Citation: Feng SU, Shao-Dong LI, Chun HAN, Lin-Tao WU, Zhi-Jun WANG. Co(Ⅱ)/Ni(Ⅱ)Coordination Polymer of Isomeric Terphenyl-2, 2″, 4, 4″-tetracarboxylic Acids with a Single Water Bridge: Syntheses, Structures, and Magnetic Properties[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(7): 1421-1432. doi: 10.11862/CJIC.2022.147 shu

Co(Ⅱ)/Ni(Ⅱ)Coordination Polymer of Isomeric Terphenyl-2, 2″, 4, 4″-tetracarboxylic Acids with a Single Water Bridge: Syntheses, Structures, and Magnetic Properties

Department of Chemistry, Changzhi University, Changzhi, Shanxi 046011, China

Corresponding author: Zhi-Jun WANG, 250951251@qq.com
Received Date: 25 January 2022
Revised Date: 17 April 2022

Figures(7)

Two single water-bridged Co(Ⅱ)/Ni(Ⅱ) chains coordination polymers, namely[Co(m-H₂tpta)(H₂O)₃]_n (1) and {[Ni₂(p-tpta)(H₂O)₆]·2H₂O}_n (2) were synthesized based on isomeric terphenyl-2, 2″, 4, 4″-tetracarboxylic acid (m-H₄tpta and p-H₄tpta) ligands under hydrothermal conditions. They have been structurally characterized by FT-IR, elemen- tal analysis, single-crystal, and powder X-ray diffraction analysis. Structurally, the central metal ions display slightly distorted octahedral geometries in 1 and 2, and are linked to 1D metal chains by single bridging water molecules. The isomeric H₄tpta ligands coordinate metal ions in differentμ₁-η¹: η⁰: η¹: η⁰ and μ₄-η¹: η¹: η¹: η¹ coordination modes, leading to the formation of 1D chain and 3D network structure. Complex 2 displays a 3D network with (4, 4)-connected NbO net topology. Magnetically, complex 1 exhibited an antiferromagnetic interaction through μ₂-H₂O in the uniform Co(Ⅱ) chain model. Complex 2 also showed an antiferromagnetic coupling between Ni(Ⅱ) ions corresponding to magnetic coupling Ni-Ow-Ni angles. CCDC: 1415021, 1; 1415020, 2.
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