Citation: Chao HUANG, Kai-Teng WANG, Dong-Mei CHEN, Bi-Xue ZHU, Ji-Hong LU. Synthesis, Crystal Structures, Luminescence, and Vapor Adsorption Properties of 1D Mercury(Ⅱ) Coordination Polymers Based on Two Dipyridylamide Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(11): 2291-2298. doi: 10.11862/CJIC.2022.236 shu

Synthesis, Crystal Structures, Luminescence, and Vapor Adsorption Properties of 1D Mercury(Ⅱ) Coordination Polymers Based on Two Dipyridylamide Ligands

Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang 550025, China

Corresponding author: Ji-Hong LU, lujhgzu@163.com
Received Date: 10 April 2022
Revised Date: 30 August 2022

Figures(8)

Two coordination polymers, {[Hg₂(L¹) (μ₂-I)₂I₂] ·2DMF·H₂O}_n (1) and {[Hg(L²)I₂] ·H₂O}_n (2), have been designed and synthesized from two dipyridylamide ligands (L¹ and L²) with mercury(Ⅱ) iodide, respectively. X-ray crystallographic analyses show that both the two complexes exist as 1D zig-zag chain structures but exhibit different configurations by slightly adjusted 3-and 4-pyridyl nitrogen atoms from the ligands. Each Hg(Ⅱ) center of the two complexes is four-coordinated with distorted tetrahedral geometry. In complex 1, the Hg(Ⅱ) center is coordinated by one 3-pyridyl nitrogen atom and three iodide anions in a 1∶2 molar ratio of L¹ and mercury iodide. In complex 2, the Hg(Ⅱ) center is coordinated by two 4-pyridyl nitrogen atoms and two iodide anions in a 1∶1 molar ratio of L² and mercury iodide. In addition, the thermal stabilities, luminescence properties, together with vapor adsorption properties of the two complexes were investigated.
- coordination polymer,
- dipyridylamide,
- crystal structure,
- one-dimensional,
- vapor adsorption
1. [1]
  Ovsyannikov A, Solovieva S, Antipin I, Ferlay S. Coordination Polymers Based on Calixarene Derivatives: Structures and Properties[J]. Coord. Chem. Rev., 2017,352:151-186. doi: 10.1016/j.ccr.2017.09.004
2. [2]
  Sun J K, Yang X D, Yang G Y, Zhang J. Bipyridinium Derivative-Based Coordination Polymers: From Synthesis to Materials Applications[J]. Coord. Chem. Rev., 2019,378:533-560. doi: 10.1016/j.ccr.2017.10.029
3. [3]
  Li N, Feng R, Zhu J, Chang Z, Bu X H. Conformation Versatility of Ligands in Coordination Polymers: From Structural Diversity to Properties and Applications[J]. Coord. Chem. Rev., 2018,375:558-586. doi: 10.1016/j.ccr.2018.05.016
4. [4]
  Liu J Q, Luo Z D, Pan Y, Singh A K, Trivedi M, Kumar A. Recent Developments in Luminescent Coordination Polymers: Designing Strategies, Sensing Application and Theoretical Evidences[J]. Coord. Chem. Rev., 2020,406213145. doi: 10.1016/j.ccr.2019.213145
5. [5]
  Tay H M, Kyratzis N, Thoonen S, Boer S A, Turner D R, Hua C. Synthetic Strategies towards Chiral Coordination Polymers[J]. Coord. Chem. Rev., 2021,435213763. doi: 10.1016/j.ccr.2020.213763
6. [6]
  Chen Y T, Ding Y, He S X, Huang C, Chen D M, Zhu B X. Synthesis, Crystal Structures and Vapor Adsorption Properties of Mercury(Ⅱ) Coordination Polymers Derived from Two Dipyridylamide Ligands[J]. Z. Anorg. Allg. Chem., 2021,647:623-628. doi: 10.1002/zaac.202000346
7. [7]
  Li J X, Qin Z B, Li Y H, Cui G H. Sonochemical Synthesis and Properties of Two New Nanostructured Silver Coordination Polymers[J]. Ultrason. Sonochem., 2018,48:127-135. doi: 10.1016/j.ultsonch.2018.05.016
8. [8]
  Zhang H, Liu G, Shi L, Liu H, Wang T, Ye J. Engineering Coordination Polymers for Photocatalysis[J]. Nano Energy, 2016,22:149-168. doi: 10.1016/j.nanoen.2016.01.029
9. [9]
  Rosa I M L, Costa M C S, Vitto B S, Amorim L, Correa C C, Pinheiro C B, Doriguetto A C. Influence of Synthetic Methods in the Structure and Dimensionality of Coordination Polymers[J]. Cryst. Growth Des., 2016,16:1606-1616. doi: 10.1021/acs.cgd.5b01716
10. [10]
  WANG L B, WANG J J, YUE E L, TANG L, WANG X, HOU X Y, ZHANG Y Q. Synthesis, Structure, Magnetic and Photocatalytic Properties of Nickel(Ⅱ) Coordination Polymer Based on 1-(3, 5-Dicar-boxybenzyl)-1H-pyrazole-3, 5-dicarboxylic Acid Ligand[J]. Chinese J. Inorg. Chem., 2021,37(4):744-750.
11. [11]
  Feng X, Guo N, Chen H, Wang H, Yue L, Chen X, Ng S W, Liu X, Ma L, Wang L. A Series of Anionic Host Coordination Polymers Based on Azoxybenzene Carboxylate: Structures, Luminescence and Magnetic Properties[J]. Dalton Trans., 2017,46:14192-14200. doi: 10.1039/C7DT02974H
12. [12]
  Fan L, Zhang Y, Liang J, Wang X, Lv H, Wang J, Zhao L, Zhang X. Structural Diversity, Magnetic Properties, and Luminescence Sensing of Five 3D Coordination Polymers Derived from Designed 3, 5-Di(2', 4'-dicarboxylphenyl)benozoic Acid[J]. CrystEngComm, 2018,20:4752-4762. doi: 10.1039/C8CE00877A
13. [13]
  Yang X G, Zhai Z M, Lu X M, Zhao Y, Chang X H, Ma L F. Room Temperature Phosphorescence of Mn(Ⅱ) and Zn(Ⅱ) Coordination Polymers for Photoelectron Response Applications[J]. Dalton Trans., 2019,48:10785-10789. doi: 10.1039/C9DT02178G
14. [14]
  YANG X Q, HE C Y, ZHANG Y H, MU X G, JIANG S. Synthesis, Crystal Structure and Properties of Mn(Ⅱ)/Co(Ⅱ) Coordination Polymers Based on 1, 4-Bis(imidazol-1-yl) benzene[J]. Chinese J. Inorg. Chem., 2021,37(8):1364-1374.
15. [15]
  Tzeng B C, Chang T Y, Wei S L, Sheu H S. Reversible Phase Transformation and Mechanochromic Luminescence of Zn^Ⅱ-Dipyridylamide-Based Coordination Frameworks[J]. Chem. Eur. J., 2012,18:5105-5112. doi: 10.1002/chem.201103405
16. [16]
  Liu G C, Li Y, Xiong Y, Liu X X, Li Q M, Zhang J W, Lin H Y, Li X W. Spacers-Directed Structural Diversity of Co(Ⅱ)/Zn(Ⅱ) Complexes Based on S-/O-Bridged Dipyridylamides: Electrochemical, Fluorescent Recognition Behavior and Photocatalytic Properties[J]. J. Coord. Chem., 2018,71:483-501. doi: 10.1080/00958972.2018.1438606
17. [17]
  Cardile S A, Burchell T J, Jennings M C, Puddephatt R J. Self-Assembly of Polymers through Dynamic Coordination Chemistry and Hydrogen Bonding: Polymers from Mercury (Ⅱ) Halides and Bis(amidopyridine) Ligands[J]. J. Inorg. Organomet. Polym. Mater., 2007,17:235-240. doi: 10.1007/s10904-006-9088-x
18. [18]
  Fletcher B E, Peach M J G, Evans N H. Rapidly Accessible"Click" Rotaxanes Utilizing a Single Amide Hydrogen Bond Templating Motif[J]. Org. Biomol. Chem., 2017,15:2797-2803. doi: 10.1039/C7OB00284J
19. [19]
  Han L, Zhang K, Ishida H, Froimowicz P. Study of the Effects of Intramolecular and Intermolecular Hydrogen-Bonding Systems on the Polymerization of Amide-Containing Benzoxazines[J]. Macromol. Chem. Phys., 2017,2181600562. doi: 10.1002/macp.201600562
20. [20]
  Henderson W R, Kumar A, Abboud K A, Castellano R K. Influence of Amide Connectivity on the Hydrogen-Bond-Directed Self-Assembly of [n. n]Paracyclophanes[J]. Chem. Eur. J., 2020,26:17588-17597. doi: 10.1002/chem.202003909
21. [21]
  Markad D, Mandal S K. An Exploration into the Amide-Pseudo Amide Hydrogen Bonding Synthon between a New Coformer with Two Primary Amide Groups and Theophylline[J]. CrystEngComm, 2017,19:7112-7124. doi: 10.1039/C7CE01666B
22. [22]
  Kaneko R, Wu G, Sugawa K, Otsuki J. Intermolecular Electronic Communication in Tetrathiafulvalene Derivatives with Hydrogen-Bonding Amide Units[J]. J. Org. Chem., 2018,7:897-901.
23. [23]
  Sheldrick G M. SHELXT-Integrated Space-Group and Crystal-Structure Determination[J]. Acta Crystallogr. Sect. A, 2015,A71:3-8.
24. [24]
  Dolomanov O V, Bourhis L J, Gildea R J, Howard J A K, Puschmann H. OLEX2: A Complete Structure Solution, Refinement and Analysis Program[J]. J. Appl. Cryst., 2009,42:339-341. doi: 10.1107/S0021889808042726
25. [25]
  Yang L, Powell D R, Houser R P. Structural Variation in Copper(Ⅰ) Complexes with Pyridylmethylamide Ligands: Structural Analysis with a New Four-Coordinate Geometry Index, τ₄[J]. Dalton Trans., 2007:955-964.
26. [26]
  Lin L Z, Zhong Q X, Hong J T, Chen H L, Chen W T. Syntheses, Structures, Photoluminescence and Semiconductor Properties of Two Novel Mercury-Lanthanide Complexes with a Three-Dimensional Open Framework[J]. Inorg. Chim. Acta, 2018,479:30-35. doi: 10.1016/j.ica.2018.04.039
27. [27]
  Heering C, Francis B, Nateghi B, Makhloufi G, Lüdeke S, Janiak C. Syntheses, Structures and Properties of Group 12 Element (Zn, Cd, Hg) Coordination Polymers with a Mixed-Functional Phosphonate-Biphenylcarboxylate Linker[J]. CrystEngComm, 2016,18:5209-5223. doi: 10.1039/C6CE00587J
28. [28]
  Bigdeli F, Hosseini-Monfared H, Morsali A, Mayer P. Synthesis of a New Hg(Ⅱ) Coordination Polymer: Ultrasonic-Assisted Synthesis and Mechanical Preparation of Nanostructure[J]. Ultrason. Sonochem., 2017,39:669-675. doi: 10.1016/j.ultsonch.2017.03.055
29. [29]
  Chhetri P M, Yang X K, Chen J D. Isostructural Hg(Ⅱ) Halide Coordination Polymers: A Comparison of Powder XRD, IR, Emission and Hirshfeld Surface Analysis[J]. J. Mol. Struct., 2021,1239130543. doi: 10.1016/j.molstruc.2021.130543
30. [30]
  Xu C, Li L, Wang Y, Guo Q, Wang X, Hou H, Fan Y. Three-Dimensional Cd(Ⅱ) Coordination Polymers Based on Semirigid Bis(methyl-benzimidazole) and Aromatic Polycarboxylates: Syntheses, Topological Structures and Photoluminescent Properties[J]. Cryst. Growth Des., 2011,11:4667-4675. doi: 10.1021/cg200961a
31. [31]
  Huang C, Yang J, Chen J L, Chen D M, Zhu B X. Synthesis and Crystal Structures of Metallomacrocyclic and Helical Hg(Ⅱ) Complexes with Two Bis(pyridylurea) Ligands[J]. Inorg. Chim. Acta, 2018,483:252-257. doi: 10.1016/j.ica.2018.08.020
32. [32]
  Huang C, Luo X, Zhai J, Chen Y, Chen D M, Zhu B X. [2+2] or[4+ 4] Metallamacrocycle: Synthesis and Crystal Structures of Hg(Ⅱ) Complexes Derived from Two Flexible Bis(pyridylurea) Ligands[J]. Polyhedron, 2019,165:111-115. doi: 10.1016/j.poly.2019.03.012
33. [33]
  Chen D M, Wu X F, Liu Y J, Huang C, Zhu B X. Synthesis, Crystal Structures and Vapor Adsorption Properties of Hg(Ⅱ) and Cd(Ⅱ) Coordination Polymers Derived from Two Hydrazone Schiff Base Ligands[J]. Inorg. Chim. Acta, 2019,494:181-186. doi: 10.1016/j.ica.2019.05.026
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