Citation: Jia-Xiang HUANG, He ZHAO, Shu-Qin LIU, Jian-Jun ZHANG. Two-Dimensional Luminescent Coordination Polymer Based on Dinuclear {Zn₂(COO)₄} Second Bulidings Units: Crystal Structure and Detection of Fe³⁺[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(8): 1513-1518. doi: 10.11862/CJIC.2021.155 shu

Two-Dimensional Luminescent Coordination Polymer Based on Dinuclear {Zn₂(COO)₄} Second Bulidings Units: Crystal Structure and Detection of Fe³⁺

School of Chemical Engineering, Dalian University of Technology, Dalian, Liaoning 116024, China

Corresponding author: Shu-Qin LIU, shuqinliu@163.com Jian-Jun ZHANG, zhangjj@dlut.edu.cn
Received Date: 27 April 2021
Revised Date: 2 June 2021

Figures(5)

A two-dimensional luminescent coordination polymer based on dinuclear {Zn₂(COO)₄} second buildings units, [Zn₂(L)₂(DMSO)₂(DMF)] (1, H₂L=2-(1, 3-dioxo-1H-benzo[de]isoquinolin-2(3H)-yl) terephthalic acid, DMSO=dimethyl sulfoxide, DMF=dimethylformamide), was synthesized by hydrothermal reaction using H₂L ligand and Zn²⁺. Topological analysis shows that the dinuclear {Zn₂(COO)₄} unit can be regarded as a 4-linked node and forms a (4, 4) net topology with L^2- linker. 1 also exhibited a selective luminescence quenching type response to Fe³⁺ with detection limit as low as 2.8 μmol·L^-1. 1 has good anti-interference ability for the detection of Fe³⁺, and can be regenerated and recycled for several times by washing with DMF solvent.
- luminescent coordination polymer,
- π-π stacking interaction,
- crystal structure,
- Fe³⁺,
- detection
1. [1]
  XU Z X, LI L F, XU S F, CHEN X T. Chinese J. Inorg. Chem. , 2020, 36(11): 2087-2092 doi: 10.11862/CJIC.2020.230
2. [2]
  GAO L L, LI M X, DU Y E, CHEN Y Q. Chinese J. Inorg. Chem. , 2020, 36(12): 2359-2366 doi: 10.11862/CJIC.2020.249
3. [3]
  Feng X, Zhao J S, Liu B, Wang L Y, Ng S, Zhang G, Wang J G, Shi X G, Liu Y Y. Cryst. Growth Des. , 2010, 10(3): 1399-1408 doi: 10.1021/cg901391y
4. [4]
  Liu R, Huang M M, Yao X X, Li H H, Yang F L, Li X L. Inorg. Chim. Acta, 2015, 434: 172-180 doi: 10.1016/j.ica.2015.05.019
5. [5]
  Niu Y W, Liu X, Zhao L, Guo Y M, Li W X, Ma M M, Li X L. Polyhedron, 2019, 157: 241-248 doi: 10.1016/j.poly.2018.10.016
6. [6]
  Li B, Fang W J, Liu S Q, Zhao H, Zhang J J. Chin. J. Struct. Chem. , 2020, 39(1): 110-117
7. [7]
  Zhao H, Ni J, Zhang J J, Liu S Q, Sun Y J, Zhou H J, Li Y Q, Duan C Y. Chem. Sci. , 2018, 9(11): 2918-2926 doi: 10.1039/C8SC00021B
8. [8]
  Singh D, Bhattacharyya P K, Baruah J B. Cryst. Growth Des. , 2010, 10(1): 348-356 doi: 10.1021/cg900938x
9. [9]
  Sheldrick G M. Acta Crystallogr. Sect. C, 2015, C71: 3-8
10. [10]
  Feng X, Feng Y Q, Liu L, Wang L Y, Song H L, Ng S W. Dalton Trans. , 2013, 42(21): 7741-7754 doi: 10.1039/c3dt33002h
11. [11]
  Xu H, Pan Z R. Chin. J. Struct. Chem. , 2019, 38(12): 2121-2128
12. [12]
  Zhan D Y, Saeed A, Li Z X, Wang C M, Yu Z W, Wang J F, Zhao N J, Xu W H, Liu J H. Dalton Trans. , 2020, 49(48): 17737-17744 doi: 10.1039/D0DT03781H
1. [1]
  Yu BAI , Jijiang WANG , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A cadmium(Ⅱ) coordination polymer based on a semirigid tetracarboxylate ligand for highly selective detection of Fe³⁺ and 4-nitrophenol. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1217-1226. doi: 10.11862/CJIC.20240457
2. [2]
  Hexing SONG , Zan SUN . Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe³⁺ of an Mn(Ⅱ) complex based on 1-naphthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 885-892. doi: 10.11862/CJIC.20240402
3. [3]
  Pingping LU , Shuguang ZHANG , Peipei ZHANG , Aiyun NI . Preparation of zinc sulfate open frameworks based probe materials and detection of Pb²⁺ and Fe³⁺ ions. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 959-968. doi: 10.11862/CJIC.20240411
4. [4]
  Huaihao CHEN , Lingwen ZHANG , Yukun CHEN , Jianjun ZHANG . A water-stable metal-organic framework probe for Al³⁺/Ga³⁺/In³⁺ detection. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2601-2608. doi: 10.11862/CJIC.20250184
5. [5]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
6. [6]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273
7. [7]
  Hongren RONG , Gexiang GAO , Zhiwei LIU , Ke ZHOU , Lixin SU , Hao HUANG , Wenlong LIU , Qi LIU . High-performance supercapacitor based on 1D cobalt-based coordination polymer. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1183-1195. doi: 10.11862/CJIC.20250034
8. [8]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
9. [9]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
10. [10]
  Jia JI , Zhaoyang GUO , Wenni LEI , Jiawei ZHENG , Haorong QIN , Jiahong YAN , Yinling HOU , Xiaoyan XIN , Wenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344
11. [11]
  Yingyue ZHANG , Liuqing KANG , Yating YANG , Xiaofen GUAN , Wenmin WANG . Crystal structure and antibacterial activity of two Gd₂ complexes based on polydentate Schiff-base ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1867-1877. doi: 10.11862/CJIC.20250100
12. [12]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
13. [13]
  Jiarong ZHU , Xiaohua ZHANG , Xinting XIONG , Xuliang NIE , Xiuying SONG , Miaomiao ZHANG , Dayong PENG , Xiuguang YI . Crystal structure, Hirshfeld surface analysis, and antifungal activity of five complexes based on 2,5-bis(carboxymethoxy)terephthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2358-2370. doi: 10.11862/CJIC.20250150
14. [14]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
15. [15]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
16. [16]
  Yukun CHEN , Kexin FENG , Bolun ZHANG , Wentao SONG , Jianjun ZHANG . Syntheses, crystal structures, and diametrically opposed mechanically-stimulated luminescence response of two Mg(Ⅱ) metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1227-1234. doi: 10.11862/CJIC.20240448
17. [17]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
18. [18]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
19. [19]
  Yan XU , Suzhi LI , Yan LI , Lushun FENG , Wentao SUN , Xinxing LI . Structure variation of cadmium naphthalene-diphosphonates with the changing rigidity of N-donor auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 395-406. doi: 10.11862/CJIC.20240226
20. [20]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(1946)
HTML views(200)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Two-Dimensional Luminescent Coordination Polymer Based on Dinuclear {Zn2(COO)4} Second Bulidings Units: Crystal Structure and Detection of Fe3+

Metrics

通讯作者: 陈斌, bchen63@163.com

Two-Dimensional Luminescent Coordination Polymer Based on Dinuclear {Zn₂(COO)₄} Second Bulidings Units: Crystal Structure and Detection of Fe³⁺