Citation: Hui-Yan FANG, Jing-Chuang ZHAO, Xian-Yu KANG, Yan-Cai LI. Ni/Biomass-Derived Nitrogen-Doped Porous Carbon Nanocomposites: Preparation and Electrocatalysis for Methanol Oxidation Reaction[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(10): 1959-1969. doi: 10.11862/CJIC.2022.188 shu

Ni/Biomass-Derived Nitrogen-Doped Porous Carbon Nanocomposites: Preparation and Electrocatalysis for Methanol Oxidation Reaction

Hui-Yan FANG ¹ ,
Jing-Chuang ZHAO ¹ ,
Xian-Yu KANG ¹ ,
Yan-Cai LI ^{1, 2, 3,,}

1.
College of Chemistry, Chemical Engineering and Environment, Minnan Normal University, Zhangzhou, Fujian 363000, China
2.
Fujian Province Key Laboratory of Modern Analytical Science and Separation Technology, Minnan Normal University, Zhangzhou, Fujian 363000, China
3.
Fujian Provincial University Key Laboratory of Pollution Monitoring and Control, Minnan Normal University, Zhangzhou, Fujian 363000, China

Corresponding author: Yan-Cai LI, liyancai@mnnu.edu.cn
Received Date: 3 March 2022
Revised Date: 14 July 2022

Figures(9)

The low-cost nickel nanoparticles/towel gourd derived nitrogen-doped porous carbon nanocomposites (Ni/T-dNPCN) were prepared with Ni(Ac)₂·4H₂O and towel gourd by impregnation and then pyrolysis. The electrocatalytic performance of the nanocomposites for methanol oxidation reaction (MOR) was studied, and the effect of pyrolysis temperature on its structure and properties was also discussed. The results demonstrated that the Ni/T-dNPCN modified glassy carbon electrode (Ni/T-dNPCN/GCE) exhibited well electrocatalytic activity for MOR in alkaline electrolytes. Among them, Ni/T-dNPCN₈₀₀/GCE possessed the best catalytic performance with the lowest onset potential (0.344 V (vs Ag/AgCl)), the highest catalytic current density (mass activity: 1 902 mA·mg_Ni^-1; specific activity: 1.61 mA·cm^-2) and the fastest kinetics process (Tafel slope: 50.23 mV·dec^-1), its catalytic activity was about 3.92 times that of the commercial Pt/C catalyst modified glassy carbon electrode. And according to the chronoamperometry test, Ni/T-dNPCN₈₀₀/GCE displayed good stability.
- direct methanol fuel cell,
- methanol oxidation reaction,
- biomass-derived carbon,
- nickel-based nanocomposites,
- alkaline electrolyte
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