Citation: Feng-He ZHAO, Chong-Min ZHANG. Application of Monodisperse SiO₂ Nanoparticles Composite Gel Electrolytes[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(2): 313-320. doi: 10.11862/CJIC.2022.040 shu

Application of Monodisperse SiO₂ Nanoparticles Composite Gel Electrolytes

Feng-He ZHAO ^1,, ,
Chong-Min ZHANG ²

1.
Qingdao Public Service Center for Small and Medium Enterprises, Qingdao, Shandong 266199, China
2.
Qingdao Puke Parting Materials Co. Ltd., Qingdao, Shandong 266112, China

Corresponding author: Feng-He ZHAO, work3857@163.com
Received Date: 25 August 2021
Revised Date: 13 December 2021

Figures(6)

In this work, the well-monodispersed SiO₂ nanoparticles (about 130 nm) were used as the filler while the polyvinylidene fluoride-hexafluoropropylene (PVDF-HFP) was used as the polymer matrix. The monodisperse SiO₂ composite gel polymer electrolytes (MCGPEs) were prepared by a simple method and applied to lithium batteries. SiO₂ has better dispersion and uniformity in the polymer matrix. Compared with the conventional composite gel polymer electrolytes (GPEs) and commercial SiO₂ composite gel polymer electrolytes (CGPEs), MCGPEs exhibited the more excellent ability of liquid absorption and better lithium-ion migration ability. Moreover, the cells which used MCGPEs as electrolytes maintained a high specific capacity of 121.1 mAh·g^-1 after 300 cycles at 1.0C, showing a satisfactory cycle performance. Meanwhile, the rate performance of MCGPEs was also excellent. The cells using MCGPEs owned the specific capacity of 135 mAh·g^-1 at 10C which was higher than GPEs cells (76.2 mAh·g^-1).
- lithium-ion batteries,
- gel polymer electrolytes,
- SiO₂,
- nanoparticles
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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Application of Monodisperse SiO₂ Nanoparticles Composite Gel Electrolytes