Citation: Jian-Fei GAO, Rong-Rong NIE, Zhe FENG, Dun-Ru ZHU. Coexistence of Two Unique Cu(Ⅱ) Ions in Mononuclear Cu(Ⅱ) Complexes with Furanyl Substituted Triaryltriazoles[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(9): 1707-1712. doi: 10.11862/CJIC.2021.190 shu

Coexistence of Two Unique Cu(Ⅱ) Ions in Mononuclear Cu(Ⅱ) Complexes with Furanyl Substituted Triaryltriazoles

Jian-Fei GAO ¹ ,
Rong-Rong NIE ¹ ,
Zhe FENG ¹ ,
Dun-Ru ZHU ^{1, 2,,}

1.
College of Chemical Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 211816, China
2.
State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210023, China

Corresponding author: Dun-Ru ZHU, zhudr@njtech.edu.cn
Received Date: 10 May 2021
Revised Date: 2 June 2021

Figures(4)

Two new mononuclear Cu(Ⅱ) complexes, trans-[Cu(L¹)₂(NO₃)₂]_0.5[Cu(L¹)₂(H₂O)₂]_0.5(NO₃) (1) and trans-[Cu(L²)₂(NO₃)₂]_0.5[Cu(L²)₂(H₂O)₂]_0.5(NO₃)·₂CH₃OH (2) (L¹=3-(2-pyridyl)-4-phenyl-5-(2-furanyl)-1, 2, 4-triazole, L²=3-(2-pyridyl) -4-(p-fluorophenyl)-5-(2-furanyl)-1, 2, 4-triazole), were synthesized and characterized by FT-IR, elemental analyses, thermogravimetric analyses, single-crystal X-ray crystallography and powder X-ray diffraction. Both complexes 1 and 2 crystallize in triclinic system with space group P1. The crystal structure analysis shows that there are two crys-tallographically different Cu(Ⅱ) ions in 1 and 2 and each Cu(Ⅱ) ion lies in a distorted octahedral[CuN₄O₂] environment. However, in the axial position one Cu(Ⅱ) ion is coordinated with two water molecules, while another Cu(Ⅱ) ion with two nitrate ions. The L1 or L2 ligand coordinates with Cu(Ⅱ) via one pyridine N atom and one triazole N atom, while the furanyl group does not participate in coordination. In 1 and 2 there are some intermolecular C-H…N, C-H…O, O-H…O hydrogen bonding and C-H…π interactions, linking the mononuclear complex (1 or 2) to form a two-dimensional network.
- furan,
- Cu(Ⅱ) complex,
- crystal structure,
- triaryltriazole
1. [1]
  Kahn O, Martinez C J. Science, 1998, 279(5347): 44-48 doi: 10.1126/science.279.5347.44
2. [2]
  El-Sebaey S A. Chemistry Select., 2020, 5(37): 11654-11680
3. [3]
  Sathyanarayana R, Poojary B. J. Chin. Chem. Soc., 2020, 67(4): 459-477 doi: 10.1002/jccs.201900304
4. [4]
  Bulger P G, Cottrell I F, Cowden C J, Davies A J, Dolling U H. Tetrahedron Lett., 2000, 41(8): 1297-1301 doi: 10.1016/S0040-4039(99)02272-8
5. [5]
  Klingele M H, Brooker S. Coord. Chem. Rev., 2003, 241(1/2): 119-132
6. [6]
  Kitchen J A, Brooker S. Coord. Chem. Rev., 2008, 252(18/19/20): 2072-2092
7. [7]
  Aromí G, Barrios L A, Roubeau O, Gamez P. Coord. Chem. Rev., 2011, 255(5/6): 485-546
8. [8]
  Rezki N, Aouad M R. Acta Pharm., 2017, 67(3): 309-324 doi: 10.1515/acph-2017-0024
9. [9]
  Deodware S A, Sathe D J, Choudhari P B, Lokhande T N, Gaikwad S H. Arabian J. Chem., 2017, 10(2): 262-272 doi: 10.1016/j.arabjc.2016.09.024
10. [10]
  Shen G P, Zhao J, Jiang J J, Liu Q, Shen X, Xu Y, Zhu D R, Liu X Q. J. Mol. Struct., 2011, 1002(1/2/3): 159-166
11. [11]
  Lu W, Zhu D R, Xu Y, Cheng H M, Zhao J, Shen X. Struct. Chem., 2010, 21(1): 237-244 doi: 10.1007/s11224-009-9569-y
12. [12]
  Chen L, Zhao J, Shen G P, Shen X, Xu Y, Zhu D R, Wang J. J. Coord. Chem., 2011, 64(22): 3980-3991 doi: 10.1080/00958972.2011.634909
13. [13]
  LU W, XIE D J, WANG Z X, SHEN X, XU Y, ZHU D R. Chinese J. Inorg. Chem., 2010, 26(4): 717-720
14. [14]
15. [15]
  FENG Z, GAO J F, LI G, ZHU D R. Chinese J. Inorg. Chem., 2020, 36(6): 1169-1175
16. [16]
17. [17]
  Liu W Y, Xie Y S, Zhao B X, Lian S, Lv H S, Gong Z L, Shin D S. Spectrochim. Acta A, 2010, 76(5): 531-536 doi: 10.1016/j.saa.2010.04.019
18. [18]
  Beyzael H, Khosravi Z, Aryan R, Ghasemi B. J. Iran. Chem. Soc., 2019, 16(12): 2565-2573 doi: 10.1007/s13738-019-01714-2
19. [19]
  Farag P S, Hemdan M M, El-Sayed A A. J. Heterocycl. Chem., 2020, 57(9): 3428-3441
20. [20]
  Wang L, Jiang J J, Chen L, Shen X, Zhu D R. Inorg. Chem. Commun., 2013, 28: 104-108 doi: 10.1016/j.inoche.2012.11.022
21. [21]
  Zhou Y F, Zhang S P, Feng Z, Shen X, Zhu D R. J. Heterocycl. Chem., 2017, 54(5): 2773-2780 doi: 10.1002/jhet.2880
22. [22]
  Sheldrick G M. Acta Crystallogr. Sect. A, 2008, A64(1): 112-122
23. [23]
  Zhang Y C, Wu Y H, He X, Ma J H, Shen X, Zhu D R. Acta Crystallogr. Sect. C, 2018, C74(3): 256-262
1. [1]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
2. [2]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
3. [3]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
4. [4]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
5. [5]
  Maitri Bhattacharjee , Rekha Boruah Smriti , R. N. Dutta Purkayastha , Waldemar Maniukiewicz , Shubhamoy Chowdhury , Debasish Maiti , Tamanna Akhtar . Synthesis, structural characterization, bio-activity, and density functional theory calculation on Cu(Ⅱ) complexes with hydrazone-based Schiff base ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1409-1422. doi: 10.11862/CJIC.20240007
6. [6]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
7. [7]
  Jia JI , Zhaoyang GUO , Wenni LEI , Jiawei ZHENG , Haorong QIN , Jiahong YAN , Yinling HOU , Xiaoyan XIN , Wenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344
8. [8]
  Yinling HOU , Jia JI , Hong YU , Xiaoyun BIAN , Xiaofen GUAN , Jing QIU , Shuyi REN , Ming FANG . A rhombic Dy₄-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251
9. [9]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
10. [10]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
11. [11]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273
12. [12]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
13. [13]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
14. [14]
  Yan XU , Suzhi LI , Yan LI , Lushun FENG , Wentao SUN , Xinxing LI . Structure variation of cadmium naphthalene-diphosphonates with the changing rigidity of N-donor auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 395-406. doi: 10.11862/CJIC.20240226
15. [15]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
16. [16]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
17. [17]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
18. [18]
  Zhaodong WANG . In situ synthesis, crystal structure, and magnetic characterization of a trinuclear copper complex based on a multi-substituted imidazo[1,5-a]pyrazine scaffold. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 597-604. doi: 10.11862/CJIC.20240268
19. [19]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
20. [20]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(462)
HTML views(33)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142