Citation: Xuan WANG, Ji-Jiang WANG, Long TANG, Lao-Bang WANG, Er-Lin YUE, Chao BAI, Xiao WANG, Yu-Qi ZHANG. A stable Zinc(Ⅱ)metal-organic framework in water for the detection of tetracycline[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(6): 1151-1158. doi: 10.11862/CJIC.2023.069 shu

A stable Zinc(Ⅱ)metal-organic framework in water for the detection of tetracycline

Yan′an City Key Laboratory of New Energy & New Functional Materials, Shaanxi Key Laboratory of Chemical Reaction Engineering, College of Chemistry and Chemical Engineering, Yan′an University, Yan′an, Shaanxi 716000, China

Corresponding author: Ji-Jiang WANG, yadxwjj@126.com Long TANG, ydtanglong@163.com
Received Date: 24 December 2022
Revised Date: 18 March 2023

Figures(9)

A Zinc(Ⅱ) metal-organic framework (Zn-MOF), namely [Zn(H₂L)(4, 4′-bpy)]_n (1), where H₄L=1, 1′-ethylbi- phenyl-3, 3′, 5, 5′-tetracarboxylic acid, 4, 4′-bpy=4, 4′-bipyridine, was successfully synthesized under solvothermal conditions. The structure was characterized by single-crystal X-ray diffraction, elemental analysis, and thermogravi- metric analysis. The single crystal structure analysis shows that 1 belongs to the monoclinic C2/c space group and H ₂L^2- ligands adopt monodentate coordination mode, connecting with Zn(Ⅱ)to form 1D chains. Finally, the 1D chains are connected by 4, 4′-bpy to form a 2D wavelike network. 1 shows good stability in water, and can be used as a highly sensitive and selective fluorescent probe to detect tetracycline (TET) with a detection limit of 0.17 μmol· L^-1. 1 can be successfully used for the determination of tetracycline in Yanhe River water. In addition, the possible fluorescence quenching mechanisms of 1 were also studied. CCDC: 2212375, 1.
- metal-organic framework,
- crystal structure,
- tetracycline,
- fluorescent sensor
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