Citation: Na LI, Cong ZHANG, Ju-Jie REN, Min CUI, Hai-Yan ZHAO, Hong-Yue ZHANG, Shi-Xu CHEN, Hong-Yan HAN, Huan ZHANG. Construction and Properties of the Electrochemical Bisphenol A Sensor Based on Polyoxometalates and Multi-walled Carbon Nanotubes[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(8): 1633-1642. doi: 10.11862/CJIC.2022.164 shu

Construction and Properties of the Electrochemical Bisphenol A Sensor Based on Polyoxometalates and Multi-walled Carbon Nanotubes

Na LI ¹ ,
Cong ZHANG ¹ ,
Ju-Jie REN ^3,, ,
Min CUI ¹ ,
Hai-Yan ZHAO ¹ ,
Hong-Yue ZHANG ¹ ,
Shi-Xu CHEN ¹ ,
Hong-Yan HAN ^2,, ,
Huan ZHANG ³

1.
Hebei Provincial Key Laboratory of Photoelectric Control on Sunface and Interface, College of Science, Hebei University of Science and Technology, Shijiazhuang 050018, China
2.
Hebei University of Industry and Technology, Shijiazhuang 050091, China
3.
Hebei Province Chinese Medicine Hospital, Shijiazhuang 050018, China

Corresponding author: Ju-Jie REN, jujieren@163.com Hong-Yan HAN, hhy051824@163.com
Received Date: 25 February 2022
Revised Date: 23 June 2022

Figures(15)

A new inorganic-organic hybrid (H₂L)₂(HL)₂L(PMo₁₂O₄₀)₂·2H₂O (marked as PMo₁₂) derived from the selfassembling of N-containing ligands L (L=1, 3-bis(1-imidazolyl) propane) and inorganic polyoxometalates (H₃PMo₁₂O₄₀) have been hydrothermally synthesized. The compound was characterized by infrared spectroscopy (IR), thermal gravity (TG), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and single-crystal X-ray diffraction. Studies on single-crystal X-ray diffraction reveal that the compound displays 3D structures. Then a bisphenol A (BPA) electrochemical sensor based on PMo₁₂ and multi-walled carbon nanotubes (MWCNTs) has been successfully constructed. The detection limit was 0.5 μmol·L^-1 (S/N=3) in a range of 1-20 μmol·L^-1, and the sensor had good anti-interference and stability.
- crystal growth,
- polyoxometalates,
- electroanalytical,
- sensor
1. [1]
  Müller A, Kögerler P, Dress A W M. Giant[J]. Metal - Oxide - Based Spheres and Their Topology: From Pentagonal Building Blocks to Keplerates and Unusual Spin Systems. Coord. Chem. Rev., 2001,222:193-218.
2. [2]
  Hutin M, Rosnes M H, Long D L, Cronin L. Polyoxometalates: Synthesis and Structure-From Building Blocks to Emergent Materials// Reedijk J, Poeppelmeier K. Comprehensive Inorganic Chemistry: Vol. 2. 2nd ed. Oxford: Elsevier, 2013: 241-269
3. [3]
  Zou C, Zhang Z J, Xuan X, Gong Q H, Li J, Wu C D. A Multifunctional Organic-Inorganic Hybrid Structure Based on Mn^Ⅲ-Porphyrin and Polyoxometalate as a Highly Effective Dye Scavenger and Heterogenous Catalyst[J]. J. Am. Chem. Soc., 2012,134(1):87-90. doi: 10.1021/ja209196t
4. [4]
  Li S J, Peng Q P, Chen X N, Wang R Y, Zhai J X, Hu W H, Ma F J, Zhang J, Liu S X. A Ta/W Mixed Addenda Heteropolyacid with Excellent Acid Catalytic Activity and Proton-Conducting Property[J]. J. Solid State Chem., 2016,243:1-7. doi: 10.1016/j.jssc.2016.08.003
5. [5]
  Song J, Luo Z, Britt D K, Furukawa H, Yaghi O M, Hardcastle K I, Hill C L. A Multiunit Catalyst with Synergistic Stability and Reactivity: A Polyoxometalate-Metal Organic Framework for Aerobic Decontami- nation[J]. J. Am. Chem. Soc., 2011,133:16839-16846. doi: 10.1021/ja203695h
6. [6]
  Kamata K, Yonehara K, Sumida Y, Yamaguchi K, Hikichi S, Mizuno N. Efficient Epoxidation of Olefins with ≥99% Selectivity and Use of Hydrogen Peroxide[J]. Science, 2003,300(5621):964-966. doi: 10.1126/science.1083176
7. [7]
  Müller A, Krickemeyer E, Bögge H, Schmidtmann M, Beugholt C, Das S K, Peters F. Giant Ring - Shaped Building Blocks Linked to Form a Layered Cluster Network with Nanosized Channels: [Mo₁₂₄^ⅥMo₂₈^ⅤO₄₂₉(μ₃ - O)₂₈H₁₄(H₂O)_66.5]¹⁶-[J]. Chem. Eur. J., 1999,5(5):1496-1502. doi: 10.1002/(SICI)1521-3765(19990503)5:5<1496::AID-CHEM1496>3.0.CO;2-D
8. [8]
  Falaise C, Khlifi S, Bauduin P, Schmid P, Shepard W, Ivanov A A, Sokolov M N, Shestopalov M A, Abramov P A, Cordier S, Marrot J, Haouas M, Cadot E. "Host in Host"Supramolecular Core-Shell Type Systems Based on Giant Ring - Shaped Polyoxometalates[J]. Angew. Chem. Int. Ed., 2021,60:14146-14153. doi: 10.1002/anie.202102507
9. [9]
  Dong P F, Li N, Zhao H Y, Cui M, Zhang C, Han H Y, Ren J J. POMs as Active Center for Sensitively Electrochemical Detection of Bisphenol A and Acetaminophen[J]. Chem. Res. Chin. Univ., 2019,35(4):592-597. doi: 10.1007/s40242-019-8370-8
10. [10]
  Shi S K, Li X, Guo H L, Fan Y H, Li H Y, Dang D B, Bai Y. Ionothermal Synthesis of an Antimonomolybdate Cluster, [Sb₈Mo₁₃^VIMo₅^VO₆₆]^5-, and Its Catalytic Behavior to the Reduction of Nitrobenzene[J]. Inorg. Chem., 2020,59(16):11213-11217. doi: 10.1021/acs.inorgchem.0c00825
11. [11]
  Li N, Mu B, Lv L, Huang R D. Assembly of New Polyoxometalate- Templated Metal-Organic Frameworks Based on Flexible Ligands[J]. J. Solid State Chem., 2015,226:88-93. doi: 10.1016/j.jssc.2015.02.005
12. [12]
  Fernandes D M, Freire C. Carbon Nanomaterial-Phosphomolybdate Composites for Oxidative Electrocatalysis[J]. ChemElectroChem, 2015,2(2):269-279. doi: 10.1002/celc.201402271
13. [13]
  Wang Y L, Ma Y Y, Zhao Q, Hou L, Han Z G. Polyoxometalate - Based Crystalline Catalytic Materials for Efficient Electrochemical Detection of Cr(Ⅵ)[J]. Sens. Actuators B, 2020,305127469. doi: 10.1016/j.snb.2019.127469
14. [14]
  Moghadam F H, Taher M A, Karimi-Maleh H. A Sensitive and Fast Approach for Voltammetric Analysis of Bisphenol A as a Toxic Compound in Food Products Using a Pt-SWCNTs/Ionic Liquid Modified Sensor[J]. Food Chem. Toxicol., 2021,152112166. doi: 10.1016/j.fct.2021.112166
15. [15]
  JIANG X L, ZENG M, HAO Y, XU Z H, WANG J Q, CHEN K, HUANG J. Study of Migration of Bisphenol A to Food Simulants un- der Microwave Radiation[J]. Chinese Journal of Inorganic Analytical, 2013,3(4):69-72.
16. [16]
  Yola M L, Atar N. A Novel Voltametric Sensor Based on Gold Nanoparticles Involved in p-Aminothiophenol Functionalized Multiwalled Carbon Nanotubes: Application to the Simultaneous Determination of Quercetin and Rutin[J]. Electrochim. Acta, 2014,119:24-31. doi: 10.1016/j.electacta.2013.12.028
17. [17]
  Xiao C Y, Wang L H, Zhou Q, Huang X H. Hazards of Bisphenol A (BPA) Exposure: A Systematic Review of Plant Toxicology Studies[J]. J. Hazard. Mater., 2020,384121488. doi: 10.1016/j.jhazmat.2019.121488
18. [18]
  Dhanjai , Sinha A, Wu L X, Lu X B, Chen J P, Jain R. Advances in Sensing and Biosensing of Bisphenols: A Review[J]. Anal. Chim. Acta, 2018,998:1-27. doi: 10.1016/j.aca.2017.09.048
19. [19]
  Qin W L, Liu X, Chen H P, Yang J. Amperometric Sensors for Detection of Phenol in Oilfield Wastewater Using Electrochemical Polymerization of Zincon Film[J]. Anal. Methods, 2014,6(15):5734-5740. doi: 10.1039/C3AY41855C
20. [20]
  Mazzotta E, Malitesta C, Margapoti E. Direct Electrochemical Detection of Bisphenol A at PEDOT-modified Glassy Carbon Electrodes[J]. Anal. Bioanal. Chem., 2013,405(11):3587-3592. doi: 10.1007/s00216-013-6723-6
21. [21]
  Sun P Y, Wu Y H. An Amperometric Biosensor Based on Human Cytochrome P450 2C9 in Polyacrylamide Hydrogel Films for Bisphenol A Determination[J]. Sens. Actuators B, 2013,178:113-118. doi: 10.1016/j.snb.2012.12.055
22. [22]
  Huang D H, Huang X Z, Chen J Y, Ye R H, Lin Q, Chen S. An Electrochemical Bisphenol: A Sensor Based on Bimetallic Ce-Zn-MOF[J]. Electrocatalysis, 2021,12(4):456-468. doi: 10.1007/s12678-021-00659-6
23. [23]
  Zhang R Y, Zhang Y, Deng X L, Sun S G, Li Y C. A Novel Dualsignal Electrochemical Sensor for Bisphenol A Determination by Coupling Nanoporous Gold Leaf and Self-Assembled Cyclodextrin[J]. Electrochim. Acta, 2018,271:417-424. doi: 10.1016/j.electacta.2018.03.113
24. [24]
  Zhang J, Xu X J, Chen L. An Ultrasensitive Electrochemical Bisphenol A Sensor Based on Hierarchical Ce-Metal-Organic Framework Modified with Cetyltrimethy Lammonium Bromide[J]. Sens. Actuators B, 2018,261:425-433. doi: 10.1016/j.snb.2018.01.170
25. [25]
  Wu Y Y, Zheng Z Y, Yang J Y, Lin Y J, Zhang X S, Chen Y W, Gao W H. Bisphenol A Electrochemiluminescence Sensor Based on Reduced Graphene Oxide - Bi₂ZnS₄ Nanocomposite[J]. J. Electroanal. Chem., 2018,817:118-127. doi: 10.1016/j.jelechem.2018.03.064
26. [26]
  Ndlovu T, Arotiba O A, Sampath S, Krause R W, Mamba B B. An Exfoliated Graphite - Based Bisphenol A Electrochemical Sensor[J]. Sensors, 2012,12:11601-11611. doi: 10.3390/s120911601
27. [27]
  Rao H B, Liu Y T, Zhong J, Zhang Z Y, Zhao X, Liu X, Jiang Y Y, Zou P, Wang X X, Wang Y Y. Gold Nanoparticle/Chitosan@N, S Codoped Multiwalled Carbon Nanotubes Sensor: Fabrication, Characterization, and Electrochemical Detection of Catechol and Nitrite[J]. ACS Sustainable Chem. Eng., 2017,5:10926-10939. doi: 10.1021/acssuschemeng.7b02840
28. [28]
  Sheldrick G M. A Short History of SHELX[J]. Acta Crystallogr. Sect. A, 2008,64(1):112-122. doi: 10.1107/S0108767307043930
29. [29]
  Jiao J, Zuo J W, Pang H J, Tan L C, Chen T, Ma H Y. A Dopamine Electrochemical Sensor Based on Pd-Pt Alloy Nanoparticles Decorated Polyoxometalate and Multiwalled Carbon Nanotubes[J]. J. Electroanal. Chem., 2018,827:103-111. doi: 10.1016/j.jelechem.2018.09.014
30. [30]
  TENG D, WANG Q, LI N, ZHAO H Y, HUANG R D. Synthesis and Electrochemical Properties of Supramolecular Compounds Based on POMs[J]. Journal of Molecular Science, 2019,35(2):149-150.
31. [31]
  Bard A J, Faulkner L R. Electrochemical Methods: Fundamentals and Applications[J]. Surf. Technol., 1983,20:91-92. doi: 10.1016/0376-4583(83)90080-8
32. [32]
  Laviron E. General Expression of the Linear Potential Sweep Voltammogram in the Case of Diffusionless Electrochemical Systems[J]. J. Electroanal. Chem. Interfacial Electrochem., 1979,101:19-28. doi: 10.1016/S0022-0728(79)80075-3
33. [33]
  Zhang R Y, Zhang Y, Deng X L, Sun S G, Li Y C. A Novel Dualsignal Electrochemical Sensor for Bisphenol A Determination by Coupling Nanoporous Gold Leaf and Self- Assembled Cyclodextrin[J]. Electrochim. Acta, 2018,271:417-424. doi: 10.1016/j.electacta.2018.03.113
34. [34]
  Jiang L Y, Santiago I, Foord J. A Comparative Study of Fouling-Free Nano Diamond and Nanocarbon Electrochemical Sensors for Sensitive Bisphenol A Detection[J]. Carbon, 2021,174:390-395. doi: 10.1016/j.carbon.2020.11.073
35. [35]
  Skunik M, Kulesza P J. Phosphomolybdate -Modified Multi - walled Carbon Nanotubes as Effective Mediating Systems for Electrocatalytic Reduction of Bromate[J]. Anal. Chim. Acta, 2009,631:153-160. doi: 10.1016/j.aca.2008.10.031
36. [36]
  Zhang L, Li S B, O′Halloran K P, Zhang Z F, Ma H Y, Wang X M, Tan L C, Pang H J. A Highly Sensitive Non - enzymatic Ascorbic Acid Electrochemical Sensor Based on Polyoxometalate/Tris(2, 2′ - bipyridine)ruthenium(Ⅱ)/Chitosan-Palladium Inorganic-Organic Self- Assembled Film[J]. Colloids Surf. A, 2021,641126184.
37. [37]
  Qin W L, Liu X, Chen H P, Yang J. Amperometric Sensors for Detection of Phenol in Oilfield Wastewater Using Electrochemical Polymerization of Zincon Film[J]. Anal. Methods, 2014,6:5734-5740. doi: 10.1039/C3AY41855C
38. [38]
  Mazzotta E, Malitesta C, Margapoti E. Direct Electrochemical Detec- tion of Bisphenol A at PEDOT-Modified Glassy Carbon Electrodes[J]. Anal. Bioanal. Chem., 2013,405:3587-3592. doi: 10.1007/s00216-013-6723-6
39. [39]
  Messaoud N B, Ghica M E, Dridi C, Ali M B, Brett C M A. Electrochemical Sensor Based on Multiwalled Carbon Nanotube and Gold Nanoparticle Modified Electrode for the Sensitive Detection of Bisphenol A[J]. Sens. Actuators B, 2017,253:513-522.
40. [40]
  DONG B T, FENG Q X, GONG B. Determination of Bisphenol A and Phenol in By-product Sodium Chloride of Synthesis of Polycarbonate by High Performance Liquid Chromatography[J]. Chemical Analysis and Meterage, 2021,7:56-59.
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