Citation: Yang-Zheng CAO, Wei PAN, Chuan-Jiang ZHOU, Jun-Yong ZHANG, Hao XU, Chun-Hua GONG, Hui-Ting XU, Run-Pu SHEN, Sui-Jun LIU, Jing-Li XIE. A Series of Metal-Organic Frameworks Based on Mixed Ligand Strategy: Synthesis, Structures, and Properties[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(11): 2143-2153. doi: 10.11862/CJIC.2022.229 shu

A Series of Metal-Organic Frameworks Based on Mixed Ligand Strategy: Synthesis, Structures, and Properties

Yang-Zheng CAO ^{1, 4} ,
Wei PAN ¹ ,
Chuan-Jiang ZHOU ¹ ,
Jun-Yong ZHANG ^1,, ,
Hao XU ¹ ,
Chun-Hua GONG ^2,, ,
Hui-Ting XU ³ ,
Run-Pu SHEN ³ ,
Sui-Jun LIU ⁴ ,
Jing-Li XIE ^4,,

1.
College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing, Zhejiang 314001, China
2.
College of Advanced Materials Engineering, Jiaxing Nanhu University, Jiaxing, Zhejiang 314001, China
3.
Zhejiang Engineering Research Center of Fat - Soluble Vitamin, Shaoxing University, Shaoxing, Zhejiang 312000, China
4.
School of Chemistry and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou, Jiangxi 341000, China

Corresponding author: Jun-Yong ZHANG, zhangjy@mail.zjxu.edu.cn Chun-Hua GONG, gongch@jxnhu.edu.cn Jing-Li XIE, jlxie@mail.zjxu.edu.cn
Received Date: 20 April 2022
Revised Date: 15 September 2022

Figures(9)

Taking advantage of a basic ligand (BPCH=2, 6 -bis(4-pyridyl methylidene)cyclohexanone) and three acid ligands (H₂TP=terephthalic acid, H₂IP=isophthalic acid, H₃TMA=1, 3, 5 - benzenetricarboxylic acid), seven metal - organic frameworks (MOFs) 1-7 have been achieved by using this acid - base mixed - ligand synthetic strategy. These complexes were characterized by single-crystal X-ray diffraction, IR spec- tra, powder X-ray diffraction, and thermogravimetric analysis. Diverse 3D structural characters of MOFs 1-3 or 2D structural characters of MOFs 4-7 have been observed. The fluorescence properties of these complexes have been explored, indicating that they had selectivity towards Fe³⁺ ions. Several complexes had shown certain performance for adsorbing dye molecules.
- metal-organic frameworks,
- mixed-ligand strategy,
- fluorescence,
- dye adsorption
1. [1]
  Oisaki K, Li Q, Furukawa H, Czaja A U, Yaghi O M. A Metal-Organic Framework with Covalently Bound Organometallic Complexes[J]. J. Am. Chem. Soc., 2010,132:9262-9264. doi: 10.1021/ja103016y
2. [2]
  Kitagawa S, Kitaura R, Noro S. Functional Porous Coordination Polymers[J]. Angew. Chem. Int. Ed., 2004,43:2334-2375. doi: 10.1002/anie.200300610
3. [3]
  Peng P, Li F F, Neti V S P K, Metta-Magana A J, Echegoyen L. Design, Synthesis, and X-ray Crystal Structure of a Fullerene-Linked Metal-Organic Framework[J]. Angew. Chem. Int. Ed., 2014,53:160-163. doi: 10.1002/anie.201306761
4. [4]
  Wang X N, Zhang P, Kirchon A, Li J L, Chen W M, Zhao Y M, Li B, Zhou H C. Crystallographic Visualization of Postsynthetic Nickel Clusters into Metal-Organic Framework[J]. J. Am. Chem. Soc., 2019,141:13654-13663. doi: 10.1021/jacs.9b06711
5. [5]
  Xiao J D, Jiang H L. Metal -Organic Frameworks for Photocatalysis and Photothermal Catalysis[J]. Acc. Chem. Res., 2019,52:356-366. doi: 10.1021/acs.accounts.8b00521
6. [6]
  Yoon M, Srirambalaji R, Kim K. Homochiral Metal-Organic Frameworks for Asymmetric Heterogeneous Catalysis[J]. Chem. Rev., 2012,112:1196-1231. doi: 10.1021/cr2003147
7. [7]
  Li H, Wang K C, Sun Y J, Lollar C T, Li J L, Zhou H C. Recent Advances in Gas Storage and Separation Using Metal-Organic Frameworks[J]. Mater. Today, 2018,21:108-121. doi: 10.1016/j.mattod.2017.07.006
8. [8]
  Li J, Jiang L, Chen S, Kirchon A, Li B, Li Y, Zhou H C. Metal-Organic Framework Containing Planar Metal-Binding Sites: Efficiently and Cost-Effectively Enhancing the Kinetic Separation of C₂H₂/C₂H₄[J]. J. Am. Chem. Soc., 2019,141:3807-3811. doi: 10.1021/jacs.8b13463
9. [9]
  Mi X N, Sheng D F, Yu Y, Wang Y H, Zhao L M, Lu J, Li Y W, Li D C, Dou J M, Duan J G, Wang S N. Tunable Light Emission and Multiresponsive Luminescent Sensitivities in Aqueous Solutions of Two Series of Lanthanide Metal-Organic Frameworks Based on Structurally Related Ligands[J]. ACS Appl. Mater. Interfaces, 2019,11:7914-7926. doi: 10.1021/acsami.8b18320
10. [10]
  Yang X G, Ma L F, Yan D P. Facile Synthesis of 1D Organic-Inorganic Perovskite Micro-belts with High Water Stability for Sens-ing and Photonic Applications[J]. Chem. Sci., 2019,10:4567-4572. doi: 10.1039/C9SC00162J
11. [11]
  Zhao F, Guo X Y, Dong Z P, Liu Z L, Wang Y Q. 3D Ln^Ⅲ-MOFs: Slow Magnetic Relaxation and Highly Sensitive Luminescence Detection of Fe³⁺ and Ketones[J]. Dalton Trans., 2018,47:8972-8982. doi: 10.1039/C8DT01034J
12. [12]
  Wang H Y, Ge J Y, Hua C, Jiao C Q, Wu Y, Leong C F, D'Alessandro D M, Liu T, Zuo J L. Photo-and Electronically Switchable Spin-Crossover Iron(Ⅱ) Metal-Organic Frameworks Based on a Tetrathia-fulvalene Ligand[J]. Angew. Chem. Int. Ed., 2017,56:5465-5470. doi: 10.1002/anie.201611824
13. [13]
  Coronado E, Espallargas G M. Dynamic Magnetic MOFs[J]. Chem. Soc. Rev., 2013,42:1525-1539. doi: 10.1039/C2CS35278H
14. [14]
  Lustig W P, Mukherjee S, Rudd N D, Desai A V, Li J, Ghosh S K. Metal-Organic Frameworks: Functional Luminescent and Photonic Materials for Sensing Applications[J]. Chem. Soc. Rev., 2017,46:3242-3285.
15. [15]
  Easun T L, Jia J, Calladine J A, Blackmore D L, Stapleton C S, Vuong K Q, Champness N R, George M W. Photochemistry in a 3D Metal-Organic Framework (MOF): Monitoring Intermediates and Reactivity of the fac -to-mer Photoisomerization of Re(diimine)(CO)₃Cl Incorporated in a MOF[J]. Inorg. Chem., 2014,53:2606-2612. doi: 10.1021/ic402955e
16. [16]
  Zou J Y, Li L, You S Y, Chen K H, Dong X N, Chen Y H, Cui J Z. A usf Zinc(Ⅱ) Metal -Organic Framework as a Highly Selective Luminescence Probe for Acetylacetone Detection and Its Postsynthetic Cation Exchange[J]. Cryst. Growth Des., 2018,18:3997-4003. doi: 10.1021/acs.cgd.8b00344
17. [17]
  Huang R W, Wei Y S, Dong X Y, Wu X H, Du C X, Zang S Q, Mak T C W. Hypersensitive Dual-Function Luminescence Switching of a Silver-Chalcogenolate Cluster -Based Metal -Organic Framework[J]. Nat. Chem., 2017,9:689-697. doi: 10.1038/nchem.2718
18. [18]
  Huang W, Hu G B, Yao L Y, Yang Y, Liang W B, Yuan R, Xiao D R. Matrix Coordination-Induced Electrochemiluminescence Enhancement of Tetraphenylethylene-Based Hafnium Metal-Organic Framework: An Electrochemiluminescence Chromophore for Ultrasensitive Electrochemiluminescence Sensor Construction[J]. Anal. Chem., 2020,92:3380-3387.
19. [19]
  Du M, Li C P, Liu C S, Fang S M. Design and Construction of Coordination Polymers with Mixed -Ligand Synthetic Strategy[J]. Coord. Chem. Rev., 2013,257:1282-1305.
20. [20]
  Yin Z, Zhou Y L, Zeng M H, Kurmoo M. The Concept of Mixed Organic Ligands in Metal-Organic Frameworks: Design, Tuning and Functions[J]. Dalton Trans., 2015,44:5258-5275.
21. [21]
  Bhattacharyya S, Maji T K. Multi-Dimensional Metal-Organic Frameworks Based on Mixed Linkers: Interplay between Structural Flexibility and Functionality[J]. Coord. Chem. Rev., 2022,469214645.
22. [22]
  Zhang Y J, Gao L L, Zhou W D, Wei X Q, Hu T P. Synthesis and Magnetic Properties of Two Mn-based Coordination Polymers Constructed by a Mixed-Ligand Strategy[J]. CrystEngComm, 2020,22:7123-7128.
23. [23]
  Yu G H, Yang C L, Zhao H L, Yu A X, Zhang G, Du D Y, Su Z M. Mixed-Linker Strategy for the Construction of Metal-Organic Framework Combined with Dyes toward Alcohol Detection[J]. Inorg. Chem., 2022,61:5318-5325.
24. [24]
  Sheldrick G M. Crystal Structure Refinement with SHELXL[J]. Acta Crystallogr. Sect. C, 2015,C71:3-8.
25. [25]
  Spek A L. PLATON SQUEEZE: A Tool for the Calculation of the Disordered Solvent Contribution to the Calculated Structure Factors[J]. Acta Crystallogr. Sect. C, 2015,C71:9-18.
26. [26]
  Zhao D, Liu X H, Zhao Y, Wang P, Liu Y, Azam M, Al-Resayes S I, Lu Y, Sun W Y. Luminescent Cd(Ⅱ)-Organic Frameworks with Chelating NH₂ Sites for Selective Detection of Fe(Ⅲ) and Antibiotics[J]. J. Mater. Chem. A, 2017,5:15797-15807.
27. [27]
  Wang Y, Xu P, Xie Q, Ma Q Q, Meng Y H, Wang Z W, Zhang S, Zhao X J, Chen J, Wang Z L. Cadmium(Ⅱ)-Triazole Framework as a Luminescent Probe for Ca²⁺ and Cyano Complexes[J]. Chem. Eur. J., 2016,22:10459-10474.
28. [28]
  Liu W L, Yu J H, Jiang J H, Yuan L M, Xu B, Liu Q A, Qu B T, Zhang G Q, Yan C G. Hydrothermal Syntheses, Structures and Luminescent Properties of Zn(Ⅱ) Coordination Polymers Assembled with Benzene-1, 2, 3-Tricarboxylic Acid Involving In Situ Ligand Reactions[J]. CrystEngComm, 2011,13:2764-2773.
29. [29]
  Xu H, Zeng X H, Pan W, Zhang J Y, Cao Y Z, Guo H Y, Xie J L. Structural Diversity of Metal-Organic Frameworks Based on a Chalcone Dicarboxylic Acid Ligand[J]. Dalton Trans., 2020,49:5783-5786.
30. [30]
  Pan W, Gong C H, Zeng X H, Hu C Y, Zhang Y, Zhu D R, Xu H, Guo H Y, Zhang J Y, Xie J L. Assembly of Porous Lanthanide Metal-Organic Frameworks Constructed by Chalcone Dicarboxylic Acid and Exploration of Their Properties[J]. Polyhedron, 2019,169:24-31.
31. [31]
  PAN W, MA C X, ZHOU C J, ZHANG L, ZHANG J Y, SHI Y B, XU H, ZHU D R, XIE J L. Synthesis and Characterization of Metal-Organic Framework Based on 2, 6-Bis(4-carboxybenzylidene)cyclo-hexanone[J]. Chinese J. Inorg. Chem., 2021,37(5):953-960.
32. [32]
  Zhang J Y, Gong C H, Zeng X H, Xie J L. Continuous Flow Chemistry: New Strategies for Preparative Inorganic Chemistry[J]. Coord. Chem. Rev., 2016,324:39-53.
33. [33]
  Zhang J Y, Chang S Q, Suryanto B H R, Gong C H, Zeng X H, Zhao C, Zeng Q D, Xie J L. Efficient Synthesis of Ir-Polyoxometalate Cluster Using a Continuous Flow Apparatus and STM Investigation of Its Coassembly Behavior on HOPG Surface[J]. Inorg. Chem., 2016,55:5585-5591.
34. [34]
  Gong C H, Zhang J Y, Zeng X H, Xie J L. Highly Effective Synthesis of a Cobalt(Ⅱ) Metal-Organic Coordination Polymer by Using Continuous Flow Chemistry[J]. Dalton Trans., 2017,46:25-28.
35. [35]
  Xie J L, Zhao D Y. Continuous-Flow Photochemistry: An Expanding Horizon of Sustainable Technology[J]. Chin. Chem. Lett., 2020,31:2395-2400.
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