Citation: Xingxing SHENG, Feng XIAO, Jinbin LÜ. Luminescence characteristics and device applications of Cr³⁺-doped Ca₄HfGe₃O₁₂ broadband near-infrared phosphors[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(2): 345-352. doi: 10.11862/CJIC.20230260 shu

Luminescence characteristics and device applications of Cr³⁺-doped Ca₄HfGe₃O₁₂ broadband near-infrared phosphors

School of Biomedical Engineering, Xinjiang Second Medical College, Karamay, Xinjiang 834000, China

Corresponding author: Xingxing SHENG, 1531352712@qq.com
Received Date: 10 July 2023
Revised Date: 17 November 2023

Figures(7)

Near-infrared phosphor has shown an important application prospect in the fields of living organism imaging. However, the near-infrared phosphor for organism imaging has some bottleneck problems such as a lack of variety and poor thermal stability. Broadband near-infrared Ca₄HfGe₃O₁₂∶xCr³⁺ (0≤x≤0.09) phosphors were synthesized by the solid phase method. X-ray diffraction and energy spectrum analysis showed that Cr³⁺ ions successfully entered the Ca₄HfGe₃O₁₂ crystal lattice. Upon 469 nm excitation, Ca₄HfGe₃O₁₂∶xCr³⁺ phosphors presented a width emission band covering 690-1 200 nm (strongest peak of 825 nm for ⁴T₂-⁴A₂, bandwidth of 141 nm) with a fluorescence quantum efficiency of 33.63% (x=0.03), which exhibited good thermal stability, 60.5% of room temperature intensity at 400 K. The excitation peak shape and lifetime decay behavior results showed that Cr³⁺ occupies only one cation sites in the matrix. In addition, the self-made near-infrared phosphor conversion device was used to illuminate the palm of the human hand and the fruit shielded by the 700 nm filter, and the venous vessels and the shelter-fruit outline were clearly observed.
- thermal stability,
- Ca₄HfGe₃O₁₂,
- near-infrared phosphor,
- Cr³⁺ ions,
- optical material
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Luminescence characteristics and device applications of Cr³⁺-doped Ca₄HfGe₃O₁₂ broadband near-infrared phosphors