Citation: Xingxing ZHANG, Yunyin NIU. Synthesis of metal coordination compounds containing benzimidazole tripod ligand and their adsorption properties for iodine[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(1): 111-123. doi: 10.11862/CJIC.20230335 shu

Synthesis of metal coordination compounds containing benzimidazole tripod ligand and their adsorption properties for iodine

Xingxing ZHANG ,
Yunyin NIU ^,

Green Catalysis Center, College of Chemistry, Zhengzhou University, Zhengzhou 450001, China

Corresponding author: Yunyin NIU, niuyy@zzu.edu.cn
Received Date: 4 September 2023
Revised Date: 29 November 2023

Figures(11)

Two novel metal coordination compounds [Co₃(L1)₂Cl₆]_n (1) and {[Cu(L1)(SO₄)]·2CH₃OH}_n (2), where L1= 2, 2′, 2″-tri(1-benzimidazolyl) ethylamine, have been synthesized by solvothermal method. L1 is a neutral benzimidazole tripod ligand. Single crystal X-ray diffraction analysis shows that compound 1 is a 1D chain structure and compound 2 is a 3D structure. The purity of compounds 1 and 2 was characterized by infrared spectroscopy and powder X-ray diffraction. Thermogravimetric analysis shows that compounds 1 and 2 are heat-resistant materials. The iodine adsorption experiments show that they have high performance of capturing iodine in cyclohexane solution and gaseous iodine and have good recycling ability. At the same time, their adsorption kinetics are most suitable for the quasi-second-order model, and the adsorption process is mainly chemisorption. According to the adsorption mechanism, the structures of the compounds contain active groups such as benzene and N heterocyclic ring, which indirectly increases the adsorption site with iodine and the chemical reactivity with iodine, improving the removal rate of iodine.
- coordination compound,
- iodine,
- adsorption,
- benzimidazole,
- trapping agent
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