Citation: Guang-Huai PENG, He-Rui WEN, Zhuo HAN, Jin-Sheng LIAO. Synthesis and Luminescence Properties of Double Perovskite Ca₂Gd_1-xTaO₆: xTb³⁺ Green Phosphors[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(10): 1893-1899. doi: 10.11862/CJIC.2021.203 shu

Synthesis and Luminescence Properties of Double Perovskite Ca₂Gd_1-xTaO₆: xTb³⁺ Green Phosphors

Guang-Huai PENG ^{1, 2} ,
He-Rui WEN ^1,, ,
Zhuo HAN ¹ ,
Jin-Sheng LIAO ^1,,

1.
School of Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou, Jiangxi 341000, China
2.
School of Chemistry and Chemical Engineering, Gannan Normal University, Ganzhou, Jiangxi 341000, China

Corresponding author: He-Rui WEN, wenherui63@163.com Jin-Sheng LIAO, jsliao1209@126.com
Received Date: 13 April 2021
Revised Date: 9 August 2021

Figures(10)

A series of double perovskite Ca₂Gd_1-xTaO₆: xTb³⁺ (CGTO: xTb³⁺) phosphors were prepared by a hightemperature solid-state reaction method. The X-ray diffraction, scanning electron microscopy, photoluminescence spectroscopy, decay curve and quantum efficiency (η) were used to characterize CGTO: xTb³⁺ phosphors. Under UV excitation, CGTO: xTb³⁺ phosphors show intense green light emission, which is originated from the characteristic ⁵D₄-⁷F₅ transition of the Tb³⁺ ion. On the basis of temperature-dependence luminescence spectra, the activation energy of thermal quenching was about 0.181 9 eV for CGTO: 0.15Tb³⁺ phosphor. CGTO: 0.15Tb³⁺ phosphor as optimum doping concentration exhibited intensive green emission with the η of 32.32% under 255 nm excitation.
- green phosphor,
- Ca₂GdTaO₆,
- luminescence,
- Tb³⁺
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沈阳化工大学材料科学与工程学院沈阳 110142

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Synthesis and Luminescence Properties of Double Perovskite Ca₂Gd_1-xTaO₆: xTb³⁺ Green Phosphors