Citation: Peng XU, Wei DAI, Wei-Shan SHI, Gang XING, Zhao-Gui WANG, Sha-Sha WANG, Qun LI, Chao-Qun YOU, De-Jun HAO. Preparation of zeolitic imidazolate frameworks-8/modified polyacrylonitrile electrospun nanofibers for efficient removal of malachite green from water[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(10): 1959-1968. doi: 10.11862/CJIC.2023.154 shu

Preparation of zeolitic imidazolate frameworks-8/modified polyacrylonitrile electrospun nanofibers for efficient removal of malachite green from water

Peng XU ¹ ,
Wei DAI ¹ ,
Wei-Shan SHI ² ,
Gang XING ² ,
Zhao-Gui WANG ³ ,
Sha-Sha WANG ¹ ,
Qun LI ¹ ,
Chao-Qun YOU ¹ ,
De-Jun HAO ^3,,

1.
College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China
2.
Jiangsu Aijin Crop Science and Technology Group Co., Ltd., Nanjing 210000, China
3.
College of Forestry, Nanjing Forestry University, Nanjing 210037, China

Corresponding author: De-Jun HAO, djhao@njfu.edu.cn
Received Date: 30 March 2023
Revised Date: 28 June 2023

Figures(9)

A simple in-situ growth method was presented to synthesize zeolitic imidazolate framework-8 (ZIF-8), one of the most common metal-organic frameworks (MOFs) crystals, onto a carboxymethylated polyacrylonitrile electrospun nanofibers (PAN-COOH NFs). The synthesized ZIF-8/PAN-COOH NFs were characterized by field-emission scanning electron microscope (SEM), energy dispersive spectroscopy (EDS), X-ray powder diffraction (XRD), and Fourier-transform infrared (FTIR) spectroscopy. The characterization results confirmed that the ZIF-8 particles were successfully loaded on the surface of the PAN-COOH NFs. The ability of ZIF-8/PAN-COOH NFs to remove malachite green (MG), a model organic dye, from wastewater was evaluated to examine the potential of this novel material as an adsorbent. The adsorption to MG was consistent with the pseudo -second -order kinetic equation, and the adsorption process was expressed by the Langmuir isotherm model. The maximum adsorption capacity for MG was examined as 3 604 mg·g^-1. It is noteworthy that the ZIF-8/PAN-COOH NFs could be easily separated from the dye solution and regenerated through a simple washing process for recycling.
- ZIF-8,
- electrospinning,
- nanofiber,
- polyacrylonitrile,
- adsorption,
- malachite green
1. [1]
  Mishra S, Cheng L, Maiti A. The utilization of agro-biomass/byproducts for effective bio-removal of dyes from dyeing wastewater: A comprehensive review[J]. J. Environ. Chem. Eng., 2021,9(1)104901. doi: 10.1016/j.jece.2020.104901
2. [2]
  Uddin F. Environmental hazard in textile dyeing wastewater from local textile industry[J]. Cellulose, 2021,28(17):10715-10739. doi: 10.1007/s10570-021-04228-4
3. [3]
  Donkadokula N Y, Kola A K, Naz I, Saroj D. A review on advanced physico-chemical and biological textile dye wastewater treatment techniques[J]. Rev. Environ. Sci. Bio/Technol., 2020,19(3):543-560. doi: 10.1007/s11157-020-09543-z
4. [4]
  HUANG J, CHEN H J, FENG X M. Micromotors based on Ni-Mn binary oxide and its application for effective dye adsorption[J]. Chinese J. Inorg. Chem., 2022,38:1411-1420.
5. [5]
  Osugi M E, Umbuzeiro G A, Anderson M A, Zanoni M V B. Degradation of metallophtalocyanine dye by combined processes of electro-chemistry and photoelectrochemistry[J]. Electrochim. Acta, 2005,50(25/26):5261-5269.
6. [6]
  Jin Z K, Dong W J, Yang M, Wang J J, Gao H Y, Wang G. One-pot preparation of hierarchical nanosheet-constructed Fe₃O₄/MIL-88B(Fe) magnetic microspheres with high efficiency photocatalytic degradation of dye[J]. ChemCatChem, 2016,8(22):3510-3517. doi: 10.1002/cctc.201600952
7. [7]
  Oelgemöller M, Healy N, de Oliveira L, Jung C, Mattay J. Green photochemistry: Solar-chemical synthesis of Juglone with medium concentrated sunlight[J]. Green Chem., 2006,8(9):831-834. doi: 10.1039/B605906F
8. [8]
  Wang Z Y, Ju C J, Zhang R, Hua J Q, Chen R P, Liu G X, Yin K, Yu L. Acceleration of the bio-reduction of methyl orange by a magnetic and extracellular polymeric substance nanocomposite[J]. J. Hazard. Mater., 2021,420126576. doi: 10.1016/j.jhazmat.2021.126576
9. [9]
  Fan J X, Chen D Y, Li N J, Xu Q F, Li H, He J H, Lu J M. Adsorption and biodegradation of dye in wastewater with Fe₃O₄@MIL-100(Fe) core-shell bio-nanocomposites[J]. Chemosphere, 2018,191:315-323. doi: 10.1016/j.chemosphere.2017.10.042
10. [10]
  Wang X H, Jiang C L, Hou B X, Wang Y Y, Hao C, Wu J B. Carbon composite lignin-based adsorbents for the adsorption of dyes[J]. Chemosphere, 2018,206:587-596. doi: 10.1016/j.chemosphere.2018.04.183
11. [11]
  Gohr M S, Abd- Elhamid A I, El- Shanshory A A, Soliman H A. Adsorption of cationic dyes onto chemically modified activated carbon: Kinetics and thermodynamic study[J]. J. Mol. Liq., 2022,346118227. doi: 10.1016/j.molliq.2021.118227
12. [12]
  Atrous M, Sellaoui L, Bouzid M, Lima E C, Thue P S, Bonilla-Petriciolet A, Ben Lamine A. Adsorption of dyes acid red 1 and acid green 25 on grafted clay: Modeling and statistical physics interpretation[J]. J. Mol. Liq., 2019,294111610. doi: 10.1016/j.molliq.2019.111610
13. [13]
  Tang C Y, Yu P, Tang L S, Wang Q Y, Bao R Y, Liu Z Y, Yang M B, Yang W. Tannic acid functionalized graphene hydrogel for organic dye adsorption[J]. Ecotoxicol. Environ. Saf., 2018,165:299-306. doi: 10.1016/j.ecoenv.2018.09.009
14. [14]
  Ma X L, Wang W L, Sun C G, Li H, Sun J, Liu X. Adsorption performance and kinetic study of hierarchical porous Fe-based MOFs for toluene removal[J]. Sci. Total Environ., 2021,793148622. doi: 10.1016/j.scitotenv.2021.148622
15. [15]
  Andres M A, Fontaine P, Goldmann M, Serre C, Roubeau O, Gascon I. Solvent-exchange process in MOF ultrathin films and its effect on CO₂ and methanol adsorption[J]. J. Colloid Interface Sci., 2021,590:72-81. doi: 10.1016/j.jcis.2021.01.030
16. [16]
  Banerjee D, Elsaidi S K, Thallapally P K. Xe adsorption and separation properties of a series of microporous metal-organic frameworks (MOFs) with V-shaped linkers[J]. J. Mater. Chem. A, 2017,5(32):16611-16615. doi: 10.1039/C7TA02746J
17. [17]
  Gao Y X, Liu K, Kang R X, Xia J, Yu G, Deng S B. A comparative study of rigid and flexible MOFs for the adsorption of pharmaceuticals: Kinetics, isotherms and mechanisms[J]. J. Hazard. Mater., 2018,359:248-257. doi: 10.1016/j.jhazmat.2018.07.054
18. [18]
  Xie L H, Liu X M, He T, Li R. Metal-organic frameworks for the capture of trace aromatic volatile organic compounds[J]. Chem, 2018,4(8):1911-1927. doi: 10.1016/j.chempr.2018.05.017
19. [19]
  Ahmadipouya S, Heidarian H M, Ahmadijokani F, Jarahiyan A, Molavi H, Matloubi M F, Rezakazemi M, Arjmand M. Magnetic Fe₃O₄@UiO-66 nanocomposite for rapid adsorption of organic dyes from aqueous solution[J]. J. Mol. Liq., 2021,322114910. doi: 10.1016/j.molliq.2020.114910
20. [20]
  Khosravi M J, Hosseini S M, Vatanpour V. Performance improvement of PES membrane decorated by Mil-125(Ti)/chitosan nanocomposite for removal of organic pollutants and heavy metal[J]. Chemosphere, 2022,290133335. doi: 10.1016/j.chemosphere.2021.133335
21. [21]
  Mohammad N S, Seyedpour S F, Aghapour A S, Dadashi F M, Elliott M, Tiraferri A, Sadrzadeh M, Rahimpour A. Loose nanofiltration membranes functionalized with in situ-synthesized metal organic framework for water treatment[J]. Mater. Today Chem., 2022,24100909. doi: 10.1016/j.mtchem.2022.100909
22. [22]
  Khajavian M, Salehi E, Vatanpour V. Chitosan/polyvinyl alcohol thin membrane adsorbents modified with zeolitic imidazolate framework (ZIF-8) nanostructures: Batch adsorption and optimization[J]. Sep. Purif. Technol., 2020,241116759. doi: 10.1016/j.seppur.2020.116759
23. [23]
  HUANG J, TIAN X Y, YANG L, FENG X M. Mn-MOF derived Mn₂O₃ micromotors applied to removal of methyl blue in water[J]. Chinese J. Inorg. Chem., 2022,38:153-160. doi: 10.11862/CJIC.2022.008
24. [24]
  Park J, Oh M. Construction of flexible metalorganic framework (MOF) papers through MOF growth on filter paper and their selective dye capture[J]. Nanoscale, 2017,9(35):12850-12854. doi: 10.1039/C7NR04113F
25. [25]
  Xu Y, Zhai X, Wang X H, Li L L, Chen H, Fan F Q, Bai X J, Chen J Y, Fu Y. Fabrication of a robust MOF/aerogel composite via a covalent postassembly method[J]. Chem. Commun., 2021,57(48):5961-5964. doi: 10.1039/D1CC01613J
26. [26]
  Maan O, Song P, Chen N X, Lu Q Y. An in situ procedure for the preparation of zeolitic imidazolate framework-8 polyacrylamide hydrogel for adsorption of aqueous pollutants[J]. Adv. Mater. Interfaces, 2019,6(10)1801895. doi: 10.1002/admi.201801895
27. [27]
  Dong C, Yang J J, Xie L H, Cui G, Fang W H, Li J R. Catalytic ozone decomposition and adsorptive VOCs removal in bimetallic metal-organic frameworks[J]. Nat. Commun., 2022,13(1)4991. doi: 10.1038/s41467-022-32678-2
28. [28]
  Mahmoodi N M, Oveisi M, Taghizadeh A, Taghizadeh M. Synthesis of pearl necklace-like ZIF-8@chitosan/PVA nanofiber with synergistic effect for recycling aqueous dye removal[J]. Carbohydr. Polym., 2020,227115364. doi: 10.1016/j.carbpol.2019.115364
29. [29]
  Huang J M, Huang D, Zeng F B, Ma L, Wang Z B. Photocatalytic MOF fibrous membranes for cyclic adsorption and degradation of dyes[J]. J. Mater. Sci., 2020,56(4):3127-3139.
30. [30]
  Xie X Y, Qian X Y, Qi S C, Wu J K, Liu X Q, Sun L B. Endowing Cu-BTC with improved hydrothermal stability and catalytic activity: Hybridization with natural clay attapulgite via vapor-induced crystal-lization[J]. ACS Sustain. Chem. Eng., 2018,6(10):13217-13225. doi: 10.1021/acssuschemeng.8b02827
31. [31]
  ZHU Y B, TANG X T, DUAN L W, LIU W Y, CAO X X, FENG P Z. Mn⁴⁺ doped Co₃O₄ nanofibers: Preparation by electro-spinning and electrochemical performance[J]. Chinese J. Inorg. Chem., 2018,34:317-324.
32. [32]
  Dou Y, Zhang W, Kaiser A. Electrospinning of metal-organic frameworks for energy and environmental applications[J]. Adv. Sci., 2020,7(3)1902590. doi: 10.1002/advs.201902590
33. [33]
  Jia M, Zhang X F, Feng Y, Zhou Y, Yao J. In-situ growing ZIF-8 on cellulose nanofibers to form gas separation membrane for CO₂ separation[J]. J. Membr. Sci., 2020,595117579. doi: 10.1016/j.memsci.2019.117579
34. [34]
  Lu J, Wu J K, Jiang Y, Tan P, Zhang L, Lei Y, Liu X Q, Sun L B. Fabrication of microporous metal-organic frameworks in uninterrupted mesoporous tunnels: Hierarchical structure for efficient trypsin immobilization and stabilization[J]. Angew. Chem. Int. Ed., 2020,59(16):6428-6434. doi: 10.1002/anie.201915332
35. [35]
  Abdi J, Vossoughi M, Mahmoodi N M, Alemzadeh I. Synthesis of metalorganic framework hybrid nanocomposites based on GO and CNT with high adsorption capacity for dye removal[J]. Chem. Eng. J., 2017,326:1145-1158. doi: 10.1016/j.cej.2017.06.054
36. [36]
  Wang S M, Li Z H, Lu C. Polyethyleneimine as a novel desorbent for anionic organic dyes on layered double hydroxide surface[J]. J. Colloid Interface Sci., 2015,458:315-322. doi: 10.1016/j.jcis.2015.07.056
37. [37]
  Zhao R, Yong X Y, Pan M, Deng J P, Pan K. Aldehyde-containing nanofibers electrospun from biomass vanillin-derived polymer and their application as adsorbent[J]. Sep. Purif. Technol., 2020,246116916. doi: 10.1016/j.seppur.2020.116916
38. [38]
  Habiba U, Siddique T A, Li Lee J J, Joo T C, Ang B C, Afifi A M. Adsorption study of methyl orange by chitosan/polyvinyl alcohol/zeolite electrospun composite nanofibrous membrane[J]. Carbohydr. Polym., 2018,191:79-85. doi: 10.1016/j.carbpol.2018.02.081
39. [39]
  Gao Y, Deng S Q, Jin X, Cai S L, Zheng S R, Zhang W G. The construction of amorphous metal-organic cage-based solid for rapid dye adsorption and time-dependent dye separation from water[J]. Chem. Eng. J., 2019,357:129-139. doi: 10.1016/j.cej.2018.09.124
40. [40]
  Wang J L, Guo X. Adsorption isotherm models: Classification, physical meaning, application and solving method[J]. Chemosphere, 2020,258127279. doi: 10.1016/j.chemosphere.2020.127279
41. [41]
  Li Y F, Yan X L, Hu X Y, Feng R, Zhou M, Han D Z. In situ growth of ZIF-8 onto porous carbons as an efficient adsorbent for malachite green removal[J]. J. Porous Mater., 2020,27(4):1109-1117. doi: 10.1007/s10934-020-00887-z
42. [42]
  Wang Q Q, Lei L L, Wang F C, Chen C T, Kang X Y, Wang C, Zhao J H, Yang Q X, Chen Z J. Preparation of egg white@zeolitic imidazolate framework-8@polyacrylic acid aerogel and its adsorption properties for organic dyes[J]. J. Solid State Chem., 2020,292121656. doi: 10.1016/j.jssc.2020.121656
43. [43]
  Mahmoodi N M, Oveisi M, Bakhtiari M, Hayati B, Shekarchi A A, Bagheri A, Rahimi S. Environmentally friendly ultrasound-assisted synthesis of magnetic zeolitic imidazolate framework—Graphene oxide nanocomposites and pollutant removal from water[J]. J. Mol. Liq., 2019,282:115-130. doi: 10.1016/j.molliq.2019.02.139
44. [44]
  Rabeie B, Mahkam M, Mahmoodi N M, Lan C Q. Graphene quantum dot incorporation in the zeolitic imidazolate framework with sodalite (SOD) topology: Synthesis and improving the adsorption ability in liquid phase[J]. J. Environ. Chem. Eng., 2021,9(6)106303. doi: 10.1016/j.jece.2021.106303
1. [1]
  Bing Shen , Tongwei Yuan , Wenshuang Zhang , Yang Chen , Jiaqiang Xu . Complex shell Fe-ZnO derived from ZIF-8 as high-quality acetone MEMS sensor. Chinese Chemical Letters, 2024, 35(11): 109490-. doi: 10.1016/j.cclet.2024.109490
2. [2]
  Guang-Xu Duan , Queting Chen , Rui-Rui Shao , Hui-Huang Sun , Tong Yuan , Dong-Hao Zhang . Encapsulating lipase on the surface of magnetic ZIF-8 nanosphers with mesoporous SiO₂ nano-membrane for enhancing catalytic performance. Chinese Chemical Letters, 2025, 36(2): 109751-. doi: 10.1016/j.cclet.2024.109751
3. [3]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
4. [4]
  Shuanglin TIAN , Tinghong GAO , Yutao LIU , Qian CHEN , Quan XIE , Qingquan XIAO , Yongchao LIANG . First-principles study of adsorption of Cl₂ and CO gas molecules by transition metal-doped g-GaN. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1189-1200. doi: 10.11862/CJIC.20230482
5. [5]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
6. [6]
  Xin Zhang , Junyu Chen , Xiang Pei , Linxin Yang , Liang Wang , Luona Chen , Guangmei Yang , Xibo Pei , Qianbing Wan , Jian Wang . Drug-loading ZIF-8 for modification of microporous bone scaffold to promote vascularized bone regeneration. Chinese Chemical Letters, 2024, 35(6): 108889-. doi: 10.1016/j.cclet.2023.108889
7. [7]
  Xuexia Lin , Yihui Zhou , Jiafu Hong , Xiaofeng Wei , Bin Liu , Chong-Chen Wang . Facile preparation of ZIF-8/ZIF-67-derived biomass carbon composites for highly efficient electromagnetic wave absorption. Chinese Chemical Letters, 2024, 35(9): 109835-. doi: 10.1016/j.cclet.2024.109835
8. [8]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
9. [9]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
10. [10]
  Fugui XI , Du LI , Zhourui YAN , Hui WANG , Junyu XIANG , Zhiyun DONG . Functionalized zirconium metal-organic frameworks for the removal of tetracycline from water. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 683-694. doi: 10.11862/CJIC.20240291
11. [11]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
12. [12]
  Haixia Wu , Kailu Guo . Iodized polyacrylonitrile as fast-charging anode for lithium-ion battery. Chinese Chemical Letters, 2024, 35(10): 109550-. doi: 10.1016/j.cclet.2024.109550
13. [13]
  Xinyu Ren , Hong Liu , Jingang Wang , Jiayuan Yu . Electrospinning-derived functional carbon-based materials for energy conversion and storage. Chinese Chemical Letters, 2024, 35(6): 109282-. doi: 10.1016/j.cclet.2023.109282
14. [14]
  Zhi Wang , Lingpeng Yan , Yelin Hao , Jingxia Zheng , Yongzhen Yang , Xuguang Liu . Highly efficient and photothermally stable CDs@ZIF-8 for laser illumination. Chinese Chemical Letters, 2024, 35(10): 109430-. doi: 10.1016/j.cclet.2023.109430
15. [15]
  Wenhao Wang , Guangpu Zhang , Qiufeng Wang , Fancang Meng , Hongbin Jia , Wei Jiang , Qingmin Ji . Hybrid nanoarchitectonics of TiO₂/aramid nanofiber membranes with softness and durability for photocatalytic dye degradation. Chinese Chemical Letters, 2024, 35(7): 109193-. doi: 10.1016/j.cclet.2023.109193
16. [16]
  Jiaojiao Liang , Youming Peng , Zhichao Xu , Yufei Wang , Menglong Liu , Xin Liu , Di Huang , Yuehua Wei , Zengxi Wei . Boron/phosphorus co-doped nitrogen-rich carbon nanofiber with flexible anode for robust sodium-ion battery. Chinese Chemical Letters, 2025, 36(1): 110452-. doi: 10.1016/j.cclet.2024.110452
17. [17]
  Cunjun Li , Wencong Liu , Xianlei Chen , Liang Li , Shenyu Lan , Mingshan Zhu . Adsorption and activation of peroxymonosulfate on BiOCl for carbamazepine degradation: The role of piezoelectric effect. Chinese Chemical Letters, 2024, 35(10): 109652-. doi: 10.1016/j.cclet.2024.109652
18. [18]
  Jie Ma , Jianxiang Wang , Jianhua Yuan , Xiao Liu , Yun Yang , Fei Yu . The regulating strategy of hierarchical structure and acidity in zeolites and application of gas adsorption: A review. Chinese Chemical Letters, 2024, 35(11): 109693-. doi: 10.1016/j.cclet.2024.109693
19. [19]
  Shuo Li , Xinran Liu , Yongjie Zheng , Jun Ma , Shijie You , Heshan Zheng . Effective peroxydisulfate activation by CQDs-MnFe₂O₄@ZIF-8 catalyst for complementary degradation of bisphenol A by free radicals and non-radical pathways. Chinese Chemical Letters, 2024, 35(5): 108971-. doi: 10.1016/j.cclet.2023.108971
20. [20]
  Shuqi Yu , Yu Yang , Keisuke Kuroda , Jian Pu , Rui Guo , Li-An Hou . Selective removal of Cr(Ⅵ) using polyvinylpyrrolidone and polyacrylamide co-modified MoS₂ composites by adsorption combined with reduction. Chinese Chemical Letters, 2024, 35(6): 109130-. doi: 10.1016/j.cclet.2023.109130

Get Citation

PDF

XML

Metrics

PDF Downloads(9)
Abstract views(766)
HTML views(97)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142