Citation: Basharat ALI, Xiao-Lei LI, Jin-Kui TANG. Improving Energy Barrier by Altering Coordination Environment in Two Dy(Ⅲ) Single-Ion Magnets[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(8): 1519-1526. doi: 10.11862/CJIC.2021.174 shu

Improving Energy Barrier by Altering Coordination Environment in Two Dy(Ⅲ) Single-Ion Magnets

Basharat ALI ^{1, 2} ,
Xiao-Lei LI ¹ ,
Jin-Kui TANG ^{1, 2,,}

1.
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
2.
School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei 230026, China

Corresponding author: Jin-Kui TANG, tang@ciac.ac.cn
Received Date: 8 May 2021
Revised Date: 25 June 2021

Figures(6)

Altering the synthetic strategies and further tuning the magnetic dynamics of single-ion magnets (SIMs) are critical tasks for chemists. Two mononuclear Dy(Ⅲ) complexes[DyL₂(H₂O)₂]ClO₄·2H₂O·2CH₃CN·CH₃OH (1) and [DyL₂(H₂O)₂]CF₃SO₃·4H₂O·2CH₃OH (2) have been successfully synthesized by using tris(2-hydroxybenzylidene) triaminoguanidine ligand (L). Structural and magnetic investigations reveal that different counter anions play an important role in dynamic magnetic behaviors of 1 and 2. In both the complexes the Dy(Ⅲ) centers are eight-coordinated with triangular dodecahedron D_2d symmetry. They all showed single-ion magnets (SIMs) behavior under zero dc applied field with effective energy barriers (U_eff) of 358 K (1) and 309 K (2), respectively. A comparison of the structural parameters shows that the small but significant changes at axial positions in bond lengths and bond angles affect the axial ligand field which in turn is mainly responsible for distinct magnetic properties of both the complexes.
- dysprosium,
- coordination compounds,
- magnetism,
- single-molecule magnets
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