Citation: Ling-Wen ZHANG, Shu-Qin LIU, Pei-Pei ZHANG, Ai-Yun NI, Jian-Jun ZHANG. Synthesis, Crystal Structure, and Detection of Acidic Amino Acids of a Cd(Ⅱ) Metal-Organic Framework Based on 5-((Naphthalen-1-ylmethyl)amino)isophthalic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(9): 1871-1877. doi: 10.11862/CJIC.2022.181 shu

Synthesis, Crystal Structure, and Detection of Acidic Amino Acids of a Cd(Ⅱ) Metal-Organic Framework Based on 5-((Naphthalen-1-ylmethyl)amino)isophthalic Acid

School of Chemical Engineering, Dalian University of Technology, Dalian, Liaoning 116024, China

Corresponding author: Shu-Qin LIU, shuqinliu@163.com Jian-Jun ZHANG, zhangjj@dlut.edu.cn
Received Date: 24 March 2022
Revised Date: 18 May 2022

Figures(5)

A 2D layered metal-organic framework [Cd(L) (H₂O)]·H₂O (1) was synthesized from 5-((naphthalen-1-ylmethyl)amino)isophthalic acid (H₂L) and Cd²⁺ by a solvothermal method. Structural analysis reveals that the adjacent layers are connected by π-π stacking and C—H⋯π interactions to form a 3D supramolecular structure. Notably, the luminescence of 1 was significantly enhanced under acidic conditions, which can be used for selective and sensitive detection of acidic amino acids. The limits of detection of 1 for aspartic acid and glutamic acid were 3.88 and 5.43 μmol·L^-1, respectively.
- metal-organic framework,
- crystal structure,
- luminescence,
- acidic amino acids,
- detection
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