Advanced Search

Citation: Yiqing KANG, Yin WANG, Yueyuan MIAO, Yanru WANG, Siyu WANG, Lijie ZHANG, Daohao LI. Efficient hydrogen evolution reaction activity induced by P-doped defective WS2 nanosheets[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(2): 373-382. doi: 10.11862/CJIC.2023.208 shu

Efficient hydrogen evolution reaction activity induced by P-doped defective WS2 nanosheets

  • Qingdao University, College of Materials Science and Engineering, State Key Laboratory of Bio-fibers and Eco-textiles, Qingdao, Shandong 266071, China

Figures(9)

  • Herein, tungsten disulfide (WS2) nanosheets were firstly prepared by ultrasonic stripping method. Subsequently, the mixture of WS2 nanosheets and P powder were treated by the Ar plasma, obtaining P-doped defective WS2 nanosheets (P-D-WS2 NSs). The as-prepared P-D-WS2 NSs samples exhibited higher catalytic activity for hydrogen evolution reaction (HER) than defective WS2 nanosheets and pure WS2 nanosheets, such as lower overpotential, smaller Tafel slope, and better durability. Density functional theory calculations showed that the P atoms and defective structures in WS2 regulated the electronic environment around the materials, optimizing the energy barrier of H+ adsorption and hydrogen formation kinetics performance, thus improving the HER electrocatalytic activity.
  • 加载中
    1. [1]

      Li Y G, Wang H L, Xie L M, Liang Y, Hong G Y, Dai H S, Dai H J. MoS2 nanoparticles grown on graphene: An advanced catalyst for the hydrogen evolution reaction[J]. J. Am. Chem. Soc., 2011,133(19):7296-7299. doi: 10.1021/ja201269b

    2. [2]

      Tiwari A P, Kim D, Kim Y, Prakash O, Lee H. Highly qctive and stable layered ternary transition metal chalcogenide for hydrogen evolution reaction[J]. Nano Energy, 2016,28:366-372. doi: 10.1016/j.nanoen.2016.08.065

    3. [3]

      Song J H, Zhu C Z, Xu B Z, Fu S F, Mark H E, Ye R F, Du D, Scott P B, Lin Y H. Bimetallic cobalt-based phosphide zeolitic imidazolate framework: CoPx phase-dependent electrical conductivity and hydrogen atom adsorption energy for efficient overall water splitting[J]. Adv. Energy Mater., 2017,7(2)1601555. doi: 10.1002/aenm.201601555

    4. [4]

      Li Y H, Liu P F, Pan L F, Wang H F, Yang Z Z, Zheng L R, Zhao H J, Gu L, Yang H G. Local atomic structure modulations activate metal oxide as electrocatalyst for hydrogen evolution in acidic water[J]. Nat. Commun., 2015,68064. doi: 10.1038/ncomms9064

    5. [5]

      Tang C, Zhong L, Zhang B, Wang H F, Zhang Q. 3D mesoporous van der Waals heterostructures for trifunctional energy electrocatalysis[J]. Adv. Mater., 2018,30(5)1705110. doi: 10.1002/adma.201705110

    6. [6]

      Yuan K, Zhuang X D, Fu H Y, Brunklaus G, Forster M, Chen Y W, Feng X L, Ullrich S. Two-dimensional core-shelled porous hybrids as highly efficient catalysts for the oxygen reduction reaction[J]. Angew. Chem. Int. Ed., 2016,55(24):6858-6863. doi: 10.1002/anie.201600850

    7. [7]

      Huang Y C, Sun Y H, Zheng X L, Toshihiro A, Brian P, Jier H, He X, Bian W, Sabrina Y, Nicholas W, Hu J, Ge J X, Pu N, Yan X X, Pan X Q, Zhang L J, Wei Y G, Gu J. Atomically engineering activation sites onto metallic 1T-MoS2 catalysts for enhanced electrochemical hydrogen evolution[J]. Nat. Commun., 2019,10(1):1-11. doi: 10.1038/s41467-018-07882-8

    8. [8]

      Kim M, Anjum M A R, Lee M, Lee B J, Lee J S. Activating MoS2 basal plane with Ni2P nanoparticles for Pt-like hydrogen evolution reaction in acidic media[J]. Adv. Funct. Mater., 2019,29(10)1809151. doi: 10.1002/adfm.201809151

    9. [9]

      Guo Y N, Park T, Yi J W, Henzie J, Kim J, Wang Z L, Jiang B, Bando Y, Sugahara Y, Tang J, Yamauchi Y. Nanoarchitectonics for transition-metal-sulfide-based electrocatalysts for water splitting[J]. Adv Mater., 2019,31(17)1807134. doi: 10.1002/adma.201807134

    10. [10]

      Pramoda K, Gupta U, Chhetri M, Bandyopadhyay A, Pati S K, Rao C N R. Nanocomposites of C3N4 with layers of MoS2 and nitrogenated RGO, obtained by covalent cross-linking: Synthesis, characterization, and HER activity[J]. ACS Appl. Mater. Interfaces, 2017,9(12):10664-10672. doi: 10.1021/acsami.7b00085

    11. [11]

      Sun Y, Alimohammadi F, Zhang D, Guo G S. Enabling colloidal synthesis of edge-oriented MoS2 with expanded interlayer spacing for enhanced HER catalysis[J]. Nano Lett., 2017,17(3):1963-1969. doi: 10.1021/acs.nanolett.6b05346

    12. [12]

      Zhang J, Wang T, Pohl D, Rellinghaus B, Dong R H, Zhuang X D, Feng X L. Interface engineering of MoS2/Ni3S2 heterostructures for highly enhanced electrochemical overall-water-splitting activity[J]. Angew. Chem. Int. Ed., 2016,55(23):6702-6707. doi: 10.1002/anie.201602237

    13. [13]

      Chua X J, Luxa J, Eng A Y S, Tan S M, Sofer Z, Pumera M. Negative electrocatalytic effects of p-doping niobium and tantalum on MoS2 and WS2 for the hydrogen evolution reaction and oxygen reduction reaction[J]. ACS Catal., 2016,6(9):5724-5734. doi: 10.1021/acscatal.6b01593

    14. [14]

      Duan J J, Chen S, Chambers B A, Andersson G G, Qiao S Z. 3D WS2 nanolayers@heteroatom-doped graphene films as hydrogen evolution catalyst electrodes[J]. Adv. Mater., 2015,27(28):4234-4241. doi: 10.1002/adma.201501692

    15. [15]

      Cheng L, Huang W J, Gong Q G, Liu C H, Liu Z, Li Y G, Dai H J. Ultrathin WS2 nanoflakes as a high-performance electrocatalyst for the hydrogen evolution reaction[J]. Angew. Chem. Int. Ed., 2014,53(30):7860-7863. doi: 10.1002/anie.201402315

    16. [16]

      Wang F, He P, Li Y, Shiafa T A, Deng Y, Liu K L, Wang Q S, Wang F, Wen Y, Wang Z X, Zhan X Y, Sun L F, He J. Interface engineered WxC@WS2 nanostructure for enhanced hydrogen evolution catalysis[J]. Adv. Funct. Mater., 2017,27(7)1605802. doi: 10.1002/adfm.201605802

    17. [17]

      An Y R, Fan X L, Luo Z F, Lau W M. Nanopolygons of monolayer MS2: Best morphology and size for HER catalysis[J]. Nano Lett., 2017,17(1):368-376. doi: 10.1021/acs.nanolett.6b04324

    18. [18]

      Tang K, Wang X F, Li Q, Yan C L. High edge selectivity of in situ electrochemical Pt deposition on edge-rich layered WS2 nanosheets[J]. Adv. Mater., 2018,30(7)1704779. doi: 10.1002/adma.201704779

    19. [19]

      Wang Q, Zhao Z L, Dong S, He D S, Lawrence M J, Han S B, Cai C, Xiang S H, Rodriguez P, Xiang B, Wang Z G, Liang Y Y, Gu M. Design of active nickel single-atom decorated MoS2 as a pH-universal catalyst for hydrogen evolution reaction[J]. Nano Energy, 2018,53:458-467. doi: 10.1016/j.nanoen.2018.09.003

    20. [20]

      Zhang X, Zhou F, Zhang S, Liang Y Y, Wang R H. Engineering MoS2 basal planes for hydrogen evolution via synergistic ruthenium doping and nanocarbon hybridization[J]. Adv. Sci., 2019,6(10)1900090. doi: 10.1002/advs.201900090

    21. [21]

      Gu C, Hu S, Zheng X S, Gao M R, Zheng Y R, Shi L, Gao Q, Zheng X, Chu W S, Yao H B, Zhu J F, Yu S H. Synthesis of sub-2 nm iron-doped NiSe2 nanowires and their surface-confined oxidation for oxygen evolution catalysis[J]. Angew. Chem. Int. Ed., 2018,57(15):4020-4024. doi: 10.1002/anie.201800883

    22. [22]

      Qian X, Liu H, Yang J, Wang H, Huang J, Xu C. Co-Cu-WSx ball-in-ball nanospheres as high-performance Pt-free bifunctional catalysts in efficient dye-sensitized solar cells and alkaline hydrogen evolution[J]. J. Mater. Chem. A, 2019,7(11):6337-6347. doi: 10.1039/C8TA12558A

    23. [23]

      Kwak I H, Abbas H G, Kwon I S, Park Y C, Seo J, Cho M K, Ahn J P, Seo H W, Park J, Kang H S. Intercalation of cobaltocene into WS2 nanosheets for enhanced catalytic hydrogen evolution reaction[J]. J. Mater. Chem. A, 2019,7(14):8101-8106. doi: 10.1039/C9TA01238A

    24. [24]

      Xiong Q, Wang Y, Liu P F, Zheng L R, Wang G Z, Yang H G, Wong P K, Zhang H, Zhao H J. Cobalt covalent doping in MoS2 to induce bifunctionality of overall water splitting[J]. Adv Mater., 2018,30(29)1801450. doi: 10.1002/adma.201801450

    25. [25]

      Xing Z C, Yang X R, Asiri A M, Sun X P. Three-dimensional structures of MoS2@Ni core/shell nanosheets array toward synergetic electrocatalytic water splitting[J]. ACS Appl. Mater. Interfaces, 2016,8(23):14521-14526. doi: 10.1021/acsami.6b02331

    26. [26]

      Li Y, Majewski M B, Islam S M, Hao S Q, Murthy A A, DisStefano J G, Haned E D, Xu Y B, Wolverton C, Kanatzidis M G, Chen X, Dravid V P. Morphological engineering of winged Au@MoS2 heterostructures for electrocatalytic hydrogen evolution[J]. Nano Lett., 2018,18(11):7104-7110. doi: 10.1021/acs.nanolett.8b03109

    27. [27]

      Amiinu I S, Pu Z, Liu X, Owusu K A, Monestel H G R, Boakye F O, Zhang H, Mu S C. Multifunctional Mo-N/C@MoS2 electrocatalysts for HER, OER, ORR, and Zn-air batteries[J]. Adv. Funct. Mater., 2017,27(44)1702300. doi: 10.1002/adfm.201702300

    28. [28]

      Yuan Z, Li J, Yang M, Fang Z, Jian J H, Yu D S, Chen X D, Dai L M. Ultrathin black phosphorus-on-nitrogen doped graphene for efficient overall water splitting: dual modulation roles of directional interfacial charge transfer[J]. J. Am. Chem. Soc., 2019,141(12):4972-4979. doi: 10.1021/jacs.9b00154

    29. [29]

      Zong L, Li M, Li C. Bioinspired coupling of inorganic layered nanomaterials with marine polysaccharides for efficient aqueous exfoliation and smart actuating hybrids[J]. Adv. Mater., 2017,29(10)1604691. doi: 10.1002/adma.201604691

    30. [30]

      Yu S, Kim J, Yoon K R, Jung J W, Oh J, Kim I D. Rational design of efficient electrocatalysts for hydrogen evolution reaction: single layers of WS2 nanoplates anchored to hollow nitrogen-doped carbon nanofibers[J]. ACS Appl. Mater. Interfaces., 2015,7(51):28116-28121. doi: 10.1021/acsami.5b09447

    31. [31]

      Zhao X, Ma X, Sun J, Li D, Yang X. Enhanced catalytic activities of surfactant-assisted exfoliated WS2 nanodots for hydrogen evolution[J]. ACS Nano, 2016,10(2):2159-2166. doi: 10.1021/acsnano.5b06653

    32. [32]

      Salvati Jr L, Makovsky L E, Stencel J M, Brown F R, Hercules D M. Surface spectroscopic study of tungsten-alumina catalysts using X-ray photoelectron, ion scattering, and Raman spectroscopies[J]. J. Phys. Chem., 1981,85(24):3700-3707. doi: 10.1021/j150624a035

    33. [33]

      Pelavin M, Hendrickson D N, Hollander J M, Jolly W L. Phosphorus 2p electron binding energies. correlation with extended hueckel charges[J]. J. Phys. Chem., 1970,74(5):1116-1121. doi: 10.1021/j100700a027

    34. [34]

      Morgan W E, Stec W J, Albridge R G. pi.-Bond feedback interpreted from the binding energy of the "2p" electrons of phosphorus[J]. Inorg. Chem., 1971,10(5):926-930. doi: 10.1021/ic50099a013

    35. [35]

      Jiang Y, Huang J B, Mao B G, An T Y, Wang J, Cao M H. Inside solid liquid interfaces: Understanding the influence of the electrical double layer on alkaline hydrogen evolution reaction[J]. Appl. Catal. B-Environ., 2021,293120220. doi: 10.1016/j.apcatb.2021.120220

    36. [36]

      ZHOU Q, LI X B, JIAO S Z. Mesoporous regulated Co9S8/Ni3S2 composite electrode materials and electrocatalytic hydrogen evolution performance[J]. Chinese J. Inorg. Chem., 2021,37(11):1970-1980. doi: 10.11862/CJIC.2021.223 

  • 加载中
    1. [1]

      Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454

    2. [2]

      Yongwei ZHANG , Chuang ZHU , Wenbin WU , Yongyong MA , Heng YANG . Efficient hydrogen evolution reaction activity induced by ZnSe@nitrogen doped porous carbon heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 650-660. doi: 10.11862/CJIC.20240386

    3. [3]

      Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346

    4. [4]

      Runhua Chen ,  Qiong Wu ,  Jingchen Luo ,  Xiaolong Zu ,  Shan Zhu ,  Yongfu Sun . 缺陷态二维超薄材料用于光/电催化CO2还原的基础与展望. Acta Physico-Chimica Sinica, 2025, 41(3): 2308052-. doi: 10.3866/PKU.WHXB202308052

    5. [5]

      Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350

    6. [6]

      Zhengyu Zhou ,  Huiqin Yao ,  Youlin Wu ,  Teng Li ,  Noritatsu Tsubaki ,  Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-. doi: 10.3866/PKU.WHXB202312010

    7. [7]

      Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni3N supported Al-doped SrTiO3: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371

    8. [8]

      Pingping HAO , Fangfang LI , Yawen WANG , Houfen LI , Xiao ZHANG , Rui LI , Lei WANG , Jianxin LIU . Hydrogen production performance of the non-platinum-based MoS2/CuS cathode in microbial electrolytic cells. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1811-1824. doi: 10.11862/CJIC.20240054

    9. [9]

      Xinyu Miao ,  Hao Yang ,  Jie He ,  Jing Wang ,  Zhiliang Jin . 调整Keggin型多金属氧酸盐电子结构构建S型异质结用于光催化析氢. Acta Physico-Chimica Sinica, 2025, 41(6): 100051-. doi: 10.1016/j.actphy.2025.100051

    10. [10]

      Zizheng LU , Wanyi SU , Qin SHI , Honghui PAN , Chuanqi ZHAO , Chengfeng HUANG , Jinguo PENG . Surface state behavior of W doped BiVO4 photoanode for ciprofloxacin degradation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 591-600. doi: 10.11862/CJIC.20230225

    11. [11]

      Wenxiu Yang ,  Jinfeng Zhang ,  Quanlong Xu ,  Yun Yang ,  Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014

    12. [12]

      Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au11(dppf)4Cl2 nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047

    13. [13]

      Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C60-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289

    14. [14]

      Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO2 with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149

    15. [15]

      Asif Hassan Raza ,  Shumail Farhan ,  Zhixian Yu ,  Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020

    16. [16]

      Qin Hu ,  Liuyun Chen ,  Xinling Xie ,  Zuzeng Qin ,  Hongbing Ji ,  Tongming Su . Ni掺杂构建电子桥及激活MoS2惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024

    17. [17]

      Kaihui Huang ,  Dejun Chen ,  Xin Zhang ,  Rongchen Shen ,  Peng Zhang ,  Difa Xu ,  Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu2O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020

    18. [18]

      Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271

    19. [19]

      Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn2+ doped quasi-two-dimensional perovskites (PEA)2PbyMn1-yBr4. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473

    20. [20]

      Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003

Get Citation
PDF
XML
Metrics
  • PDF Downloads(2)
  • Abstract views(633)
  • HTML views(69)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return