Citation: Teng-Yue MA, Jin-Ling AN, Peng ZHANG, Jin-Rong LIU, Wei-Yan HE. Synthesis and properties of P2-Na_2/3Mn_1/3Bi_1/3Ni_1/3O₂ as long-life and high voltage sodium-ion battery cathode[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(6): 1023-1030. doi: 10.11862/CJIC.2023.077 shu

Synthesis and properties of P2-Na_2/3Mn_1/3Bi_1/3Ni_1/3O₂ as long-life and high voltage sodium-ion battery cathode

School of Chemical Engineering, Inner Mongolia University of Technology, Hohhot 010051, China

Corresponding author: Wei-Yan HE, heweiyan@imut.edu.cn
Received Date: 11 January 2023
Revised Date: 18 April 2023

Figures(7)

Layered nickel-based cathode materials are of great interest due to their high voltage and specific capacities for sodium ion batteries. However, the Jahn-Teller effect is detrimental for achieving considerable cycling stability at high voltage (4.5 V) and rate capability. Herein, a P2-type Na_2/3Mn_1/3Bi_1/3Ni_1/3O₂ cathode material was synthesized by adjusting the process conditions of sol-gel, and used as positive active materials to assemble sodium ion battery in air environment. The improved cycling and rate performance under high voltage can be achieved by Mnsubstitution and Bi-substitution. In a wide voltage range of 1.2 to 4.5 V, the material maintained a specific discharge capacity of 90.39 mAh·g^-1 after 50 cycles. The cathode obtained a remarkable capacity retention of 96.96% after 50 cycles at 1C (115 mA·g^-1) and 80.15% capacity retention up to 850 cycles from 2.0 to 4.0 V. The above data indicate that the cathode materials own an extremely long cycling life and better rate capability.
- sodium-ion battery,
- nickel-based oxide,
- manganese doping,
- bismuth doping,
- electrochemical performance
1. [1]
  Pimlott J L, Street R J, Down M P, Banks C E. Electrochemical overview: A summary of ACo_xMn_yNi_zO₂ and metal oxides as versatile cathode materials for metal-ion batteries[J]. Adv. Funct. Mater., 2021,31(51)2107761. doi: 10.1002/adfm.202107761
2. [2]
  Xiang X D, Zhang K, Chen J. Recent advances and prospects of cathode materials for sodium-ion batteries[J]. Adv. Mater., 2015,27(36):5343-5364. doi: 10.1002/adma.201501527
3. [3]
  Wheeler S, Capone I, Day S, Tang C, Pasta M. Low-potential prussian blue analogues for sodium-ion batteries: Manganese hexacyanochromate[J]. Chem. Mater., 2019,31(7):2619-2626. doi: 10.1021/acs.chemmater.9b00471
4. [4]
  Delmas C, Fouassier C, Hagenmuller P. Structural classification and properties of the layered oxides[J]. Physica. B+C, 1980,99(1):81-85.
5. [5]
  Han M H, Gonzalo E, Singh G, Rojo T. A comprehensive review of sodium layered oxides: Powerful cathodes for Na-ion batteries[J]. Energy Environ. Sci., 2015,8(1):81-102. doi: 10.1039/C4EE03192J
6. [6]
  Park K, Yu B C, Goodenough J B. Electrochemical and chemical properties of Na₂NiO₂ as a cathode additive for a rechargeable sodium battery[J]. Chem. Mater., 2015,27(19):6682-6688. doi: 10.1021/acs.chemmater.5b02684
7. [7]
  Wang Y, Li W, Hu G, Peng Z D, Cao Y B, Gao H C, Du K, Goodenough J B. Electrochemical performance of large-grained NaCrO₂ cathode materials for Na-ion batteries synthesized by decomposition of Na₂Cr₂O₇·2H₂O[J]. Chem. Mater., 2019,31(14):5214-5223. doi: 10.1021/acs.chemmater.9b01456
8. [8]
  Khan M A, Han D, Lee G, Kim Y I, Kang Y M. P2/O3 phase-integrated Na_0.7MnO₂ cathode materials for sodium-ion rechargeable batteries[J]. J. Alloy. Compd., 2019,771:987-993. doi: 10.1016/j.jallcom.2018.09.033
9. [9]
  Gao L, Chen S, Hu H, Cheng H Y, Zhang L L, Yang X L. Hierarchical Na_xCoO₂ microspheres with low surface area toward high performance sodium ion batteries[J]. Mater. Lett., 2020,260126965. doi: 10.1016/j.matlet.2019.126965
10. [10]
  SUN Y Y, LI S Q, WANG C R, QIAN Y X, ZHENG S Y, YUAN T. Research proaress of lavered transition metal oxide cathode materials for sodium ion batteries[J]. Chinese Journal of Rare Metals, 2022,46(6):776-795.
11. [11]
  Wang L G, Wang J J, Zhang X Y, Ren Y, Zuo P J, Yin G P, Wang J. Unravelling the origin of irreversible capacity loss in NaNiO₂ for high voltage sodium ion batteries[J]. Nano Energy, 2017,34:215-223. doi: 10.1016/j.nanoen.2017.02.046
12. [12]
  Kaushalya R, Iyngaran P, Kuganathan N, Chroneos A. Defect, diffusion and dopant properties of NaNiO₂: Atomistic simulation study[J]. Energies, 2019,12(16)3094. doi: 10.3390/en12163094
13. [13]
  Komaba S, Yabuuchi N, Nakayama T, Ogata A, Ishikawa T, Nakai I. Study on the reversible electrode reaction of Na_1-xNi_0.5Mn_0.5O₂ for a rechargeable sodium-ion battery[J]. Inorg. Chem., 2012,51(11):6211-6220. doi: 10.1021/ic300357d
14. [14]
  Yu H, Guo S, Zhu Y, Ishida M, Zhou H. Novel titanium-based O3-type NaTi_0.5Ni_0.5O₂ as a cathode material for sodium ion batteries[J]. Chem. Commun., 2014,50(4):457-459. doi: 10.1039/C3CC47351A
15. [15]
  Kubota K, Yoda Y, Komaba S. Origin of enhanced capacity retention of P2-type Na_2/3Ni_1/3-xMn_2/3Cu_xO₂ for Na-ion batteries[J]. J. Electrochem. Soc., 2017,164(12):A2368-A2373. doi: 10.1149/2.0311712jes
16. [16]
  HEI W Y, ZHANG P, TENG Y Y, AN J L, MA T Y, LIU J R. Method for assembling sodium-ion half-cells in air: CN202111536441. X. 2022-03-22.
1. [1]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014
2. [2]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF模板法合成氮掺杂碳材料用于增强电化学钠离子储存和去除. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-. doi: 10.3866/PKU.WHXB202405002
3. [3]
  Yu Guo , Zhiwei Huang , Yuqing Hu , Junzhe Li , Jie Xu . 钠离子电池中铁基异质结构负极材料的最新研究进展. Acta Physico-Chimica Sinica, 2025, 41(3): 2311015-. doi: 10.3866/PKU.WHXB202311015
4. [4]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
5. [5]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
6. [6]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
7. [7]
  Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363
8. [8]
  Zhuo WANG , Xiaotong LI , Zhipeng HU , Junqiao PAN . Three-dimensional porous carbon decorated with nano bismuth particles: Preparation and sodium storage properties. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 267-274. doi: 10.11862/CJIC.20240223
9. [9]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050
10. [10]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
11. [11]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
12. [12]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
13. [13]
  Xiangyu CAO , Jiaying ZHANG , Yun FENG , Linkun SHEN , Xiuling ZHANG , Juanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270
14. [14]
  Shipeng WANG , Shangyu XIE , Luxian LIANG , Xuehong WANG , Jie WEI , Deqiang WANG . Piezoelectric effect of Mn, Bi co-doped sodium niobate for promoting cell proliferation and bacteriostasis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1919-1931. doi: 10.11862/CJIC.20240094
15. [15]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
16. [16]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
17. [17]
  Qianwen Han , Tenglong Zhu , Qiuqiu Lü , Mahong Yu , Qin Zhong . 氢电极支撑可逆固体氧化物电池性能及电化学不对称性优化. Acta Physico-Chimica Sinica, 2025, 41(1): 2309037-. doi: 10.3866/PKU.WHXB202309037
18. [18]
  Qinjin DAI , Shan FAN , Pengyang FAN , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Yong ZHANG . Performance of oxygen vacancy-rich V-doped MnO₂ for high-performance aqueous zinc ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 453-460. doi: 10.11862/CJIC.20240326
19. [19]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
20. [20]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447

Get Citation

PDF

XML

Metrics

PDF Downloads(24)
Abstract views(3976)
HTML views(955)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and properties of P2-Na2/3Mn1/3Bi1/3Ni1/3O2 as long-life and high voltage sodium-ion battery cathode

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis and properties of P2-Na_2/3Mn_1/3Bi_1/3Ni_1/3O₂ as long-life and high voltage sodium-ion battery cathode