Citation: Chen WANG, Qi-Hang LIU, Chen-Yang QI, Cong-Yu WANG, Xiao-Li ZHAO, Xiao-Wei YANG. Synthesis and Supercapacitor Performances of 0D/2D MXene Composite Membrane[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(9): 1707-1715. doi: 10.11862/CJIC.2022.178 shu

Synthesis and Supercapacitor Performances of 0D/2D MXene Composite Membrane

1.
School of Materials Science and Engineering, Tongji University, Shanghai 201804, China
2.
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

Corresponding author: Xiao-Li ZHAO, zxl36@tongji.edu.cn Xiao-Wei YANG, yangxw@sjtu.edu.cn
Received Date: 13 April 2022
Revised Date: 9 July 2022

Figures(6)

The restacking of MXene nanosheets resulted in poor ion accessibility to absorption sites, preventing MXene from high energy density and power density. Herein, 0D/2D composite Ti₃C ₂T_x MXene was prepared by hydrothermal method to alleviate the restacking problem. The quantum dot-interspersed Ti₃C₂T_x nanosheets (QDT) structure was confirmed by X - ray diffraction, dynamic light scattering, and fluorescence spectroscopy. The free - standing film electrodes assembled by QDT showed prominently improved electrochemical properties compared to the pristine Ti₃C₂T_x nanosheets. In three-electrode system, the mass specific capacitance reached 338 F·g^-1 under a scan rate of 5 mV·s^-1. The capacitance retention reached 46% as the scan rate was 2 000 mV·s^-1. In two-electrode system, the assembled symmetric supercapacitor delivered a discharge capacitance of 216 F·g^-1 at a current density of 0.5 A·g^-1. The capacitance retention rate was 87% after 10 000 cycles. The above electrochemical properties of QDT film electrodes were ascribed to the increased ion absorption sites from quantum dots and shortened ion path-way resulted from reduced nanosheet sizes.
- supercapacitor,
- Ti₃C₂T_x,
- quantum dot,
- hydrothermal method,
- ion transport
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