Citation: Ru LIU, Bi-Yao JIN, Yi-Ming ZHAO, Lian-Hua ZHAO. Preparation and Oxygen Reduction Activity of PdMo Catalyst by Phase Transfer Method[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(10): 1819-1827. doi: 10.11862/CJIC.2021.201 shu

Preparation and Oxygen Reduction Activity of PdMo Catalyst by Phase Transfer Method

College of Science, Yanbian University, Yanji, Jilin 133002, China

Corresponding author: Bi-Yao JIN, biyaojin@ybu.edu.cn Lian-Hua ZHAO, zhaolianhua@ybu.edu.cn
Received Date: 21 April 2021
Revised Date: 9 August 2021

Figures(7)

A series of Pd_xMo/C (atomic ratio x of Pd/Mo was 1, 2, 3, 4, 5, respectively) catalysts in dichloromethane were prepared by phase transfer method using tetrabutylammonium hydroxide as phase transfer agent and sodium borohydride as reducing agent. Trancmission electron microscope (TEM) images showed that Pd_xMo/C was 2~4 nm circular particles with uniform size and good dispersion. The X-ray diffraction (XRD) results showed that the crystal lattice of Pd was expanded by adding the second component Mo, and the lattice structure of Pd was adjusted. In addition, X-ray photoelectron spectroscopy (XPS) results show that compared with Pd/C, the binding energy of Pd3d_5/2 for Pd₄Mo/C was shifted by 0.50 eV to the lower direction, indicating that Pd with higher electronegativity absorbs electrons from Mo, and the electronic structure changes. The results of oxygen reduction reaction (ORR) showed that the activity of different ratios of Pd_xMo/C was better than that of Pd/C, and the ORR activity was the best when x=4. The initial oxidation potential and half-wave potential were 0.876 and 0.813 V, respectively, which were higher than that of 0.870 and 0.810 V of commercial Pt/C. In addition, the current density retained 82.9% after 3 h of operation, showing a significant advantage over commercial Pt/C.
- Pd_xMo/C,
- phase transfer method,
- electrocatalytic oxygen reduction,
- fuel cell
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