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Citation: Ti-Tong NI, Yue MENG, KOSO Aoki, Yi-Yang YAO, Hao-Dong TANG, Ai-Min CHEN, Sheng-Jie XIA. Photocatalytic Degradation of Methylene Blue by Fe3O4@MAl-Layered Double Hydroxides (M=Zn, Co, Ni) Composite: Performance, Kinetics, and Mechanism[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(9): 1759-1770. doi: 10.11862/CJIC.2022.171 shu

Photocatalytic Degradation of Methylene Blue by Fe3O4@MAl-Layered Double Hydroxides (M=Zn, Co, Ni) Composite: Performance, Kinetics, and Mechanism

  • 1.

    College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China

  • 2.

    Department of Life and Health Sciences, Huzhou College, Huzhou, Zhejiang 313000, China

  • 3.

    Zhejiang Huayuan Pigment Co., Ltd., Deqing, Zhejiang 310024, China

Figures(7)

  • Based on low-cost, non-toxic, and strong light absorption ferric oxide (Fe3O4) and layered double hydrox-ides (LDHs) with large specific surface and high stability, Fe3O4@MAl -LDHs (M=Zn, Co, Ni) composites were pre-pared and used for photocatalytic degradation of methylene blue. The composition and structure of the composites were characterized by X-ray powder diffraction (XRD), UV-Vis absorption spectroscopy, scanning electron microsco-py (SEM), transmission electron microscopy (TEM), and N2 adsorption-desorption test. The optimum conditions were as follows: the amount of catalyst was 50 mg, the light intensity was 500 W, the pH value was 9, and the reaction temperature was 40 ℃. The degradation rate of methylene blue increased significantly from 23.2% of LDHs to 87.0% of Fe 3O4@MAl- LDHs. The degradation of methylene blue by LDHs mainly comes from ·OH, while the photo-degradation activity of Fe3O4@MAl-LDHs is mainly contributed by both ·OH and holes. In addition, there were also great differences in the electrochemical properties of LDHs and Fe3O4@MAl-LDHs.
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