Citation: Qing-Yuan XIE, Dan LI, Dan-Dan LI, Sheng-Li LI, Jie-Ying WU, Qiong ZHANG, Yu-Peng TIAN. Design, Synthesis, Electrochemical Activity and Multiphoton Absorption of Ferrocenyl Diketone Zn(Ⅱ) Complex[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(9): 1665-1673. doi: 10.11862/CJIC.2021.183 shu

Design, Synthesis, Electrochemical Activity and Multiphoton Absorption of Ferrocenyl Diketone Zn(Ⅱ) Complex

Qing-Yuan XIE ¹ ,
Dan LI ¹ ,
Dan-Dan LI ¹ ,
Sheng-Li LI ¹ ,
Jie-Ying WU ¹ ,
Qiong ZHANG ^{1, 2,,} ,
Yu-Peng TIAN ^{1, 2,,}

1.
Key Laboratory of Functional Inorganic Materials Chemistry of Anhui Province, Department of Chemistry, Anhui University, Hefei 230601, China
2.
State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210023, China

Corresponding author: Qiong ZHANG, zhangqiong.314@163.com Yu-Peng TIAN, yptian@ahu.edu.cn
Received Date: 22 March 2021
Revised Date: 15 May 2021

Figures(10)

A functional ferrocenyl ligand (L) with D-A configuration and its complex (NHEt₃)[ZnL₃] were synthesized. Single crystal analysis shows that the ferrocene diketone loses a proton to coordinate with Zn²⁺, which finally gives the negative monovalent ferrocene diketo Zn(Ⅱ) complex. The results from electrochemical cyclic voltammetry and IR in situ revealed that (NHEt₃)[Zn(L)₃] went through two-step oxidation and one-step reduction process. As the potential increased during the oxidation process, one ferrocene (Fc) unit was oxidized to Fc⁺, forming a D-A asymmetric structure mode. Along with the oxidation continued, the other Fc units were also oxidized. The three Fc⁺ with Zn²⁺ still formed the D-A structure mode, and finally the Fc⁺ was reduced to Fc in one step. Theoretical calculation result shows that the complex is prone to exist high degree of electron delocalization. The experiment results from nonlinear optical property determinations show that the complex has a larger two/three-photon absorption cross sections and third-order nonlinear optical susceptibility in near IR region.
- ferrocenyl diketone Zn(Ⅱ) complex,
- nonlinear optics,
- multiphoton absorption,
- in situ FTIR spectroelectrochemistry
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