Citation: Nan SHEN, Yong SHEN, Hong PAN, Li-Hui XU, Kai LI, Zhe-Wei NI, Kai NI, Hang-Li LING. Preparation and Photocatalytic Properties of Cu-Doped BiVO₄ Catalyst[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(10): 1839-1846. doi: 10.11862/CJIC.2021.214 shu

Preparation and Photocatalytic Properties of Cu-Doped BiVO₄ Catalyst

College of Textile and Fashion Engineering, Shanghai University of Engineering Science, Shanghai 201620, China

Corresponding author: Yong SHEN, shenyong@sues.edu.cn
Received Date: 1 June 2021
Revised Date: 7 August 2021

Figures(8)

BiVO₄ photocatalytic materials with different Cu doping amounts were prepared by hydrothermal method at 180℃ via Cu(NO₃)₂·3H₂O as the copper source, and exhibited enhanced photocatalytic performance under visible light. The samples were characterized and analyzed by X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy, UV-Vis absorption spectroscopy, photoluminescence spectra and electrochemical impedance spectroscopy. The photocatalytic activity of rhodamine B (RhB) dye was evaluated under the irradiation of 500 W Xe lamp to simulate the visible light. The results suggest that the Cu doping can not only alter the morphology of BiVO₄, but also influence the photocatalytic activity of BiVO₄. The visible light absorption of BiVO₄ doped with mass ratio of 1% Cu was significantly enhanced in the range of 500~800 nm. This catalyst can achieve the optimum photocatalytic activity for the degradation of RhB (10 mg·L^-1) with degradation rate of 81.6%, which was nearly 20% higher than that of pure BiVO₄ prepared under the same conditions.
- BiVO₄,
- Cu-doped,
- dye degradation,
- photocatalytic
1. [1]
  Ullah S, Ferreira-Neto E P, Hazra C, Parveen R, Ribeiro S J L, Calegaro M L, Serge-Correales Y E. Appl. Catal. B, 2019, 243: 121-135 doi: 10.1016/j.apcatb.2018.09.091
2. [2]
  Wei Y, Zhang Y W, Geng W, Su H R, Long M C. Appl. Catal. B, 2019, 259: 118084 doi: 10.1016/j.apcatb.2019.118084
3. [3]
  Li C X, Che H N, Liu C B, Che G B, Charpentier P A, Xu W Z, Wang X Y, Liu L H. J. Taiwan Inst. Chem. Eng. , 2018, 95: 669-681
4. [4]
  Wu Z B, Yuan X Z, Zeng G M, Jiang L B, Zhong H, Xie Y, C, Wang H, Chen X H, Wang H. Appl. Catal. B, 2018, 225: 8-21 doi: 10.1016/j.apcatb.2017.11.040
5. [5]
  ZHU J X, XIONG Y H, GUO Y. Inorganic Chemicals Industry, 2020, 52(3): 23-27
6. [6]
  LU C L, ZHANG Y F, WANG H L. Journal of Hubei Polytechnic University, 2019(6): 11-14
7. [7]
  Zhao W, Feng Y, Huang H B, Zhou P C, Li J, Zhang L L, Dai B L, Xu J M, Zhu F X, Sheng N, Leung D Y C. Appl. Catal. B, 2019, 245: 448-458 doi: 10.1016/j.apcatb.2019.01.001
8. [8]
  Li W, Chen J F, Guo R T, Wu J M, Zhou X S, Luo J. J. Mater. Sci. : Mater. Electron. , 2017, 28(21): 1-13
9. [9]
  Zhou F Q, Fan J C, Xu Q J, Min Y L. Appl. Catal. B, 2017, 201: 77-83 doi: 10.1016/j.apcatb.2016.08.027
10. [10]
  Wu L J, Wang L, Zhu J, Sun M, Liu X H, Schmuki P, Zhang J. J. Mater. Chem. A, 2020, 8(5): 2563-2570 doi: 10.1039/C9TA13122A
11. [11]
  Wang Y L, Yu D, Wang W, Gao P, Zhong S, Zhang L S, Zhao Q Q, Liu B J. Sep. Purif. Technol. , 2020, 239: 116562 doi: 10.1016/j.seppur.2020.116562
12. [12]
  Zhou B, Zhao X, Liu H J, Qu J H, Huang C P. Sep. Purif. Technol. , 2011, 77(3): 275-282 doi: 10.1016/j.seppur.2010.12.017
13. [13]
  Wang M, Han J, Lv C M, Zhang Y, You M Y, Liu T Y, Li S L, Zhu T. J. Alloys Compd. , 2018, 753: 465-474 doi: 10.1016/j.jallcom.2018.04.068
14. [14]
  Ge L. J. Mol. Catal. A: Chem. , 2008, 282(1/2): 62-66
15. [15]
  Zambrano-Robledo P, Vazquez-Arenas J, Romero-Ibrra I, Ostos C, Peral J. Appl. Surf. Sci. , 2019, 487: 743-754 doi: 10.1016/j.apsusc.2019.05.041
16. [16]
  Ge L. Mater. Chem. Phys. , 2008, 107(2/3): 465-470
17. [17]
  Chen P. J. Mater. Sci. : Mater. Electron. , 2016, 27(3): 2394-2403 doi: 10.1007/s10854-015-4037-5
18. [18]
  Regmi C, Kshetri Y K, Kim T, Pandey R P, Ray S K, Lee S W. Appl. Surf. Sci. , 2017, 475: 253-265
19. [19]
  Li H B, Zhang J, Huang G Y, Fu S H, Ma C, Wang B Y, Huang Q R, Liao H W. Trans. Nonferrous Met. Soc. China, 2017, 27(4): 868-875 doi: 10.1016/S1003-6326(17)60102-X
20. [20]
  Geng Y L, Zhang P, Li N, Sun Z H. J. Alloys Compd. , 2015, 651: 744-748 doi: 10.1016/j.jallcom.2015.08.123
21. [21]
  Shan L W, Liu H G, Wang G L. J. Nanopart. Res. , 2015, 17(4): 1-11
22. [22]
  Gu S N, Li W J, Wang F Z, Li H D, Zhou H L. Catal. Sci. Technol. , 2016, 6(6): 1870-1881 doi: 10.1039/C5CY01412C
23. [23]
  Merupo V I, Velumani S, Ordon K, Errien N, Szade J, Kassiba A H. CrystEngComm, 2015, 17(17): 3366-3375 doi: 10.1039/C5CE00173K
24. [24]
  Liu X L, Xu L Y, Zhou G S, Liu Q, Lu Z, Song M S, Han S. J. Taiwan Inst. Chem. Eng. , 2020, 117: 48-55 doi: 10.1016/j.jtice.2020.11.028
25. [25]
  Cui J W, Wang G H, Liu W, Ke P, Tian Y, Li X, Tian Y S. Fuel, 2021, 290: 120066 doi: 10.1016/j.fuel.2020.120066
26. [26]
  Che H N, Chen J B, Huang K, Hu W, Hu H, Liu X T, Che G B, Liu C B, Shi W D. J. Alloys Compd. , 2016, 688: 882-890 doi: 10.1016/j.jallcom.2016.07.311
27. [27]
  Wang Z L, Lv J L, Zhang J F, Dai K, Liang C H. Appl. Surf. Sci. , 2017, 430(1): 595-602
28. [28]
  Jo W J, Jang J W, Kong K J, Kang H J, Kim J Y, Jun H, Parmar K P S, Lee J S. Angew. Chem. Int. Ed. , 2012, 51(13): 3147-3151 doi: 10.1002/anie.201108276
29. [29]
  Xia T, Chen M, Xiao L S, Fan W Q, Mao B D, Xu D B, Guan P, Zhu J J, Shi W D. J. Taiwan Inst. Chem. Eng. , 2018, 93: 582-589
30. [30]
  Tang C N, Liu E Z, Wan J, Hu X Y, Fan J. Appl. Catal. B, 2016, 181: 707-715
31. [31]
  Palaniswamy V K, Ramasamy B, Manoharan K, Raman K, Sundaram R. Chem. Phys. Lett. , 2021, 771(9): 138531
32. [32]
  Wang Y L, Yu D, Wang W, Gao P, Zhang L S, Zhong S, Liu B J. Colloids Surf. A, 2019, 578: 123608
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Photocatalytic Properties of Cu-Doped BiVO4 Catalyst

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通讯作者: 陈斌, bchen63@163.com

Preparation and Photocatalytic Properties of Cu-Doped BiVO₄ Catalyst