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Citation: Yiqing KANG, Yin WANG, Yueyuan MIAO, Yanru WANG, Siyu WANG, Lijie ZHANG, Daohao LI. Efficient hydrogen evolution reaction activity induced by P-doped defective WS2 nanosheets[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(2): 373-382. doi: 10.11862/CJIC.2023.208 shu

Efficient hydrogen evolution reaction activity induced by P-doped defective WS2 nanosheets

  • Qingdao University, College of Materials Science and Engineering, State Key Laboratory of Bio-fibers and Eco-textiles, Qingdao, Shandong 266071, China

Figures(9)

  • Herein, tungsten disulfide (WS2) nanosheets were firstly prepared by ultrasonic stripping method. Subsequently, the mixture of WS2 nanosheets and P powder were treated by the Ar plasma, obtaining P-doped defective WS2 nanosheets (P-D-WS2 NSs). The as-prepared P-D-WS2 NSs samples exhibited higher catalytic activity for hydrogen evolution reaction (HER) than defective WS2 nanosheets and pure WS2 nanosheets, such as lower overpotential, smaller Tafel slope, and better durability. Density functional theory calculations showed that the P atoms and defective structures in WS2 regulated the electronic environment around the materials, optimizing the energy barrier of H+ adsorption and hydrogen formation kinetics performance, thus improving the HER electrocatalytic activity.
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