Citation: Xue-Zhi GAO, Huan SONG, Bing LI, Rui WANG, Xiao-Shuang ZHU, Xiao-Yan TIAN. Synthesis, Crystal Structure, and Catalytic Performance of a Cd(Ⅱ) Complex Based on 3-Carboxyl-5-ammino-1, 2, 4-triazole[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(9): 1808-1816. doi: 10.11862/CJIC.2022.193 shu

Synthesis, Crystal Structure, and Catalytic Performance of a Cd(Ⅱ) Complex Based on 3-Carboxyl-5-ammino-1, 2, 4-triazole

Xue-Zhi GAO ^{1, 2} ,
Huan SONG ^{1, 2} ,
Bing LI ^{1, 2,,} ,
Rui WANG ^{1, 2} ,
Xiao-Shuang ZHU ^{1, 2} ,
Xiao-Yan TIAN ^{1, 2}

1.
State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering, Ningxia University, Yinchuan 750021, China
2.
Department of Chemistry & Chemical Engineering, Ningxia University, Yinchuan 750021, China

Corresponding author: Bing LI, nxdaxue@126.com
Received Date: 23 December 2021
Revised Date: 28 June 2022

Figures(6)

Triazole -derived energetic complexes have paid significant attention in the field of energetic materials. An energetic complex [Cd(Hatzc)₂(H₂O)] (LH1) (H₂atzc=3-carboxyl-5-amino-1, 2, 4-triazole) was synthesized and fully characterized by single crystal X-ray diffraction, elemental analysis, infrared spectral analysis, and thermogravimetric analysis. LH1 belongs to the monoclinic system, space group P2₁/n. The structural analyses illustrate that LH1 exhibits a 1D chain, which is linked by hydrogen-bonding interactions to give a 3D supramolecular architecture. Complex LH1 had high detonation velocity (D=10.4 km·s^-1), detonation pressure (p =55.2 GPa), energy of detonation (16.51 kJ·g^-1), and density (2.363 g·cm^-3), which were superior to most of the energetic compounds. The impact sensitivity (> 40 J) and friction sensitivity (> 360 N) reveal that LH1 is less sensitive to impact and friction. The results of the catalytic thermal decomposition of ammonium perchlorate (AP) show that LH1 decreased the higher thermal decomposition temperature of AP by 38 ℃ and increased the exothermic quantity of decomposition by 0.46 kJ·g^-1 in a short time, which showed a good catalytic effect on the thermal decomposition of AP.
- energetic complex,
- 3-carboxyl-5-amino-1, 2, 4-triazole,
- thermal decomposition,
- ammonium perchlorate
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