Citation: Jia-Xuan WANG, Liang-Qing LI, Lei MA, Jin-Yin LÜ, Jian-Hua YANG, Jin-Ming LU. Preparation of mordenite membrane for pervaporation dehydration of acetic acid by a two-stage varying temperature crystallization hydrothermal method[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(1): 91-97. doi: 10.11862/CJIC.2022.270 shu

Preparation of mordenite membrane for pervaporation dehydration of acetic acid by a two-stage varying temperature crystallization hydrothermal method

1.
State Key Laboratory of Fine Chemicals, Institute of Adsorption and Inorganic Membrane, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China
2.
Key Laboratory of Functional Membranes and Energy Materials, School of Chemistry and Chemical Engineering, Huangshan University, Huangshan, Anhui 245041, China

Corresponding author: Jian-Hua YANG, yjianhua@dlut.edu.cn
Received Date: 9 June 2022
Revised Date: 11 November 2022

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Pervaporation (PV) has been favorably adopted in the industrial dehydration of various organic mixtures. In this work, mordenite membrane (MOR membrane) for PV dehydration of acetic acid was prepared by a two-stage varying temperature crystallization hydrothermal method from dilute synthesis solution with a high molar ratio of water to silica (n_H₂O/n_SiO₂). The effects of varying temperature crystallization time, n_H₂O/n_SiO₂, and the amount of fluorine ion on the morphology and separation performance of MOR membrane were investigated. The results showed that the above conditions have significant effects on the morphology, crystallinity, membrane thickness, and PV performance of the MOR membranes. The best performance MOR membrane was prepared at first-stage temperature (150 ℃, 18 h) and second-stage temperature (120 ℃, 6 h) with n_H₂O/n_SiO₂=60. The permeation flux and separation coefficient of the mass fraction of 50% acetic acid aqueous solution were 1.45 kg·m^-2·h^-1 and 1 008, respectively.
- mordenite membrane,
- varying temperature crystallization,
- pervaporation,
- dehydration of acetic acid mixture
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沈阳化工大学材料科学与工程学院沈阳 110142