Citation: Ya-Qi GUO, Ai-Ling FAN, Wei PANG, Deng-Kui XIE, Dian-Chao GAO. Preparation of Plate NiWP@Polyhedral NiWO Electrocatalyst for Hydrogen Evolution[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(7): 1283-1290. doi: 10.11862/CJIC.2022.131 shu

Preparation of Plate NiWP@Polyhedral NiWO Electrocatalyst for Hydrogen Evolution

Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing 100124, Chin

Corresponding author: Ai-Ling FAN, fanailing@bjut.edu.cn
Received Date: 8 December 2021
Revised Date: 11 May 2022

Figures(5)

Here, polyhedral nickel-tungsten oxide (NiWO) precursor was prepared on nickel foam via the one-step hydrothermal method, and then it was phosphatized at different temperatures to obtain the plate nickel-tungsten phosphide (NiWP)@polyhedral NiWO composite electrocatalyst. The results showed that optimizing phosphating temperature can significantly improve the electrocatalytic hydrogen evolution performance of the plate NiWP@polyhedron NiWO. When the phosphating temperature was 450℃, it exhibited excellent hydrogen evolution catalyt-ic activity with an overpotential of 115 mV to achieve 10 mA·cm^-2. The Tafel slope was 85 mV·dec^-1, which was similar to Pt. In addition, the 24 h long-term stability test showed that the electrocatalyst had good stability. This excellent performance can be attributed to the fact that the plate NiWP@polyhedral NiWO composite structure increases the catalytic active area, reduces the charge/mass transfer resistance, accelerates the electron transfer rate, and increases the reaction kinetics performance.
- nickel-tungsten oxide,
- phosphating temperature,
- nickel-tungsten phosphide,
- composite structure,
- electrocatalyst
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