Citation: Xiaoling LUO, Pintian ZOU, Xiaoyan WANG, Zheng LIU, Xiangfei KONG, Qun TANG, Sheng WANG. Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271 shu

Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand

1.
College of Chemical and Biological Engineering, Guilin University of Technology, Guangxi Key Laboratory of Electrochemical and Magneto-chemical Functional Materials, Guilin, Guangxi 541004, China
2.
Guangxi Guilin RID Testing & Certification Group, Guilin, Guangxi 541100, China

Corresponding author: Zheng LIU, lisa4.6@163.com Qun TANG, tangq@glut.edu.cn
Received Date: 18 July 2023
Revised Date: 12 April 2024

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The present report deals with the synthesis of the two MOFs of respective formula {[Nd₂(L)₃(DMF)₂(H₂O)₂]·2DMF}_n (1) and {[Gd₂(L)₃(DMF)₂(H₂O)₂]·2DMF}_n (2) were synthesized by solvothermal method using 2, 5-dibromo-terephthalic acid (H₂L) as a ligand and reacting with neodymium nitrate hexahydrate and gadolinium nitrate hexahydrate, respectively. The structures of both of them were elucidated by single-crystal X-ray diffraction and powder X-ray diffraction to demonstrate that complexes 1 and 2 crystallize in a similar space group P1 as a triclinic system with high crystal purity. Meanwhile, the complexes were characterized by elemental analysis, IR spectroscopy, UV-Vis absorption spectroscopy, fluorescence, and thermal analysis. Single-crystal X-ray diffraction analysis demonstrates the complexes are connected to the ligand with rare earth ions as metal nodes, forming an infinitely extended 3D network structure.
- lanthanide series,
- 2, 5-dibromoterephthalic acid,
- metal-organic framework,
- crystal structure
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