Citation: Shu-Yan CHENG, Jia-Wei KOU, Fang-Qin CHENG. Preparation of Dehydrated Ni-Fe Hydrotalcite-like Compounds as an Eco-Friendly Catalyst for Highly Selective Acetalization of Biomass-Derived Furfural[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(11): 2092-2100. doi: 10.11862/CJIC.2021.220 shu

Preparation of Dehydrated Ni-Fe Hydrotalcite-like Compounds as an Eco-Friendly Catalyst for Highly Selective Acetalization of Biomass-Derived Furfural

Shu-Yan CHENG ^{1, 2, 3} ,
Jia-Wei KOU ^1,, ,
Fang-Qin CHENG ³

1.
State Key Laboratory of Clean and Efficient Coal Utilization, Taiyuan University of Technology, Taiyuan 030024, China
2.
College of Environmental & Resource Science, Shanxi University, Taiyuan 030013, China
3.
Shanxi Laboratory for Yellow River, Shanxi University, Taiyuan 030013, China

Corresponding author: Jia-Wei KOU, koujiawei@tyut.edu.cn
Received Date: 18 April 2021
Revised Date: 9 August 2021

Figures(7)

The dehydrated Ni-Fe hydrotalcite-like compounds (Ni-Fe HTLCs) containing nitrate anions were synthesized and applied in furfural acetalization at room temperature. The dehydrated Ni-Fe HTLCs showed good selectivity for furfural acetalization and achieved almost complete conversion of furfural. The dehydrated Ni-Fe HTLCs as water-tolerant Lewis acids and water scavengers was proved to be an efficient bifunctional catalyst for furfural acetalization. The removal of interlayer water leads to shrinkage of Ni-Fe HTLCs particles and increase in electronic repulsion among NO₃^- ions in the interlayer. The weak acid sites in Ni-Fe HTLCs play an important role in furfural acetalization. The dehydration changes structure of the acid sites and thus improves activity of the weak acid sites. The dehydrated Ni-Fe HTLCs can absorb the most of the resulting water during furfural acetalization, but the structure of Ni-Fe HTLCs cannot completely recover after rehydration possibly due to hindering effect of organic molecules diffusing into interlayer space.
- hydrotalcite-like compound,
- furfural,
- acetal,
- bifunctional catalyst,
- bio-oil
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