Citation: Fu-Zhi LI, Zhen CHEN, Dan ZHANG, Ao-Kui SUN, Pu SHI, Quan-Guo HE. Preparation and Catalytic Performance of Co-Co₉S₈/N-Doped Ketjen Black Composite for Oxygen Reduction Reaction[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(9): 1579-1588. doi: 10.11862/CJIC.2021.180 shu

Preparation and Catalytic Performance of Co-Co₉S₈/N-Doped Ketjen Black Composite for Oxygen Reduction Reaction

Fu-Zhi LI ¹ ,
Zhen CHEN ¹ ,
Dan ZHANG ¹ ,
Ao-Kui SUN ¹ ,
Pu SHI ^1,, ,
Quan-Guo HE ^2,,

1.
College of Packaging and Materials, Hunan University of Technology, Zhuzhou, Hunan 412008, China
2.
College of Life Science and Chemistry, Hunan University of Technology, Zhuzhou, Hunan 412008, China

Corresponding author: Pu SHI, shipu1976@163.com Quan-Guo HE, hequanguo@hut.edu.cn
Received Date: 3 March 2021
Revised Date: 26 June 2021

Figures(10)

Co-Co₉S₈/N-KB composite catalyst supported by high conductivity carbon (nitrogen doped Ketjen black) and introduced by single metal for oxygen reduction reaction (ORR) was prepared using Prussian blue analogue as precursor through high temperature annealing technology. By comparison of different annealing temperatures, it is found that the catalyst gained at the annealing temperature of 800℃ showed the best catalytic activity for ORR. The initial potential and half-wave potential were 0.93 and 0.83 V respectively, comparable to commercial Pt/C, and the limit current density reached 5.7 mA·cm^-2, higher than that of Pt/C. After a long period of 10 000 s for chronoam-perometry experiment, the current density still retained at 95.6% of the initial, and the half-wave potential shifted just only 8.6 mV after 5 000 cycles subjected in a range of 0.5 to 1.0 V (vs RHE) during the accelerated durability test. In addition, in actual Al-air full battery applications, the discharge platform of Co-Co₉S₈/N-KB reached 1.53 V at a discharge density of 50 mA·cm^-2, higher than that of Pt/C.
- cobalt sulfide,
- aluminum-air battery,
- oxygen reduction reaction catalyst
1. [1]
  Ma J L, Wen J B, Gao J W, Li Q N. Electrochim. Acta, 2014, 129(6): 69-75
2. [2]
  Ferrando W A. J. Power Sources, 2004, 130(1/2): 309-314
3. [3]
  Lei B, Li G R, Gao X P. J. Mater. Chem. A, 2014, 2(11): 3919-3925 doi: 10.1039/c3ta14313a
4. [4]
  Huang S S, Zai J T, Ma D, Hu Z J, He Q Q, Wu M H, Chen D Y, Chen Z W, Qian X F. Electrochim. Acta, 2017, 241: 89-97 doi: 10.1016/j.electacta.2017.04.116
5. [5]
  Han C, Li Q, Wang D W, Lu Q Q, Xing Z C, Yang X R. Small, 2018, 14(17): 1703642 doi: 10.1002/smll.201703642
6. [6]
  Ding J T, Ji S, Wang H, Bruno G P, Wang R F. ChemCatChem, 2019, 11(3): 1026-1032 doi: 10.1002/cctc.201801618
7. [7]
  Zhao L, Zhang Y, Huang L B, Liu X Z, Zhang Q H, He C, Wu Z Y, Zhang L J, Wu J P, Yang W L, Gu L, Hu J S, Wan L J. Nat. Commun., 2019, 10(1): 1278-1288 doi: 10.1038/s41467-019-09290-y
8. [8]
  Yu X Y, Yu L, Wu H B, Lou X W. Angew. Chem. Int. Ed., 2015, 27(18): 5421-5425
9. [9]
  Hu M, Jiang J S, Ji R P, Zeng Y. CrystEngComm, 2009, 11(11): 2257-2259 doi: 10.1039/b911613n
10. [10]
  Hu L, Zhang P, Chen Q W, Mei J Y. RSC Adv., 2011, 1(8): 1574-1578 doi: 10.1039/c1ra00624j
11. [11]
  Sanetuntikul J, Shanmugam S. Nanoscale, 2015, 7(17): 7644-7650 doi: 10.1039/C5NR00311C
12. [12]
  Liu Y Y, Jiang H L, Zhu Y H, Yang X L, Li C Z. J. Mater. Chem. A, 2016, 4(5): 1694-1701 doi: 10.1039/C5TA10551J
13. [13]
  Ashok A, Kumar A, Ponraj J, Mansour S A. Electrochim. Acta, 2021, 368: 137642 doi: 10.1016/j.electacta.2020.137642
14. [14]
  Ren J C, Meng Q, Xu Z Y, Zhang X H, Chen J H. J. Electroanal. Chem., 2019, 836: 30-37 doi: 10.1016/j.jelechem.2019.01.049
15. [15]
  Wang Z D, Bai C K, Chen X Y, Wang B D, Sun H, Lu G L, Huang H, Liu Z N, Liang S, Zang H Y. Inorg. Chem. Front., 2019, 6(9): 2558-2565 doi: 10.1039/C9QI00796B
16. [16]
  Lu X F, Wu D J, Li R Z, Li Q, Ye S H, Tong Y X, Li G R. J. Mater. Chem. A, 2014, 2(13): 4706-4713 doi: 10.1039/C3TA14930G
17. [17]
  Choudhury T, Saied S O, Sullivan J L, Abbot A M. J. Phys. D: Appl. Phys., 1989, 22(8): 1185-1195 doi: 10.1088/0022-3727/22/8/026
18. [18]
19. [19]
  Li S S, Cong H P, Wang P, Yu S H. Nanoscale, 2014, 6(13): 7534-7541 doi: 10.1039/C4NR02101K
20. [20]
  He X B, Yin F X, Yuan S, Liu N, Huang X F. ChemElectroChem, 2016, 3(7): 1107-1115
21. [21]
  Xie W F, Li Z H, Jiang S, Li J B, Shao M F, Wei M. Chem. Eng. J., 2019, 373: 734-743 doi: 10.1016/j.cej.2019.04.066
22. [22]
  Wang Z, Ang J M, Zhang B W, Zhang Y F, Ma X Y D, Yan T, Liu J, Che B Y, Huang Y Z, Lu X H. Appl. Catal. B, 2019, 254: 26-36 doi: 10.1016/j.apcatb.2019.04.027
23. [23]
  Li J S, Zhou Z, Liu K, Li F Z, Peng Z G, Tang Y G, Wang H Y. J. Power Sources, 2017, 343(1): 30-38
1. [1]
  Jiahe LIU , Gan TANG , Kai CHEN , Mingda ZHANG . Effect of low-temperature electrolyte additives on low-temperature performance of lithium cobaltate batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 719-728. doi: 10.11862/CJIC.20250023
2. [2]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
3. [3]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
4. [4]
  Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363
5. [5]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
6. [6]
  Yang WANG , Xiaoqin ZHENG , Yang LIU , Kai ZHANG , Jiahui KOU , Linbing SUN . Mn single-atom catalysts based on confined space: Fabrication and the electrocatalytic oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2175-2185. doi: 10.11862/CJIC.20240165
7. [7]
  Yulian Hu , Xin Zhou , Xiaojun Han . A Virtual Simulation Experiment on the Design and Property Analysis of CO₂ Reduction Photocatalyst. University Chemistry, 2025, 40(3): 30-35. doi: 10.12461/PKU.DXHX202403088
8. [8]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . 液相法制备硫化物固体电解质及其在全固态锂电池中的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2309019-. doi: 10.3866/PKU.WHXB202309019
9. [9]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
10. [10]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
11. [11]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409
12. [12]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
13. [13]
  Yanan Liu , Yufei He , Dianqing Li . Preparation of Highly Dispersed LDHs-based Catalysts and Testing of Nitro Compound Reduction Performance: A Comprehensive Chemical Experiment for Research Transformation. University Chemistry, 2024, 39(8): 306-313. doi: 10.3866/PKU.DXHX202401081
14. [14]
  Xue Dong , Xiaofu Sun , Shuaiqiang Jia , Shitao Han , Dawei Zhou , Ting Yao , Min Wang , Minghui Fang , Haihong Wu , Buxing Han . 碳修饰的铜催化剂实现安培级电流电化学还原CO₂制C₂₊产物. Acta Physico-Chimica Sinica, 2025, 41(3): 2404012-. doi: 10.3866/PKU.WHXB202404012
15. [15]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
16. [16]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
17. [17]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004
18. [18]
  Pengzi Wang , Wenjing Xiao , Jiarong Chen . Copper-Catalyzed C―O Bond Formation by Kharasch-Sosnovsky-Type Reaction. University Chemistry, 2025, 40(4): 239-244. doi: 10.12461/PKU.DXHX202406090
19. [19]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
20. [20]
  Xuejie Wang , Guoqing Cui , Congkai Wang , Yang Yang , Guiyuan Jiang , Chunming Xu . 碳基催化剂催化有机液体氢载体脱氢研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-. doi: 10.1016/j.actphy.2024.100044

Get Citation

PDF

XML

Metrics

PDF Downloads(32)
Abstract views(1885)
HTML views(761)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Catalytic Performance of Co-Co9S8/N-Doped Ketjen Black Composite for Oxygen Reduction Reaction

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Catalytic Performance of Co-Co₉S₈/N-Doped Ketjen Black Composite for Oxygen Reduction Reaction