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Citation: Ji-Zhuo HU, Zhi-Guang LIANG, Song-Ling WU, Xiu-Lan CHENG. Synthesis and Luminescent Properties of Blue Emitting Phosphor Sr7Zr(PO4)6: xEu2+[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(7): 1361-1366. doi: 10.11862/CJIC.2022.142 shu

Synthesis and Luminescent Properties of Blue Emitting Phosphor Sr7Zr(PO4)6: xEu2+

  • Guangxi Teli Resource Utilization Testing Services Co., Ltd., Nanning 530021, China

  • Corresponding author: Xiu-Lan CHENG, 41037387@qq.com
  • Received Date: 15 February 2022
    Revised Date: 18 May 2022

Figures(6)

  • A novel blue-emitting phosphor Sr7Zr(PO4)6: xEu2+was synthesized for the first time via a traditional solidstate reaction method. Phase purity and luminescence properties of these phosphors were studied by X-ray powder diffraction, UV -Vis spectra, and fluorescence spectra. X-ray diffraction results confirmed the pure phase of Eu2+ doped Sr7Zr(PO4)6 materials and they could be efficiently pumped by the near-ultraviolet (NUV) light region from 200 to 400 nm. Excited by 315 nm, Sr7Zr(PO4)6: xEu2+ exhibited a strong and broad emission band ranging from 380 to 480 nm with a maximum peak at 415 nm. The concentration quenching mechanism of Eu2+ in Sr7Zr(PO4)6 was electric dipole-electric dipole interaction, and the critical distance for energy transfer was 2.71 nm. The optimal con-centration of Eu2+ was 0.05 and the corresponding CIE chromaticity coordinate was (0.164, 0.021), exhibiting higher color purity than commercial BaMgAl10O17: Eu2+ (BAM) blue phosphor.
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