]. ACS Catal., 2021,11(4):1988-1994. doi: 10.1021/acscatal.0c05145
7. [7]
  Zhai G Y, Liu Y Y, Mao Y Y, Zhang H G, Lin L T, Li Y J, Wang Z Y, Cheng H F, Wang P, Zheng Z K, Dai Y, Huang B B. Improved photocatalytic CO₂ and epoxides cycloaddition via the synergistic effect of Lewis acidity and charge separation over Zn modified UiO-bpydc[J]. Appl. Catal. B-Environ., 2022,301120793. doi: 10.1016/j.apcatb.2021.120793
8. [8]
  Huang Z W, Hu K Q, Mei L, Wang C Z, Chen Y M, Wu W S, Chai Z F, Shi W Q. Potassium ions induced framework interpenetration for enhancing the stability of uranium-based porphyrin MOF with visible-light-driven photocatalytic activity[J]. Inorg. Chem., 2021,60(2):651-659. doi: 10.1021/acs.inorgchem.0c02473
9. [9]
  Zhang H G, Zhai G Y, Lei L F, Zhang C Y, Liu Y Y, Wang Z Y, Cheng H F, Zheng Z K, Wang P, Dai Y, Huang B B. Photo-induced photo-thermal synergy effect leading to efficient CO₂ cycloaddition with epoxide over a Fe-based metal organic framework[J]. J. Colloid Interface Sci., 2022,625:33-40. doi: 10.1016/j.jcis.2022.05.146
10. [10]
  Liu L F, Zhang J L, Cheng X Y, Xu M Z, Kang X C, Wan Q, Han B X, Wu N N, Zheng L R, Ma C Y. Amorphous NH₂-MIL-68 as an efficient electro- and photo-catalyst for CO₂ conversion reactions[J]. Nano Res., 2022,16(1):181-188.
11. [11]
  Cheng R L, Wang A H, Sang S X, Liang H G, Liu S Q, Tsiakaras P. Photocatalytic CO₂ cycloaddition over highly efficient W₁₈O₄₉-based composites: An economic and ecofriendly choice[J]. Chem. Eng. J., 2023,466142982. doi: 10.1016/j.cej.2023.142982
12. [12]
  Chen L Y, Yu F Y, Shen X S, Duan C Y. N-CND modified NH₂-UiO-66 for photocatalytic CO₂ conversion under visible light by a photo-induced electron transfer process[J]. Chem. Commun., 2019,55(33):4845-4848. doi: 10.1039/C9CC02193K
13. [13]
  Cheng R L, Steele J A, Roeffaers M B J, Hofkens J, Debroye E. Dual-channel charge carrier transfer in CsPbX₃ perovskite/W₁₈O₄₉ composites for selective photocatalytic benzyl alcohol oxidation[J]. ACS Appl. Energ. Mater., 2021,4(4):3460-3468. doi: 10.1021/acsaem.0c03215
14. [14]
  ZHOU X, FENG T, GAO S T, YANG L L, WANG Z C, WANG N, LIU C Y, FENG C, SHANG N Z, WANG C. Visible-light responsive photocatalyst Ag/AgCl@NH₂-UiO-66: Preparation and photocatalytic performance[J]. Chinese J. Inorg. Chem., 2016,32(5):769-776.
15. [15]
  Liang Q, Zhang M, Zhang Z H, Liu C H, Xu S, Li Z Y. Zinc phthalocyanine coupled with UiO-66 (NH₂) via a facile condensation process for enhanced visible-light-driven photocatalysis[J]. J. Alloy. Compd., 2017,690:123-130. doi: 10.1016/j.jallcom.2016.08.087
16. [16]
  Zhang N, Jalil A, Wu D X, Chen S M, Liu Y F, Gao C, Ye W, Qi Z M, Ju H X, Wang C M, Wu X J, Song L, Zhu J F, Xiong Y J. Refining defect states in W₁₈O₄₉ by Mo Doping: A strategy for tuning N₂ activation towards solar-driven nitrogen fixation[J]. J. Am. Chem. Soc., 2018,140(30):9434-9443. doi: 10.1021/jacs.8b02076
17. [17]
  Zhang X L, Huang W, Xia Z X, Xian M, Bu F, Liang F B, Feng D X. One-pot synthesis of S-scheme WO₃/BiOBr heterojunction nanoflowers enriched with oxygen vacancies for enhanced tetracycline photodegradation[J]. Sep. Purif. Technol., 2022,290120897. doi: 10.1016/j.seppur.2022.120897
18. [18]
  Jiang H Y, Zang C C, Guo L X, Gao X. Carbon vacancies enriched carbon nitride nanotubes for Pd coordination environment optimization: Highly efficient photocatalytic hydrodechlorination and CO₂ cycloaddition[J]. Sci. Total Environ., 2022,838155920. doi: 10.1016/j.scitotenv.2022.155920
19. [19]
  Liu C Y, Niu H H, Wang D X, Gao C, Said A, Liu Y S, Wang G, Tung C H, Wang Y F. S-scheme Bi-oxide/Ti-oxide molecular hybrid for photocatalytic cycloaddition of carbon dioxide to epoxides[J]. ACS Catal., 2022,12(14):8202-8213. doi: 10.1021/acscatal.2c02256
20. [20]
  Li Y X, Zhang X, Lan J W, Li D Z, Wang Z J, Xu P, Sun J M. A high-performance zinc-organic framework with accessible open metal sites catalyzes CO₂ and styrene oxide into styrene carbonate under mild conditions[J]. ACS Sustain. Chem. Eng., 2021,9(7):2795-2803. doi: 10.1021/acssuschemeng.0c08466
21. [21]
  Dai W L, Zou M L, Long J F, Li B, Zhang S Q, Yang L X, Wang D, Mao P, Luo S L, Luo X B. Nanoporous N-doped carbon/ZnO hybrid derived from zinc aspartate: An acid-base bifunctional catalyst for efficient fixation of carbon dioxide into cyclic carbonates[J]. Appl. Surf. Sci., 2021,540148311. doi: 10.1016/j.apsusc.2020.148311
22. [22]
  Xu J, Xu H, Dong A Q, Zhang H, Zhou Y T, Dong H, Tang B, Liu Y F, Zhang L X, Liu X J, Luo J, Bie L J, Dai S, Wang Y H, Sun X H, Li Y G. Strong electronic metal-support interaction between iridium single atoms and WO₃ support promotes highly efficient and robust CO₂ cycloaddition[J]. Adv. Mater., 2022,34(44)2206991. doi: 10.1002/adma.202206991
23. [23]
  CHENG R L, JIN X X, FAN X Q, WANG M, TIAN J J, ZHANG L X, SHI J L. Incorporation of N-doped reduced graphene oxide into pyridine-copolymerized g-C₃N₄ for greatly enhanced H₂ photocatalytic evolution[J]. Acta Phys.-Chim. Sin., 2017,33(7):1436-1445.
24. [24]
  Yang J, He X Q, Dai J, Tian R, Yuan D S. Photo-assisted enhancement performance for rapid detoxification of chemical warfare agent simulants over versatile ZnIn₂S₄/UiO-66-NH₂ nanocomposite catalysts[J]. J. Hazard. Mater., 2021,417126056. doi: 10.1016/j.jhazmat.2021.126056
25. [25]
  Xu Y Y, Liu M, Tong F X, Ma F H, He X Y, Wang Z Y, Wang P, Liu Y Y, Cheng H F, Dai Y, Zheng Z K, Huang B B. Strain-assisted in-situ formed oxygen defective WO₃ film for photothermal-synergistic reverse water gas shift reaction and single-particle study[J]. Chem. Eng. J., 2022,433134199. doi: 10.1016/j.cej.2021.134199
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Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst