Citation: Kai-Min WANG, Li-Feng LI, Ming-Feng SHI, Yan-Qing YE, Yu-Na WANG, Jin-Rong GUO, Huai-Jun TANG, Yu-Lu MA. Crystal Structure of Eu(Ⅲ) Coordination Polymer Based on Zwitterionic Ligand and Detection of Furacilin[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(9): 1843-1852. doi: 10.11862/CJIC.2022.196 shu

Crystal Structure of Eu(Ⅲ) Coordination Polymer Based on Zwitterionic Ligand and Detection of Furacilin

1.
School of Chemistry & Environment, Yunnan Minzu University, Kunming 650504, China
2.
School of Pharmaceutical Sciences and Yunnan Key Laboratory of Pharmacology for Natural Products, Kunming Medical University, Kunming 650500, China

Corresponding author: Yan-Qing YE, yey-qing@163.com Yu-Na WANG, kyyxywyn@163.com Yu-Lu MA, yuluma163@163.com
Received Date: 22 February 2022
Revised Date: 1 August 2022

Figures(8)

A novel coordination polymer, {[Eu(L)₂(H₂O) ₄]Cl₃·2H₂O}_n (1) (L=1, 1'-((2, 3, 5, 6-tetramethyl-1, 4-phenylene) bis(methylene))bis(pyridin-1-ium-4-carboxylate)), was synthesized under hydrothermal conditions by a zwitterionic organic ligand and characterized by single crystal X-ray diffraction. Powder X-ray diffraction, IR, thermogravimetry, and luminescence properties of 1 were also determined. The solid-state luminescence properties of 1 were investigated, realizing the zwitterionic ligand is an excellent antenna chromophore for sensitizing Eu³⁺ ions. In addition, this water-stable 1 was utilized as a chemosensor to detect various common antibiotics to find that this one can exhibit high selectivity, sensitivity, and recyclability in the detection of furacilin molecules in aqueous phases.
- Eu(Ⅲ) complex,
- coordination polymer,
- zwitterionic ligand,
- fluorescence recognition,
- furacilin
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