Citation: Xue ZHANG, Hong-Ji SONG, Nan MA, Jie LIU, Xing-Xing ZHANG, Zhan-Chao WU. Spectral Control of Ba_5-2x-yTb_xNa_x(PO₄)₃Cl: yEu²⁺ Phosphor Achieved by Energy Transfer[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(7): 1251-1257. doi: 10.11862/CJIC.2021.152 shu

Spectral Control of Ba_5-2x-yTb_xNa_x(PO₄)₃Cl: yEu²⁺ Phosphor Achieved by Energy Transfer

College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, Shandong 266042, China

Corresponding author: Zhan-Chao WU, wuzhan_chao@163.com
Received Date: 5 February 2021
Revised Date: 29 May 2021

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In this paper, a series of Ba_5-2x-yTb_xNa_x(PO₄)₃Cl: yEu²⁺ phosphor powder was prepared via [Na⁺, Tb³⁺] ion pairs substituting [Ba²⁺, Ba²⁺] ion pairs. The structure, morphology, composition and luminescence properties were studied through X-ray powder diffraction, scanning electron microscope, photoexcitation and emission spectroscopy. Under excitation at 354 nm, the emission spectra of Ba_3.97Tb_0.50Na_0.50(PO₄)₃Cl: 0.03Eu²⁺ sample was composed of the characteristic broad peak of Eu²⁺ at about 450 nm and the four characteristic sharp peaks of Tb³⁺ at 490, 545, 583 and 622 nm. Due to Eu²⁺→Tb³⁺ energy transfer, the luminescence intensity of Tb³⁺ in Ba_3.97Tb_0.50Na_0.50(PO₄)₃Cl: 0.03Eu²⁺ was significantly increased compared with that of Tb³⁺ in Ba_4.00Tb_0.50Na_0.50(PO₄)₃Cl sample. By changing the concentration of [Na⁺, Tb³⁺] ion pairs, the spectral control of Ba_5-2x-yTb_xNa_x(PO₄)₃Cl: yEu²⁺ phosphor was achieved. When x=0.50, the luminescence intensity of Tb³⁺ in Ba_4.97-2xTb_xNa_x(PO₄)₃Cl: 0.03Eu²⁺ reached the maximum.
- phosphor,
- chemical unit substitution,
- energy transfer,
- spectral control
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Spectral Control of Ba5-2x-yTbxNax(PO4)3Cl: yEu2+ Phosphor Achieved by Energy Transfer

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通讯作者: 陈斌, bchen63@163.com

Spectral Control of Ba_5-2x-yTb_xNa_x(PO₄)₃Cl: yEu²⁺ Phosphor Achieved by Energy Transfer