Citation: Yuan-Peng XIONG, Fan-Dong KONG, Rui-Xing LI. Mie Scattering Theory Deduction and Experimental Verification of Correlation Between Length of One-Dimensional Nanomaterials Cs_0.2WO₃ and W₁₈O₄₉ and Infrared Absorption[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(10): 1764-1772. doi: 10.11862/CJIC.2021.200 shu

Mie Scattering Theory Deduction and Experimental Verification of Correlation Between Length of One-Dimensional Nanomaterials Cs_0.2WO₃ and W₁₈O₄₉ and Infrared Absorption

1.
School of Materials Science and Engineering, Beihang University, Beijing 100191, China
2.
Fujian Polytechnic Normal University, Fuzhou 350300, China

Corresponding author: Rui-Xing LI, rli@buaa.edu.cn
Received Date: 4 March 2021
Revised Date: 16 July 2021

Figures(12)

The research results show size- and shape-dependent infrared absorption properties for binary and ternary tungsten-oxides. However, there is no universal theory in both physical principle and calculation method for binary and ternary tungsten-oxides. In this study, the correlation between the optical absorption characteristics and onedimensional material length was deduced based on Mie scattering theory, and the correlation of tungsten oxide based materials was studied by means of theoretical deductions and experimental verifications. Firstly, from a perspective of deduction and calculation based on Mie scattering theory reveal that increasing the length of both nanoCs_0.2WO₃ and W₁₈O₄₉ can improve their near-infrared absorption performance. Secondly, the near-infrared absorption performance of synthesized Cs_0.2WO₃ nanorods and W₁₈O₄₉ nanowires with different lengths was tested. The experimental data is consistent with the theoretical calculations and simulation results. Cs_0.2WO₃ nanorods and W₁₈O₄₉ nanowires have different trends with particle length between 2 500 and 20 000 nm, and the infrared absorption properties of Cs_0.2WO₃ nanorods were proportional to particle length. Finally, the photothermal effects of Cs_0.2WO₃ nanorods and W₁₈O₄₉ nanowires were tested. And the amplification of temperature reached 18.5% and 12.7% with the increase of particle length for both nano-tungsten oxides, respectively.
- Mie scattering,
- one-dimensional,
- infrared absorption,
- Cs_0.2WO₃,
- W₁₈O₄₉
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Mie Scattering Theory Deduction and Experimental Verification of Correlation Between Length of One-Dimensional Nanomaterials Cs0.2WO3 and W18O49 and Infrared Absorption

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通讯作者: 陈斌, bchen63@163.com

Mie Scattering Theory Deduction and Experimental Verification of Correlation Between Length of One-Dimensional Nanomaterials Cs_0.2WO₃ and W₁₈O₄₉ and Infrared Absorption