Citation: Chao HUANG, Kai-Teng WANG, Dong-Mei CHEN, Bi-Xue ZHU, Ji-Hong LU. Synthesis, Crystal Structures, Luminescence, and Vapor Adsorption Properties of 1D Mercury(Ⅱ) Coordination Polymers Based on Two Dipyridylamide Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(11): 2291-2298. doi: 10.11862/CJIC.2022.236 shu

Synthesis, Crystal Structures, Luminescence, and Vapor Adsorption Properties of 1D Mercury(Ⅱ) Coordination Polymers Based on Two Dipyridylamide Ligands

Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang 550025, China

Corresponding author: Ji-Hong LU, lujhgzu@163.com
Received Date: 10 April 2022
Revised Date: 30 August 2022

Figures(8)

Two coordination polymers, {[Hg₂(L¹) (μ₂-I)₂I₂] ·2DMF·H₂O}_n (1) and {[Hg(L²)I₂] ·H₂O}_n (2), have been designed and synthesized from two dipyridylamide ligands (L¹ and L²) with mercury(Ⅱ) iodide, respectively. X-ray crystallographic analyses show that both the two complexes exist as 1D zig-zag chain structures but exhibit different configurations by slightly adjusted 3-and 4-pyridyl nitrogen atoms from the ligands. Each Hg(Ⅱ) center of the two complexes is four-coordinated with distorted tetrahedral geometry. In complex 1, the Hg(Ⅱ) center is coordinated by one 3-pyridyl nitrogen atom and three iodide anions in a 1∶2 molar ratio of L¹ and mercury iodide. In complex 2, the Hg(Ⅱ) center is coordinated by two 4-pyridyl nitrogen atoms and two iodide anions in a 1∶1 molar ratio of L² and mercury iodide. In addition, the thermal stabilities, luminescence properties, together with vapor adsorption properties of the two complexes were investigated.
- coordination polymer,
- dipyridylamide,
- crystal structure,
- one-dimensional,
- vapor adsorption
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