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Citation: Yongzheng ZHANG, Xu GUO, Xinyue SONG, Xin LI. Advances in non-metallic doping of transition metal electrocatalysts for overall water splitting[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(2): 289-306. doi: 10.11862/CJIC.20230121 shu

Advances in non-metallic doping of transition metal electrocatalysts for overall water splitting

  • 1.

    School of Chemical Engineering and Chemistry, Harbin Institute of Technology, Harbin 150001, China

  • 2.

    School of Environment, Harbin Institute of Technology, Harbin 150001, China

  • Corresponding author: Xin LI, lixin@hit.edu.cn
  • Received Date: 4 April 2023
    Revised Date: 29 December 2023

Figures(8)

  • Transition metal-based materials with relatively low cost and excellent catalytic performance are considered as the most promising candidates to replace noble metal-based electrocatalysts in the field of overall water splitting. However, their wide applications are hindered by the limited active sites and relatively poor electrical conductivity. The doping of non-metallic elements can modulate the electronic structure of the host material and optimize the adsorption energy, thus positively affecting the activity and stability of transition metal-based electrocatalysts and narrowing the performance gap between them and precious metal materials. In this paper, we summarize the recent research on the modification of non-metallic elements in transition metal-based electrocatalytic materials, systematically review the methods of non-metallic element doping (high-temperature calcination, hydrothermal/solvent thermal, plasma treatment and electrodeposition), the doping effects of different non-metallic elements (single non-metallic element doping, multi-nonmetallic element doping and composite doping), and analyze the effects of non-metallic element modification on transition metal-based electrocatalysts from multiple perspectives of physicochemical property changes and electronic structure changes. The effects of non-metallic element modification on transition metal-based materials are analyzed from the perspectives of physicochemical property change and electronic structure change. In the end, the future development direction of non-metallic element doped transition metalbased electrocatalysts is prospected.
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