Citation: Mei-Yin WANG, Yuan-Hang REN, Chun-Bo JIA, Xiang LI, Lin YE, Bin YUE, He-Yong HE. Preparation and Characterization of Mesoporous Cs₃PMo₁₂O₄₀ Employed for Catalytic Epimerization Reaction of Aldoses[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(2): 304-312. doi: 10.11862/CJIC.2022.037 shu

Preparation and Characterization of Mesoporous Cs₃PMo₁₂O₄₀ Employed for Catalytic Epimerization Reaction of Aldoses

Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200438, China

Corresponding author: Bin YUE, yuebin@fudan.edu.cn He-Yong HE, heyonghe@fudan.edu.cn
Received Date: 24 August 2021
Revised Date: 20 December 2021

Figures(11)

Keggin-type mesoporous Cs₃PMo₁₂O₄₀ (m-Cs₃PMo) has been prepared by using H₃PMo₁₂O₄₀ and CsCl as starting materials and amphiphilic triblock copolymer F127 as a template. The composition, structure, and morphology were characterized by powder X-ray diffraction (XRD), FT-IR, field emission scanning electron microscopy (FESEM), transmission electron microscope (TEM), N₂ adsorption-desorption test, and small-angle X-ray scattering (SAXS). The results show that m-Cs₃ PMo belongs to the cubic lattice system and owns 2.5 and 6.0 nm wormlike mesoporous pores. The catalytic activity of m-Cs₃PMo in aqueous epimerization of D-glucose, D-xylose, and L-arabinose was investigated. The effects of temperature, time, and catalyst amount on the D-glucose epimerization reaction and the recycling performance of the catalyst were also studied. During the recycling process, the catalyst activity and product selectivity did not decrease significantly, which showed good stability of m-Cs₃PMo.
- mesoporous materials,
- polyoxometalates,
- heterogeneous catalysis,
- aldose epimerization
1. [1]
  Corma A, Iborra S, Velty A. Chemical Routes for the Transformation of Biomass into Chemicals[J]. Chem. Rev., 2007,107(6):2411-2502.
2. [2]
  Saidur R, Abdelaziz E A, Demirbas A, Hossain M S, Mekhilef S. A Review on Biomass as a Fuel for Boilers[J]. Renewable Sustainable Energy Rev., 2011,15(5):2262-2289. doi: 10.1016/j.rser.2011.02.015
3. [3]
  Mika L T, Csefalvay E, Nemeth A. Catalytic Conversion of Carbohydrates to Initial Platform Chemicals: Chemistry and Sustainability[J]. Chem. Rev., 2018,118(2):505-613. doi: 10.1021/acs.chemrev.7b00395
4. [4]
  Wyman C E, Dale B E, Elander R T, Holtzapple M, Ladisch M R, Lee Y Y, Mitchinson C, Saddler J N. Comparative Sugar Recovery and Fermentation Data Following Pretreatment of Poplar Wood by Leading Technologies[J]. Biotechnol. Progr., 2009,25(2):333-339. doi: 10.1002/btpr.142
5. [5]
  Huber G W, Iborra S, Corma A. Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and Engineering[J]. Chem. Rev., 2006,106(9):4044-4098. doi: 10.1021/cr068360d
6. [6]
  Goransson K, Soderlind U, He J, Zhang W N. Review of Syngas Production via Biomass DFBGs[J]. Renewable Sustainable Energy Rev., 2011,15(1):482-492. doi: 10.1016/j.rser.2010.09.032
7. [7]
  De Lasa H, Salaices E, Mazumder J, Lucky R. Catalytic Steam Gasification of Biomass: Catalysts, Thermodynamics and Kinetics[J]. Chem. Rev., 2011,111(9):5404-5433. doi: 10.1021/cr200024w
8. [8]
  Mohan D, Pittman C U, Steele P H. Pyrolysis of Wood/Biomass for Biooil: A Critical Review[J]. Energy Fuels, 2006,20(3):848-889. doi: 10.1021/ef0502397
9. [9]
  Van De Vyver S, Geboers J, Jacobs P A, Sels B F. Recent Advances in the Catalytic Conversion of Cellulose[J]. ChemCatChem, 2011,3(1):82-94. doi: 10.1002/cctc.201000302
10. [10]
  Huang Y B, Fu Y. Hydrolysis of Cellulose to Glucose by Solid Acid Catalysts[J]. Green Chem., 2013,15(5):1095-1111. doi: 10.1039/c3gc40136g
11. [11]
  Singh R, Shukla A, Tiwari S, Srivastava M. A Review on Delignification of Lignocellulosic Biomass for Enhancement of Ethanol Production Potential[J]. Renewable Sustainable Energy Rev., 2014,32:713-728. doi: 10.1016/j.rser.2014.01.051
12. [12]
  Zhang X G, Wilson K, Lee A F. Heterogeneously Catalyzed Hydrothermal Processing of C₅-C₆ Sugars[J]. Chem. Rev., 2016,116(19):12328-12368. doi: 10.1021/acs.chemrev.6b00311
13. [13]
  Besson M, Gallezot P, Pinel C. Conversion of Biomass into Chemicals over Metal Catalysts[J]. Chem. Rev., 2014,114(3):1827-1870.
14. [14]
  Delidovich I, Palkovits R. Catalytic Isomerization of Biomass-Derived Aldoses: A Review[J]. ChemSusChem, 2016,9(6):547-561. doi: 10.1002/cssc.201501577
15. [15]
  Bayu A, Abudula A, Guan G Q. Reaction Pathways and Selectivity in Chemo-Catalytic Conversion of Biomass-Derived Carbohydrates to High-Value Chemicals: A Review[J]. Fuel Process. Technol., 2019,196106162. doi: 10.1016/j.fuproc.2019.106162
16. [16]
  Angyal S J. A Short Note on the Epimerization of Aldoses[J]. Carbohydr. Res., 1997,300(3):279-281. doi: 10.1016/S0008-6215(97)00058-X
17. [17]
  Kabyemela B M, Adschiri T, Malaluan R M, Arai K. Kinetics of Glucose Epimerization and Decomposition in Subcritical and Supercritical Water[J]. Ind. Eng. Chem. Res., 1997,36(5):1552-1558. doi: 10.1021/ie960250h
18. [18]
  Hu X, Shi Y N, Zhang P, Miao M, Zhang T, Jiang B. D-Mannose: Properties, Production, and Applications: An Overview[J]. Compr. Rev. Food Sci. Food Saf., 2016,15(4):773-785.
19. [19]
  Park C S, Kim J E, Choi J G, Oh D K. Characterization of a Recombinant Cellobiose 2-Epimerase from Caldicellulosiruptor Saccharolyticus and Its Application in the Production of Mannose from Glucose[J]. Appl. Microbiol. Biotechnol., 2011,92(6):1187-1196. doi: 10.1007/s00253-011-3403-3
20. [20]
  Bilik V. Reactions of Saccharides Catalyzed by Molybdate Ions. 2. Epimerization of D-Glucose and D-Mannose[J]. Chemicke Zvesti, 1972,26(2):183-186.
21. [21]
  Hayes M L, Pennings N J, Serianni A S, Barker R. Epimerization of Aldoses by Molybdate Involving a Novel Rearrangement of the Carbon Skeleton[J]. J. Am. Chem. Soc., 1982,104(24):6764-6769. doi: 10.1021/ja00388a047
22. [22]
  Ju F, VanderVelde D, Nikolla E. Molybdenum-Based Polyoxometalates as Highly Active and Selective Catalysts for the Epimerization of Aldoses[J]. ACS Catal., 2014,4(5):1358-1364. doi: 10.1021/cs401253z
23. [23]
  Kockritz A, Kant M, Walter M, Martin A. Rearrangement of Glucose to Mannose Catalysed by Polymer-Supported Mo Catalysts in the Liquid Phase[J]. Appl. Catal. A, 2008,334(1/2):112-118. doi: 10.1016/j.apcata.2007.09.044
24. [24]
  Hu H, Liu S, Zhang W, An J, Xia H. Efficient Epimerization of Glucose to Mannose over Molybdenum-Based Catalyst in Aqueous Media[J]. ChemistrySelect, 2020,5(5):1728-1733.
25. [25]
  Takagaki A, Furusato S, Kikuchi R, Oyama S T. Efficient Epimerization of Aldoses Using Layered Niobium Molybdates[J]. ChemSusChem, 2015,8(22):3769-3772.
26. [26]
  Okuhara T, Watanabe H, Nishimura T, Inumaru K, Misono M. Microstructure of Cesium Hydrogen Salts of 12-Tungstophosphoric Acid Relevant to Novel Acid Catalysis[J]. Chem. Mater., 2000,12(8):2230-2238.
27. [27]
  Ito T, Inumaru K, Misono M. Epitaxially Self Assembled Aggregates of Polyoxotungstate Nanocrystallites, (NH₄)₃PW₁₂O₄₀: Synthesis by Homogeneous Precipitation Using Decomposition of Urea[J]. Chem. Mater., 2001,13(3):824-831. doi: 10.1002/chin.200128028
28. [28]
  Borghese S, Louis B, Blanc A, Pale P. Design of Silver-Heteropolyacids: Toward the Molecular Control of Reactivity in Organic Chemistry[J]. Catal. Sci. Technol., 2011,1(6):981-986. doi: 10.1002/chin.201201027
29. [29]
  Jagadeeswaraiah K, Kumar C R, Prasad P S S, Lingaiah N. Incorporation of Zn²⁺ Ions into the Secondary Structure of Heteropoly Tungstate: Catalytic Efficiency for Synthesis of Glycerol Carbonate from Glycerol and Urea[J]. Catal. Sci. Technol., 2014,4(9):2969-2977.
30. [30]
  WANG M Y, HUANG D F, CHEN X, ZHOU J F, REN Y H, YE L, YUE B, HE H Y. Liquid Phase Assembly of Mesoporous Cs_xH_3-xPW₁₂O₄₀ and Characterization of Their Acidity[J]. Chem. J. Chinese Univesities, 2021,42(9):2734-2741.
31. [31]
  Ilbeygi H, Kim I Y, Kim M G, Cha W, Kumar P S M, Park D H, Vinu A. Highly Crystalline Mesoporous Phosphotungstic Acid: A High-Performance Electrode Material for Energy-Storage Applications[J]. Angew. Chem. Int. Ed., 2019,58(32):10849-10854. doi: 10.1002/anie.201908558
32. [32]
  Geboers J, Van de Vyver S, Carpentier K, Jacobs P, Sels B. Hydrolytic Hydrogenation of Cellulose with Hydrotreated Caesium Salts of Heteropoly Acids and Ru/C[J]. Green Chem., 2011,13(8):2167-2174. doi: 10.1039/c1gc15350a
33. [33]
  Sun M, Zhang J Z, Cao C J, Zhang Q H, Wang Y, Wan H L. Significant Effect of Acidity on Catalytic Behaviors of Cs-Substituted Polyoxometalates for Oxidative Dehydrogenation of Propane[J]. Appl. Catal. A, 2008,349(1/2):212-221. doi: 10.1016/j.apcata.2008.07.035
34. [34]
  Wu W J, Nancollas G H. A New Understanding of the Relationship between Solubility and Particle Size[J]. J. Solution Chem., 1998,27(6):521-531. doi: 10.1023/A:1022678505433
35. [35]
  Ely D R, Garcia R E, Thommes M. Ostwald-Freundlich Diffusion-Limited Dissolution Kinetics of Nanoparticles[J]. Powder Technol., 2014,257:120-123. doi: 10.1016/j.powtec.2014.01.095
36. [36]
  Cybulski A, Kuster B F M, Marin G B. The Kinetics of the Molybdate-Catalyzed Epimerization of D-Glucose and D-Mannose in Aqueous-Solutions[J]. J. Mol. Catal., 1991,68(1):87-103. doi: 10.1016/0304-5102(91)80063-9
37. [37]
  Rojas-Buzo S, Corma A, Boronat M, Moliner M. Unraveling the Reaction Mechanism and Active Sites of Metal-Organic Frameworks for Glucose Transformations in Water: Experimental and Theoretical Studies[J]. ACS Sustainable Chem. Eng., 2020,8(43):16143-16155. doi: 10.1021/acssuschemeng.0c04398
1. [1]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
2. [2]
  Xinyu Miao , Hao Yang , Jie He , Jing Wang , Zhiliang Jin . 调整Keggin型多金属氧酸盐电子结构构建S型异质结用于光催化析氢. Acta Physico-Chimica Sinica, 2025, 41(6): 100051-. doi: 10.1016/j.actphy.2025.100051
3. [3]
  Zhengzheng LIU , Pengyun ZHANG , Chengri WANG , Shengli HUANG , Guoyu YANG . Synthesis, structure, and electrochemical properties of a sandwich-type {Co₆}-cluster-added germanotungstate. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1173-1179. doi: 10.11862/CJIC.20240039
4. [4]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
5. [5]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
6. [6]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
7. [7]
  Zhengyu Zhou , Huiqin Yao , Youlin Wu , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-. doi: 10.3866/PKU.WHXB202312010
8. [8]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
9. [9]
  Fugui XI , Du LI , Zhourui YAN , Hui WANG , Junyu XIANG , Zhiyun DONG . Functionalized zirconium metal-organic frameworks for the removal of tetracycline from water. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 683-694. doi: 10.11862/CJIC.20240291
10. [10]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
11. [11]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
12. [12]
  Xiaowu Zhang , Pai Liu , Qishen Huang , Shufeng Pang , Zhiming Gao , Yunhong Zhang . Acid-Base Dissociation Equilibrium in Multiphase System: Effect of Gas. University Chemistry, 2024, 39(4): 387-394. doi: 10.3866/PKU.DXHX202310021
13. [13]
  Yue Zhao , Yanfei Li , Tao Xiong . Copper Hydride-Catalyzed Nucleophilic Additions of Unsaturated Hydrocarbons to Aldehydes and Ketones. University Chemistry, 2024, 39(4): 280-285. doi: 10.3866/PKU.DXHX202309001
14. [14]
  Chi Li , Jichao Wan , Qiyu Long , Hui Lv , Ying Xiong . N-Heterocyclic Carbene (NHC)-Catalyzed Amidation of Aldehydes with Nitroso Compounds. University Chemistry, 2024, 39(5): 388-395. doi: 10.3866/PKU.DXHX202312016
15. [15]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
16. [16]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
17. [17]
  Zhifang SU , Zongjie GUAN , Yu FANG . Process of electrocatalytic synthesis of small molecule substances by porous framework materials. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2373-2395. doi: 10.11862/CJIC.20240290
18. [18]
  Haiyuan Wang , Yiming Tang , Haoran Guo , Guohui Chen , Yajing Sun , Chao Zhao , Zhen Zhang . Comprehensive Chemistry Experimental Teaching Design Based on the Integration of Science and Education: Preparation and Catalytic Properties of Silver Nanomaterials. University Chemistry, 2024, 39(10): 219-228. doi: 10.12461/PKU.DXHX202404067
19. [19]
  Runhua Chen , Qiong Wu , Jingchen Luo , Xiaolong Zu , Shan Zhu , Yongfu Sun . 缺陷态二维超薄材料用于光/电催化CO₂还原的基础与展望. Acta Physico-Chimica Sinica, 2025, 41(3): 2308052-. doi: 10.3866/PKU.WHXB202308052
20. [20]
  Fangfang WANG , Jiaqi CHEN , Weiyin SUN . CuBi@Cu-MOF composite catalysts for electrocatalytic CO₂ reduction to HCOOH. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 97-104. doi: 10.11862/CJIC.20240350

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(864)
HTML views(247)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Characterization of Mesoporous Cs3PMo12O40 Employed for Catalytic Epimerization Reaction of Aldoses

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Characterization of Mesoporous Cs₃PMo₁₂O₄₀ Employed for Catalytic Epimerization Reaction of Aldoses