Citation: Chuan-Hao ZHANG, Ning-Yue LU, Bin-Bin FAN, Rui-Feng LI. Effects of Coordination Cations over Zeolite on Hydrogenation Performance of Pd/H-ZSM-5 Catalyst[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(9): 1625-1632. doi: 10.11862/CJIC.2021.185 shu

Effects of Coordination Cations over Zeolite on Hydrogenation Performance of Pd/H-ZSM-5 Catalyst

College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China

Corresponding author: Bin-Bin FAN, fanbinbin@tyut.edu.cn
Received Date: 18 March 2021
Revised Date: 24 June 2021

Figures(7)

Pd/H-ZSM-5 catalysts were prepared by conventional impregnation method with commercial hierarchical NH₄-ZSM-5 and H-ZSM-5 (NH₄-ZSM-5 calcined at 550℃ for 6 h in air atmosphere) zeolite as the supports, and H₂PdCl₄ as the metal precursor. The physicochemical properties and catalytic performance of the prepared samples were characterized by X-ray diffraction, scanning electron microscopy, N₂ adsorption-desorption, UV-Vis spectroscopy, X-ray photoelectron spectroscopy, NH₃-temperature programmed desorption, transmission electron microscopy and naphthalene hydrogenation reaction. The results showed that the coordination cations over zeolites greatly influence the dispersion of the supported metal species and catalyst acidity. The NH₄⁺ over ZSM-5 supports was conducive to the dispersion of the supported Pd species, and the prepared Pd/H-ZSM-5(NH₄) had more acid sites than Pd/H-ZSM-5(H), which resulted in that Pd/H-ZSM-5(NH₄) exhibited higher catalytic activity in naphthalene hydrogenation than Pd/H-ZSM-5(H).
- ZSM-5 zeolite,
- coordination cations,
- naphthalene,
- hydrogenation reaction
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