Citation: Xiang-Wen WANG. Layered Hexagonal Co_1-xS Decorating N-Doped Carbon Nanotubes as a Sulfur Host for Li-S Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(10): 2065-2071. doi: 10.11862/CJIC.2022.180 shu

Layered Hexagonal Co_1-xS Decorating N-Doped Carbon Nanotubes as a Sulfur Host for Li-S Batteries

Xiang-Wen WANG

Department of Food Engineering, Dezhou Vocational and Technical College, Dezhou, Shandong 253034, China

Author Bio: E-mail: wxw_wyy@sina.com
Received Date: 25 February 2022
Revised Date: 10 July 2022

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The design and assembly of nanostructured materials are devoted to improving the electrochemical properties of the Li-S batteries (LSBs) by synergistic effect. In this work, a composite of hexagonal Co_1-xS nanosheets decorating N-doped carbon nanotube (Co_1-xS-CNT) was successfully synthesized and used as a sulfur host for Li-S batteries (LSBs). In Co_1-xS-CNT/S, the polar hexagonal Co_1-xS nanosheets can absorb the lithium polysulfide through chemisorption, at the same time, the CNT can provide a highly conductive network. Based on the synergy of physical encapsulating and chemical trapping, the Co_1-xS-CNT/S cathode exhibited excellent electrochemical performance, especially the superior cycle performance. After 170 cycles, the Co_1-xS-CNT/S can maintain a discharge capacity of 405.6 mAh·g^-1 at 0.5C, with a stable Coulombic efficiency (over 99.2%).
- Li-S batteries,
- hexagonal Co_1-xS nanosheets,
- cathode,
- carbon nanotube,
- chemisorption
1. [1]
  Manthiram A, Fu Y Z, Chung S H, Zu C X, Su Y S. Rechargeable Lithium-Sulfur Battery[J]. Chem. Rev., 2014,114:11751-11787. doi: 10.1021/cr500062v
2. [2]
  Armand M, Tarascon J M. Building Better Batteries[J]. Nature, 2008,451:652-657. doi: 10.1038/451652a
3. [3]
  Hosono E, Fujihara S, Honma I, Ichihara M, Zhou H. Synthesis of the CoOOH Fine Nanoflake Film with the High Rate Capacitance Property[J]. J. Power Sources, 2006,158:779-783. doi: 10.1016/j.jpowsour.2005.09.052
4. [4]
  Huang J H, Chen J T, Yao T, He J F, Jiang S, Sun Z H, Liu Q H, Cheng W, Hu F, Jiang Y, Pan Z Y, Wei S Q. CoOOH Nanosheets with High Mass Activity for Water Oxidation[J]. Angew. Chem. Int. Ed., 2015,54:8722-8727. doi: 10.1002/anie.201502836
5. [5]
  Wang Z Y, Wang L, Liu S, Li G R, Gao X P. Conductive CoOOH as Carbon-Free Sulfur Immobilizer to Fabricate Sulfur-Based Composite for Lithium-Sulfur Battery[J]. Adv. Funct. Mater., 2019,291901051. doi: 10.1002/adfm.201901051
6. [6]
  Sun R, Bai Y, Luo M, Qu M X, Wang Z H, Sun W, Sun K N. Enhancing Polysulfide Confinement and Electrochemical Kinetics by Amorphous Cobalt Phosphide for Highly Efficient Lithium-Sulfur Batteries[J]. ACS Nano, 2021,15:739-750. doi: 10.1021/acsnano.0c07038
7. [7]
  Tang H T, Yang J L, Zhang G, Liu C K, Wang H, Zhao Q H, Hu J T, Duan Y D, Pan F. Self-Assembled N-Graphene Nanohollows Enabling Ultrahigh Energy Density Cathode for Li-S Batteries[J]. Nanoscale, 2018,10:386-395. doi: 10.1039/C7NR06731C
8. [8]
  Li Z, Jiang Y, Yuan L X, Yi Z Q, Wu C, Liu Y, Strasser P, Huang Y H. A Highly Ordered Meso@Microporous Carbon-Supported Sulfur @Smaller Sulfur Core - Shell Structured Cathode for Li - S Batteries[J]. ACS Nano, 2014,8:9295-9303. doi: 10.1021/nn503220h
9. [9]
  Liu T, Zhang L Y, Cheng B, Yu J G. Hollow Carbon Spheres and Their Hybrid Nanomaterials in Electrochemical Energy Storage[J]. Adv. Energy Mater., 2019,91803900. doi: 10.1002/aenm.201803900
10. [10]
  Lu S T, Cheng Y W, Wu X H, Liu J. Significantly Improved Long- Cycle Stability in High-Rate Li-S Batteries Enabled by Coaxial Graphene Wrapping over Sulfur-Coated Carbon Nanofibers[J]. Nano Lett., 2013,13:2485-2489. doi: 10.1021/nl400543y
11. [11]
  Chen M F, Jiang S X, Cai S, Wang X Y, Xiang K X, Ma Z Y, Song P, Fisher A C. Hierarchical Porous Carbon Modified with Ionic Surfactants as Efficient Sulfur Hosts for the High - Performance Lithium - Sulfur Batteries[J]. Chem. Eng. J., 2017,313:404-414. doi: 10.1016/j.cej.2016.12.081
12. [12]
  Tan K, Liu Y, Tan Z L, Zhang J Y, Hou L R, Yuan C Z. High-Yield and In-Situ Fabrication of High-Content Nitrogen-Doped Grapheme Nanoribbons@Co/CoOOH as an Integrated Sulfur Host towards Li-S Batteries[J]. J. Mater. Chem. A, 2020,8:3048-3059. doi: 10.1039/C9TA13414J
13. [13]
  Zhong W, Chen Q W, Yang F, Liu W, Li G D, Xie K, Ren M M. N, P Dual-Doped Carbon Nanotube with Superior High-Rate Sodium Storage Performance for Sodium Ion Batteries[J]. J. Electroanal. Chem., 2019,850113392. doi: 10.1016/j.jelechem.2019.113392
14. [14]
  Ye H, Wang C Y, Zuo T T, Wang P F, Yin Y X, Zheng Z, Wang P, Cheng J, Cao F F, Guo Y G. Realizing a Highly Stable Sodium Battery with Dendrite-Free Sodium Metal Composite Anodes and O₃- Type Cathodes[J]. Nano Energy, 2018,48:369-376. doi: 10.1016/j.nanoen.2018.03.069
15. [15]
  Chen X D, Xu Y J, Du F H, Wang Y. Covalent Organic Framework Derived Boron/Oxygen Codoped Porous Carbon on CNTs as an Efficient Sulfur Host for Lithium-Sulfur Batteries[J]. Small Methods, 2019,111900338.
16. [16]
  Huang S Z, Lim Y V, Zhang X M, Wang Y, Zheng Y, Kong D Z, Ding M, Yang S Y, Yang H Y. Regulating the Polysulfide Redox Conversion by Iron Phosphide Nanocrystals for High-Rate and Ultrastable Lithium-Sulfur Battery[J]. Nano Energy, 2018,51:340-348. doi: 10.1016/j.nanoen.2018.06.052
17. [17]
  Wang Y K, Zhang R F, Pang Y C, Chen X, Lang J X, Xu J J, Xiao C H, Li H L, Xi K, Ding S J. Carbon@Titanium Nitride Dual Shell Nanospheres as Multi-functional Hosts for Lithium Sulfur Batteries[J]. Energy Storage Mater., 2019,16:228-235. doi: 10.1016/j.ensm.2018.05.019
18. [18]
  Yang F, Zhong W, Ren M M, Liu W L, Li M, Li G D, Su L W. Poplar Flower-like Nitrogen-Doped Carbon Nanotube@VS₄ Composites with Excellent Sodium Storage Performance[J]. Inorg. Chem. Front., 2020,7:4883-4891. doi: 10.1039/D0QI00985G
19. [19]
  Zhou S Y, Yang S, Ding X W, Lai Y C, Nie H G, Zhang Y G, Chan D, Duan H, Huang S M, Yang Z. Dual-regulation Strategy to Improve Anchoring and Conversion of Polysulfides in Lithium-Sulfur Batteries[J]. ACS Nano, 2020,14:7538-7551. doi: 10.1021/acsnano.0c03403
20. [20]
  Razzaq A A, Yuan X T, Chen Y J, Hu J P, Mu Q Q, Ma Y, Zhao X H, Miao L X, Ahn J H, Peng Y, Deng Z. Anchoring MOF-Derived CoS₂ on Sulfurized Polyacrylonitrile Nanofibers for High Areal Capacity Lithium-Sulfur Batteries[J]. J. Mater. Chem. A, 2020,8:1298-1306. doi: 10.1039/C9TA11390H
21. [21]
  Li B H, Pan Y X, Luo B, Zao J, Xiao Y H, Lei S J, Cheng B C. MOF- Derived NiCo₂S₄@C as a Separator Modification Material for High- Performance Lithium-Sulfur Batteries[J]. Electrochim. Acta, 2020,344135811. doi: 10.1016/j.electacta.2020.135811
22. [22]
  Qiu Y, Fan L S, Wang M X, Yin X J, Wu X, Sun X, Tian D, Guan B, Tang D Y, Zhang N Q. Precise Synthesis of Fe-N₂ Sites with High Activity and Stability for Long - Life Lithium - Sulfur Batteries[J]. ACS Nano, 2020,14:16105-16113. doi: 10.1021/acsnano.0c08056
23. [23]
  Xiao T J, Yi F J, Yang M Z, Liu W L, Li M, Ren M M, Zhang X, Zhou Z. A Composite of CoNiP Quantum Dots-Decorated Reduced Graphene Oxide as a Sulfur Host for Li-S Batteries[J]. J. Mater. Chem. A, 2021,9:16692-16698. doi: 10.1039/D1TA03608D
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2. [2]
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3. [3]
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4. [4]
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5. [5]
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6. [6]
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7. [7]
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8. [8]
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9. [9]
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10. [10]
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11. [11]
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12. [12]
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13. [13]
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14. [14]
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15. [15]
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16. [16]
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17. [17]
  Shengyu Zhao , Qinhao Shi , Wuliang Feng , Yang Liu , Xinxin Yang , Xingli Zou , Xionggang Lu , Yufeng Zhao . Suppression of multistep phase transitions of O3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(5): 108606-. doi: 10.1016/j.cclet.2023.108606
18. [18]
  Jiayu Bai , Songjie Hu , Lirong Feng , Xinhui Jin , Dong Wang , Kai Zhang , Xiaohui Guo . Manganese vanadium oxide composite as a cathode for high-performance aqueous zinc-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109326-. doi: 10.1016/j.cclet.2023.109326
19. [19]
  Shengyu Zhao , Xuan Yu , Yufeng Zhao . A water-stable high-voltage P3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109933-. doi: 10.1016/j.cclet.2024.109933
20. [20]
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Layered Hexagonal Co1-xS Decorating N-Doped Carbon Nanotubes as a Sulfur Host for Li-S Batteries

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通讯作者: 陈斌, bchen63@163.com

Layered Hexagonal Co_1-xS Decorating N-Doped Carbon Nanotubes as a Sulfur Host for Li-S Batteries