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Citation: Wen-Min WANG, Na QIAO, Shan-Shan DONG, Ying CHEN, Xiao-Yan XIN, Guo-Li YANG, Ming FANG. Crystal structure, slow magnetic relaxation behavior and conversion CO2 of a tetranuclear Ho(Ⅲ)-based complex[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(5): 917-927. doi: 10.11862/CJIC.2023.053 shu

Crystal structure, slow magnetic relaxation behavior and conversion CO2 of a tetranuclear Ho(Ⅲ)-based complex

  • 1.

    College of Chemistry and Materials, Taiyuan Normal University, Jinzhong, Shanxi 030619, China

  • 2.

    Department of Chemistry and Chemical Engineering, Jinzhong University, Jinzhong, Shanxi 030619, China

  • 3.

    Department of Chemistry, Hebei Normal University of Science & Technology, Qinhuangdao, Hebei 066004, China

Figures(8)

  • A novel Ho4 complex, namely [Ho4(NO3)2(acac)4(L)2(CH3OH)2]·2CH3CN, where H4L=(E)-2-(hydroxymethyl)-2-(((2-hydroxynaphthalen-1-yl)methylene)amino)propane-1,3-diol and acac=acetylacetone, has been constructed by using a polydentate Schiff base ligand (H4L) reacting with Ho(acac)3·2H2O. X-ray diffraction analysis indicates that complex 1 shows a central symmetric tetranuclear structure. Both eight-coordinated Ho1(Ⅲ) and Ho2(Ⅲ) ions possess a distorted triangular dodecahedron geometrical configuration. Complex 1 shows good solvent stability. The magnetic study reveals that complex 1 exhibits a slow relaxation of the magnetization behavior. To our knowledge, complex 1 is a rarely Ho(Ⅲ)-based complex displaying slow magnetic relaxation behavior under Hdc=0 Oe filed. Interestingly, complex 1 exhibited high catalytic activity and could effectively catalyze the cycloaddition reaction of CO2 with vari-ous epoxides.
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