Citation: Alamgir, Yan-Long ZHAO, Talha Khalid, Ya-Bo XIE, Lu WANG, Lin-Hua XIE, Xin ZHANG, Jian-Rong LI. An Interpenetrated Anionic In(Ⅲ) Metal-Organic Framework for Selective Sensing of Fe³⁺ in Water[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(9): 1817-1824. doi: 10.11862/CJIC.2022.174 shu

An Interpenetrated Anionic In(Ⅲ) Metal-Organic Framework for Selective Sensing of Fe³⁺ in Water

Beijing Key Laboratory for Green Catalysis and Separation and Department of Environmental Chemical Engineering, Faculty of Environment and Life, Beijing University of Technology, Beijing 100124, China

Corresponding author: Xin ZHANG, zhang.xin@bjut.edu.cn
Received Date: 9 January 2022
Revised Date: 19 May 2022

Figures(6)

As an emerging type of porous material, metal-organic frameworks (MOFs) have been developed as sensors for monitoring environmental pollutants in water. It is of high significance to develop fluorescent MOFs with simple precursors for selective detection of toxic Fe³⁺ ions. In this work, we present a water-stable two-fold interpenetrated indium-based metal-organic framework (NH₂Me₂)[In(fdc)₂]·2H₂O named BUT-205 (BUT stands for Beijing University of Technology, H₂fdc=furan -2, 5-dicarboxylic acid) constructed from a biomass-derived ligand. BUT-205 has been structurally characterized by single-crystal X-ray diffraction. BUT-205 was an efficient sensor for Fe³⁺ ions in water with high sensitivity and selectivity. The limit of detection (LOD) was calculated to be 1.3 μmol·L^-1 being lower than the US-EPA (U. S. Environmental Protection Agency) standard (15.7 μmol·L^-1) in drinking water. Furthermore, BUT-205 could be recycled and used for at least four cycles.
- metal-organic frameworks,
- anionic framework,
- fluorescent sensing,
- metal cations,
- water safety
1. [1]
  Mitchell E, Frisbie S, Sarkar B. Exposure to Multiple Metals from Groundwater—A Global Crisis: Geology, Climate Change, Health Effects, Testing, and Mitigation[J]. Metallomics, 2011,3:874-908. doi: 10.1039/c1mt00052g
2. [2]
  Xiang Z H, Fang C Q, Leng S H, Cao D P. An Amino Group Functionalized Metal-Organic Framework as a Luminescent Probe for Highly Selective Sensing of Fe³⁺ Ions[J]. J. Mater. Chem. A, 2014,2:7662-7665. doi: 10.1039/c4ta00313f
3. [3]
  Chen C H, Wang X S, Li L, Huang Y B, Cao R. Highly Selective Sensing of Fe³⁺ by an Anionic Metal-Organic Framework Containing Uncoordinated Nitrogen and Carboxylate Oxygen Sites[J]. Dalton Trans., 2018,47:3452-3458. doi: 10.1039/C8DT00088C
4. [4]
  Rasheed T, Nabeel F. Luminescent Metal-Organic Frameworks as Potential Sensory Materials for Various Environmental Toxic Agents[J]. Coord. Chem. Rev., 2019,401213065. doi: 10.1016/j.ccr.2019.213065
5. [5]
  Kreno L E, Leong K, Farha O K, Allendorf M, Van Duyne R P, Hupp J T. Metal-Organic Framework Materials as Chemical Sensors[J]. Chem. Rev., 2012,112:1105-1125. doi: 10.1021/cr200324t
6. [6]
  He Y B, Zhou W, Qian G D, Chen B L. Methane Storage in Metal-Organic Frameworks[J]. Chem. Soc. Rev., 2014,43:5657-5678. doi: 10.1039/C4CS00032C
7. [7]
  Li J R, Kuppler R J, Zhou H C. Selective Gas Adsorption and Separation in Metal-Organic Frameworks[J]. Chem. Soc. Rev., 2009,38:1477-1504. doi: 10.1039/b802426j
8. [8]
  Xu T T, Jiang Z Z, Liu P X, Chen H N, Lan X S, Chen D L, Li L B, He Y B. Immobilization of Oxygen Atoms in the Pores of Microporous Metal-Organic Frameworks for C₂H₂ Separation and Purification[J]. ACS Appl. Nano Mater., 2020,3:2911-2919. doi: 10.1021/acsanm.0c00162
9. [9]
  Li J H, Xie Y, Zhou M Y, Lin R B, Chen X M. Microporous Zinc Formate for Efficient Separation of Acetylene over Carbon Dioxide[J]. Chem. Res. Chin. Univ., 2022,38:87-91. doi: 10.1007/s40242-021-1380-3
10. [10]
  LI J, HAN S, CHEN T J, GOU Z X, ZHANG Q, NIE X S, CAO H R. Two Homologous Metal-Organic Frameworks Based on Zn²⁺ and Cd²⁺ : Luminescent Sensors for Nitro Aromatic Compounds in Solution and Vapor Medium[J]. Chinese J. Inorg. Chem., 2020,35(10):1843-1852.
11. [11]
  LIU Z Q, CAO S H, ZHANG Z, WU J F, ZHAO Y, SUN W Y. Metal-Organic Frameworks with 2, 6-Di(1H-imidazol-1-yl)naphthalene and Dicarboxylate Ligands: Synthesis, Crystal Structure and Photoluminescence Sensing Property[J]. Chinese J. Inorg. Chem., 2019,35(11):2145-2151. doi: 10.11862/CJIC.2019.225
12. [12]
  Horcajada P, Serre C, Vallet-Regi M, Sebban M, Taulelle F, Ferey G. Metal-Organic Frameworks as Efficient Materials for Drug Delivery[J]. Angew. Chem. Int. Ed., 2006,45:5974-5978. doi: 10.1002/anie.200601878
13. [13]
  Chen Y J, Li P, Modica J A, Drout R J, Farha O K. Acid-Resistant Mesoporous Metal-Organic Framework toward Oral Insulin Delivery: Protein Encapsulation, Protection, and Release[J]. J. Am. Chem. Soc., 2018,140:5678-5681. doi: 10.1021/jacs.8b02089
14. [14]
  Maity R, Chakraborty D, Nandi S, Yadav A K, Mullangi D, Vinod C P, Vaidhyanathan R. Aqueous-Phase Differentiation and Speciation of Fe³⁺ and Fe²⁺ Using Water-Stable Photoluminescent Lanthanide-Based Metal-Organic Framework[J]. ACS Appl. Nano Mater., 2019,2:5169-5178. doi: 10.1021/acsanm.9b01047
15. [15]
  ZHANG C L. Two Cd(Ⅱ)-Based Metal-Organic Frameworks for Luminescence Sensing of Metal Ions and Organic Molecules[J]. Chinese J. Inorg. Chem., 2019,35(1):165-173. doi: 10.11862/CJIC.2019.021
16. [16]
  Talha K, Alamgir , Ahmed N, Xie L H, Zhang X, Li J R. Construction of a Zeolite A-Type Multivariate Metal-Organic Framework for Selective Sensing of Fe³⁺ and Cr₂O₇^2-[J]. CrystEngComm, 2021,23:4923-4929. doi: 10.1039/D1CE00610J
17. [17]
  Jin M, Wei L H, Yang Y T, Run M T, Yin C X. A New Turn-On Fluorescent Probe for the Detection of Palladium(0) and Its Application in Living Cells and Zebrafish[J]. New J. Chem., 2019,43:548-551. doi: 10.1039/C8NJ04438D
18. [18]
  Li E Z, Kang J, Ye P Y, Zhang W J, Cheng F Q, Yin C X. A Prospective Material for the Highly Selective Extraction of Lithium Ions Based on a Photochromic Crowned Spirobenzopyran[J]. J. Mater. Chem. B, 2019,7:903-907. doi: 10.1039/C8TB02906G
19. [19]
  Wu Y C, Yin C X, Zhang W J, Chao J B, Huo F J. A Red -Emitting Fluorescent Probe Imaging Release of Calcium Ions from Lysosome Induced by Chloroquine Based on a Photochromic Crowned Spirobenzopyran[J]. Dyes Pigment., 2021,193109467. doi: 10.1016/j.dyepig.2021.109467
20. [20]
  Wang B, Wang P L, Xie L H, Lin R B, Lv J, Li J R, Chen B. A Stable Zirconium Based Metal-Organic Framework for Specific Recognition of Representative Polychlorinated Dibenzo-p-Dioxin Molecules[J]. Nat. Commun., 2019,103861. doi: 10.1038/s41467-019-11912-4
21. [21]
  Singh D, Nagaraja C M. A Luminescent 3D Interpenetrating Metal-Organic Framework for Highly Selective Sensing of Nitrobenzene[J]. Dalton Trans., 2014,43:17912-17915. doi: 10.1039/C4DT02841D
22. [22]
  Yuan R R, He H M. State of the Art Methods and Challenges of Luminescent Metal-Organic Frameworks for Antibiotic Detection[J]. Inorg. Chem. Front., 2020,7:4293-4319. doi: 10.1039/D0QI00955E
23. [23]
  Wang B, Lv X L, Feng D, Xie L H, Zhang J, Li M, Xie Y, Li J R, Zhou H C. Highly Stable Zr(Ⅳ)-Based Metal-Organic Frameworks for the Detection and Removal of Antibiotics and Organic Explosives in Water[J]. J. Am. Chem. Soc., 2016,138:6204-6216. doi: 10.1021/jacs.6b01663
24. [24]
  Hu Z C, Deibert B J, Li J. Luminescent Metal-Organic Frameworks for Chemical Sensing and Explosive Detection[J]. Chem. Soc. Rev., 2014,43:5815-5840. doi: 10.1039/C4CS00010B
25. [25]
  Cui Y, Yue Y, Qian G D, Chen B L. Luminescent Functional Metal-Organic Frameworks[J]. Chem. Rev., 2012,112:1126-1162. doi: 10.1021/cr200101d
26. [26]
  Wang C H, Liu X L, Demir N K, Chen J P, Li K. Applications of Water Stable Metal-Organic Frameworks[J]. Chem. Soc. Rev., 2016,45:5107-5134. doi: 10.1039/C6CS00362A
27. [27]
  Zhang X, Wang B, Alsalme A, Xiang S C, Zhang Z J, Chen B L. Design and Applications of Water-Stable Metal-Organic Frameworks: Status and Challenges[J]. Coord. Chem. Rev., 2020,423213507. doi: 10.1016/j.ccr.2020.213507
28. [28]
  Devic T, Serre C. High Valence 3p and Transition Metal Based MOFs[J]. Chem. Soc. Rev., 2014,43:6097-6115. doi: 10.1039/C4CS00081A
29. [29]
  Cavka J H, Jakobsen S, Olsbye U, Guillou N, Lamberti C, Bordiga S, Lillerud K P. A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability[J]. J. Am. Chem. Soc., 2008,130:13850-13851. doi: 10.1021/ja8057953
30. [30]
  Lv X L, Yuan S, Xie L H, Darke H F, Chen Y, He T, Dong C, Wang B, Zhang Y Z, Li J R, Zhou H C. Ligand Rigidification for Enhancing the Stability of Metal-Organic Frameworks[J]. J. Am. Chem. Soc., 2019,141:10283-10293. doi: 10.1021/jacs.9b02947
31. [31]
  Bu F, Lin Q P, Zhai Q G, Bu X H, Feng P Y. Charge-Tunable Indium-Organic Frameworks Built from Cationic, Anionic, and Neutral Building Blocks[J]. Dalton Trans., 2015,44:16671-16674. doi: 10.1039/C5DT02861B
32. [32]
  Kumar Maka V, Tamuly P, Jindal S, Narasimha Moorthy J. Control of In-MOF Topologies and Tuning of Porosity through Ligand Structure, Functionality and Interpenetration: Selective Cationic Dye Exchange[J]. Appl. Mater. Today, 2020,19100613. doi: 10.1016/j.apmt.2020.100613
33. [33]
  Yang H, Guo F, Lama P, Gao W Y, Wu H, Barbour L J, Zhou W, Zhang J, Aguila B, Ma S. Visualizing Structural Transformation and Guest Binding in a Flexible Metal-Organic Framework under High Pressure and Room Temperature[J]. ACS Central Sci., 2018,4:1194-1200. doi: 10.1021/acscentsci.8b00378
34. [34]
  Yang Q Y, Lama P, Sen S, Lusi M, Chen K J, Gao W Y, Shivanna M, Pham T, Hosono N, Kusaka S, Perry J J, Ma S Q, Space B, Barbour L J, Kitagawa S, Zaworotko M J. Reversible Switching between Highly Porous and Nonporous Phases of an Interpenetrated Diamondoid Coordination Network that Exhibits Gate-Opening at Methane Storage Pressures[J]. Angew. Chem. Int. Ed., 2018,57:5684-5689. doi: 10.1002/anie.201800820
35. [35]
  Park I H, Mulijanto C E, Lee H H, Kang Y, Lee E, Chanthapally A, Lee S S, Vittal J J. Influence of Interpenetration in Diamondoid Metal-Organic Frameworks on the Photoreactivity and Sensing Properties[J]. Cryst. Growth Des., 2016,16:2504-2508. doi: 10.1021/acs.cgd.6b00354
36. [36]
  Swaidan A, Borthakur P, Boruah P K, Das M R, Barras A, Hamieh S, Toufaily J, Hamieh T, Szunerits S, Boukherroub R. A Facile Preparation of CuS-BSA Nanocomposite as Enzyme Mimics: Application for Selective and Sensitive Sensing of Cr(Ⅵ) Ions[J]. Sens. Actuator B-Chem., 2019,294:253-262. doi: 10.1016/j.snb.2019.05.052
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通讯作者: 陈斌, bchen63@163.com

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An Interpenetrated Anionic In(Ⅲ) Metal-Organic Framework for Selective Sensing of Fe3+ in Water

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通讯作者: 陈斌, bchen63@163.com

An Interpenetrated Anionic In(Ⅲ) Metal-Organic Framework for Selective Sensing of Fe³⁺ in Water