Citation: Zhong-Lian XIAO, Xuan-Yi WU, He-Yun TAN, Aprea Paolo, Shi-You HAO. Effect of Zn on Photocatalytic Activity of Block-Shaped Monoclinic WO₃[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(9): 1700-1706. doi: 10.11862/CJIC.2021.189 shu

Effect of Zn on Photocatalytic Activity of Block-Shaped Monoclinic WO₃

Zhong-Lian XIAO ^{1, #} ,
Xuan-Yi WU ^{1, #} ,
He-Yun TAN ¹ ,
Aprea Paolo ² ,
Shi-You HAO ^1,,

1.
Xingzhi College, College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua, Zhejiang 321004, China
2.
Department of Chemical, Materials and Production Engineering, University Federico Ⅱ, Naples 802125, Italy

Corresponding author: Shi-You HAO, sky54@zjnu.cn

Received Date: 21 March 2021
Revised Date: 8 June 2021

Figures(5)

Zn-doped block-shaped monoclinic WO₃ composite (Zn-doped WO₃) was synthesized via a facile method and the photocatalytic activity of rhodamine B (RhB) over Zn-doped WO₃ was evaluated. The prepared samples were characterized by X-ray diffraction, Raman spectrum, scanning electron micrograph, UV-Vis diffuse reflection spectrum, Fourier transform infrared spectrum, and X-ray photoelectron spectrum and other techniques, and the results showed that the block-shaped monoclinic WO₃ did not be changed by appropriate amount of Zn doping. The photo-catalytic results illustrated that mass ratio of 5% Zn doped WO₃ performed the best photocatalytic efficiency due to the formation of more oxygen vacancy and the increase of hydroxyl groups number.
- Zn,
- WO₃,
- synthesis,
- photocatalysis,
- oxygen vacancy
1. [1]
  Kim K H, Ihm S K. J. Hazard. Mater., 2011, 186: 16-34 doi: 10.1016/j.jhazmat.2010.11.011
2. [2]
  Liu X D, Yan L, Yin W Y, Zhou L J, Tian G, Shi J X, Yang Z Y, Xiao D B, Gu Z J, Zhao Y L. J. Mater. Chem. A, 2014, 2: 12296-12303 doi: 10.1039/C4TA00753K
3. [3]
  Salleh M A M, Mahmoud D K, Karim W A, Idris A. Desalination, 2011, 280: 1-13 doi: 10.1016/j.desal.2011.07.019
4. [4]
  Koyuncu, D D E, Okur M. Sep. Purif. Technol., 2021, 257: 117657 doi: 10.1016/j.seppur.2020.117657
5. [5]
  Liu Y, Xu D L, Wang P, Dong Y H. Desalin. Water Treat., 2016, 57: 6772-6780 doi: 10.1080/19443994.2015.1010232
6. [6]
  Wang Y F, Geng Q J, Yang J M, Liu, Y, Liu C. ACS Omega, 2020, 5: 31137-31145 doi: 10.1021/acsomega.0c04285
7. [7]
  Malato S, Fernandez-Ibanez P, Maldonado M I, Blanco J, Gernjak W. Catal. Today, 2009, 147: 1-60
8. [8]
  Roussel P, Labbe P, Groult D. Acta Crystallogr. Sect. B: Struct. Sci., 2000, 56: 377-399 doi: 10.1107/S0108768199016195
9. [9]
  Gillet M, Aguir K, Lemire C, Gillet E, Schierbaum K. Thin Solid Films, 2004, 467: 239-246 doi: 10.1016/j.tsf.2004.04.018
10. [10]
  Shang J, Xiao Z L, Yu L X, Aprea P, Hao S Y. Nanotechnology, 2020, 31: 125603 doi: 10.1088/1361-6528/ab5c4f
11. [11]
  Xi G C, Yue B, Cao J Y, Ye J H. Chem. Eur. J., 2011, 17: 5145-5154 doi: 10.1002/chem.201002229
12. [12]
  Odhiambo V O, Ongarbayeva A, Keri O, Simon L, Szilagyi I M. Nanomaterials, 2020, 10: 882 doi: 10.3390/nano10050882
13. [13]
  Dursun S, Koyuncu S N, Kaya I C, Kaya G G, Kalem V, Akyildiz H. J. Water Process Eng., 2020, 36: 101390 doi: 10.1016/j.jwpe.2020.101390
14. [14]
  Truong H B, Huy B T, Ray S K, Lee Y I, Cho J, Hur J. Chem. Eng. J., 2020, 399: 125733 doi: 10.1016/j.cej.2020.125733
15. [15]
  Zeng W, Ren Y F, Zheng Y Y, Pan A Q, Zhu T. ChemCatChem, 2021, 13: 564-573 doi: 10.1002/cctc.202001407
16. [16]
  Lin Y, Hu H Y, Hu Y H. Appl. Surf. Sci., 2020, 502: 144202 doi: 10.1016/j.apsusc.2019.144202
17. [17]
  Chen J, Xiong Y, Duan M, Li X, Li J, Fang S W, Qin S, Zhang R. Langmuir, 2020, 36: 520-533 doi: 10.1021/acs.langmuir.9b02879
18. [18]
  Arshad M, Ehtisham-ul-Haque S, Bilal M, Ahmad N, Ahmad A, Abbas M, Nisar J, Khan M I, Nazir A, Ghaffar A, Iqba M. Mater. Res. Express, 2020, 7: 015407 doi: 10.1088/2053-1591/ab6380
19. [19]
  Santhi K, Rani C, Kumar R D, Karuppuchamy S. J. Mater. Sci. : Mater. Electron., 2015, 26: 10068-10074 doi: 10.1007/s10854-015-3689-5
20. [20]
  Chen S H, Xiao Y, Xie W, Wang Y H, Hu Z F, Zhang W, Zhao H. Nanomaterials, 2018, 8: 1-13
21. [21]
  Djaoued Y, Balaji S, Bruning R. J. Nanomater., 2012, 2012: 674168
22. [22]
  Huang Y S, Zhang Y Z, Zeng X T, Hu X F. Appl. Surf. Sci., 2002, 202: 104-109 doi: 10.1016/S0169-4332(02)00943-1
23. [23]
  Akira S, Hamdi A, Addad A, Coffinier Y, Boukherroub R, Omrani A D. Appl. Surf. Sci., 2017, 400: 461-470 doi: 10.1016/j.apsusc.2016.12.212
24. [24]
  Samanta S, Martha S, Parida K. ChemCatChem, 2014, 6: 1453-1462
25. [25]
  Annanouch E F, Roso S, Haddi Z, Vallejos S, Umek P, Bittencourt C, Blackman C, Vilic T, Llobe E. Thin Solid Films, 2016, 618: 238-245 doi: 10.1016/j.tsf.2016.08.053
26. [26]
  Ozin G A, Prokopowicz R A, Ozkar S. J. Am. Chem. Soc., 1992, 114: 8953-8963 doi: 10.1021/ja00049a028
27. [27]
  Hao S Y, Hou J, Aprea P, Pepe F. Appl. Catal. B, 2014, 160-161: 566-573
28. [28]
  Hao S Y, Hou J, Aprea P, Lv T X. Ind. Eng. Chem. Res., 2014, 53: 14617-14622
29. [29]
  Wang Y G, Li B, Zhang C L, Cui L F, Kang S F, Li X, Zhou L H. Appl. Catal. B, 2013, 130-131: 277-84
30. [30]
  Han H G, Li H P, Fu L, Yang J, Liu Z. Chem. Phys. Lett., 2016, 651: 183-187
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Effect of Zn on Photocatalytic Activity of Block-Shaped Monoclinic WO3

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通讯作者: 陈斌, bchen63@163.com

Effect of Zn on Photocatalytic Activity of Block-Shaped Monoclinic WO₃