Citation: Yan-Yan AN, Li-Ping LU, Miao-Li ZHU. One Cd^Ⅱ-MOF as a multi-responsive fluorescent probe for sensing Fe(Ⅲ) and Cr(Ⅵ)[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(5): 939-946. doi: 10.11862/CJIC.2023.056 shu

One Cd^Ⅱ-MOF as a multi-responsive fluorescent probe for sensing Fe(Ⅲ) and Cr(Ⅵ)

Yan-Yan AN ^1,, ,
Li-Ping LU ² ,
Miao-Li ZHU ^2,,

1.
Department of Materials and Chemical Engineering, Taiyuan University, Taiyuan 030032, China
2.
Key Laboratory of Chemical Biology and Molecular Engineering of the Education Ministry, Institute of Molecular Science, Shanxi University, Taiyuan 030006, China

Corresponding author: Yan-Yan AN, anyanyan@tyu.edu.cn Miao-Li ZHU, miaoli@sxu.edu.cn
Received Date: 2 November 2022
Revised Date: 15 March 2023

Figures(7)

One metal-organic framework [Cd₃(L)₂(H₂O)₉]·9H₂O (MOF 1), where H₃L=5-(((4-carboxyphenyl)oxy)methyl) benzene-1,3-dicarboxylic acid, has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction, powder X-ray diffraction, and elemental analysis. MOF 1 exhibits a 2D microporous structure with an accessible volume of 22.4%. Luminescent property studies reveal that MOF 1 can act as a promising luminescent sensor for detecting Fe(Ⅲ) and Cr(Ⅵ) with high selectivities and low detection limits, which are additionally free from the interference of other ions. Moreover, the mechanism of selective quenching was studied by measuring the UV-Vis absorption of the host metal-organic framework and the target analyte ions. The fluorescence resonance energy transfer is the possible mechanism involved in the quenching of the fluorescence intensity.
- 5-(((4-carboxyphenyl)oxy)methyl)benzene-1,3-dicarboxylic acid,
- Cd^Ⅱ complex,
- crystal structure,
- fluorescence probe
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

One CdⅡ-MOF as a multi-responsive fluorescent probe for sensing Fe(Ⅲ) and Cr(Ⅵ)

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通讯作者: 陈斌, bchen63@163.com

One Cd^Ⅱ-MOF as a multi-responsive fluorescent probe for sensing Fe(Ⅲ) and Cr(Ⅵ)