Citation: Qian ZHANG, Yue-Li WEN, Bin WANG, He-Ming FAN, Chen YANG, Rong-Peng SONG, Wei-Zhong ZHANG, Wei HUANG. Effect of Component Control of Catalysts with Dual Ligand CuFe@MOFs as Precursor on Performance of CO₂ Hydrogenation to C₂₊ Alcohol[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(8): 1390-1398. doi: 10.11862/CJIC.2021.148 shu

Effect of Component Control of Catalysts with Dual Ligand CuFe@MOFs as Precursor on Performance of CO₂ Hydrogenation to C₂₊ Alcohol

Qian ZHANG ¹ ,
Yue-Li WEN ^1,, ,
Bin WANG ² ,
He-Ming FAN ¹ ,
Chen YANG ¹ ,
Rong-Peng SONG ¹ ,
Wei-Zhong ZHANG ¹ ,
Wei HUANG ^{2, 3,,}

1.
College of Environmental Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China
2.
State Key Laboratory of Clean and Efficient Coal Utilization, Taiyuan 030024, China
3.
Shanxi Taiyuan Coal Conversion Technology Engineering Co., Ltd., Taiyuan 030024, China

Corresponding author: Yue-Li WEN, wenyueli@tyut.edu.cn Wei HUANG, huangwei@tyut.edu.cn
Received Date: 28 January 2021
Revised Date: 25 April 2021

Figures(7)

CuFe@MOFs derived catalysts were synthesized by introducing a second ligand, p-aminobenzoic acid, in the hydrothermal synthesis of MIL-88B(Fe), which was followed by impregnation with Cu species. The physicochemical properties of the catalysts were characterized by X-ray diffraction (XRD), H₂-temperature programmed reduction (H₂-TPR), N₂ adsorption-desorption, scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The catalytic performance of the catalysts for hydrogenation of CO₂ to C₂₊ alcohol (C₂₊OH) was tested in a fixed bed reactor. The results show that the elements of active components were evenly dispersed, and the active species distribution on the catalyst surface can be controlled by adjusting the molar ratio of two ligands (terephthalic acid to p-aminobenzoic acid ligands) in the raw materials. When the molar ratio of terephthalic acid to p-aminobenzoic acid was 5:2, the proportion of low-valence iron of the as-obtained catalyst was the highest (71.27%). Accordingly, this catalyst showed the best performance for CO₂ hydrogenation to C₂₊OH, that the conversion of CO₂ was 8.80%, the selectivity of total alcohol (ROH) was 31.52% and the molar fraction of C₂₊OH was 94.70%. This might be due to the high proportion of low-valence iron species and the well-dispersed active components.
- dual ligand,
- CuFe@MOFs,
- composition control,
- carbon dioxide,
- hydrogenation,
- C₂₊,
- alcohol
1. [1]
  Wang L X, Guan E J, Wang Y Q, Wang L, Gong Z M, Cui Y, Meng X J, Gates B C, Xiao F S. Nat. Commun. , 2020, 11(1): 1033-1042 doi: 10.1038/s41467-020-14817-9
2. [2]
  Xu D, Ding M Y, Hong X L, Liu G L, Tsang S C E. ACS Catal. , 2020, 10(9): 5250-5260 doi: 10.1021/acscatal.0c01184
3. [3]
  JIA C X, SHAO J A, BAI X W, XIAO J J, YANG H P, CHEN H P. Chemical Industry and Engineering Progress, 2020, 39(9): 271-281
4. [4]
  Khan M K, Butolia P, Jo H, Irshad M, Han D, Nam K W, Kim J. ACS Catal. , 2020, 10(18): 10325-10338 doi: 10.1021/acscatal.0c02611
5. [5]
  Li J C, Wang L G, Cao Y, Zhang C J, He P, Li H Q. Chin. J. Chem. Eng. , 2018, 26(11): 2266-2279 doi: 10.1016/j.cjche.2018.07.008
6. [6]
  Gao P, Zhang L N, Li S G, Zhou Z X, Sun Y H. ACS Cent. Sci. , 2020, 6(10): 1657-1670 doi: 10.1021/acscentsci.0c00976
7. [7]
  LI J, JIN B H, YUE H R, YING J K. Applied Chemical Industry, 2016, 45(11): 2005-2008
8. [8]
  Ouyang B, Xiong S, Zhang Y H, Liu B, Li J L. Appl. Catal. A, 2017, 543: 189-195 doi: 10.1016/j.apcata.2017.06.031
9. [9]
  Wang Y, Zhang J J, Qian Q L, Bediako B B A. Green Chem. , 2019, 21: 589-596 doi: 10.1039/C8GC03320J
10. [10]
  Wang P, Bai Y X, Xiao H, Tian S P, Zhang Z Z, Wu Y Q, Xie H J, Yang G H, Han Y Z, Tan Y S. Catal. Commun. , 2016, 75: 92-97 doi: 10.1016/j.catcom.2015.12.012
11. [11]
  Xiang Y, Chitry V, Liddicoat P, Felfer P, Cairmey J, Ringer S, Kruse N. J. Am. Chem. Soc. , 2013, 135(19): 7114-7117 doi: 10.1021/ja402512r
12. [12]
  He Z H, Cui M, Qian Q L, Zhang J J, Liu H Z, Han B X. Proc. Natl. Acad. Sci. U. S. A. , 2019, 116(26): 12654-12659 doi: 10.1073/pnas.1821231116
13. [13]
  Hong Z S, Cao Y, Deng J F, Fan K N. Catal. Lett. , 2002, 82(1): 37-44
14. [14]
  XIANG H, LI J, CAO J X, YANG L. Modern Chemical Industry, 2015, 35(2): 27-31
15. [15]
  FU H, ZHANG M, ZHENG H Y, LI Z. Natural Gas Chemical Industry, 2019, 44(1): 129-134
16. [16]
  Luk H T, Mondeli C, Mitchell S, Curulla F D, Stewart J A, Perez R J. J. Catal. , 2019, 371: 116-125 doi: 10.1016/j.jcat.2019.01.021
17. [17]
  JIANG X Y, RONG N X, QIU T T, QIAN R, WANG Y Z, HAO Q P, HUANG X Q. Chinese J. Inorg. Chem. , 2017, 33(12): 2303-2310 doi: 10.11862/CJIC.2017.222
18. [18]
  LIU C H, GUO X M, ZHONG C L, LI L, HUA Y X, MAO D S, LU G Z. Chinese J. Inorg. Chem. , 2016, 32(8): 1405-1412
19. [19]
  XIN L L, SUN Q, YANG L Y, LI C, MA J F. Tianjin Agricultural Sciences, 2019, 25(4): 80-85
20. [20]
  Shi X P, Yu H B, Gao S, Li X Y, Fang H H, Li R J, Li Y Y, Zhang L J, Liang X L, Yuan Y Z. Fuel, 2017, 20(1): 241-248
21. [21]
  Natesakhawat S, Ohodnicki P J, Howard B, Lekse J, Baltrus J, Mayranga C. Top. Catal. , 2013, 56: 1752-1763 doi: 10.1007/s11244-013-0111-5
22. [22]
  Francielle C F M, Jose M A, Elisabete M A. Mol. Catal. , 2017, 458: 297-306
23. [23]
  Gao W, Zhao Y F, Liu J M, Huang Q W, He S, Li C M, Zhao J W, Wei M. Catal. Sci. Technol. , 2013, 3(5): 1324-1332 doi: 10.1039/c3cy00025g
24. [24]
  Ding J, Zhao W X, Zi L T, Xu X, Liu Q, Zhong Q, Xu Y. Int. J. Hydrogen Energy, 2020, 45(30): 15254-15262 doi: 10.1016/j.ijhydene.2020.03.249
25. [25]
  Liu J H, Zhang G H, Jiang X, Wang J H, Song C S, Guo X W. Catal. Today, 2020, 371(SI): 162-170
26. [26]
  Yu H, Fang C Y, Ji X W, Wei J, Ge Q J, Sun J. ACS Catal. , 2020, 10(20): 12098-12108 doi: 10.1021/acscatal.0c03215
27. [27]
  Reddy G K, Boolchand P, Smirniotis P G. J. Phys. Chem. C, 2012, 116(20): 11019-11031 doi: 10.1021/jp301090d
28. [28]
  Turu Y, Peter H. Appl. Surf. Sci. , 2008, 254: 2441-2449 doi: 10.1016/j.apsusc.2007.09.063
29. [29]
  Shi J J, Hu X M, Madsen M R, Lamagni P, Bjerglund E T, Pedersen S U, Skrydstrup T, Daasbjerg K. ACS Appl. Nano Mater. , 2018, 1(7): 3608-3615 doi: 10.1021/acsanm.8b00755
30. [30]
  Yang C, Zhao H B, Hou Y L, Ma D. J. Am. Chem. Soc. , 2012, 134(38): 15814-15821 doi: 10.1021/ja305048p
31. [31]
  Ramirez A, Gevers L, Bavykina A, Ould-chikh S, Gascon J. ACS Catal. , 2018, 8(10): 9174-9182 doi: 10.1021/acscatal.8b02892
32. [32]
  ZHANG W Z, WEN Y L, SONG R P, WANG B, ZANG Q, HUANG W. Chem. J. Chinese Universities, 2020, 41(6): 1297-1305
33. [33]
  Shigenori U, Hiroaki H, Yoshiyuki H, Hirofumi K, Kunimitsu T, Hideki S, Masahiko A, Masako Y, Sumio I, Kastumi K. J. Phys. Chem. C, 2007, 111(15): 5572-5575 doi: 10.1021/jp071273k
34. [34]
  Mukasyan A S, Roslyakov S, Pauls J M, Gallington L C, Orlova C, Liu X Y, Dobrowolska M, Furdyna J K, Manukyan K V. Inorg. Chem. , 2019, 58(9): 5583-5592 doi: 10.1021/acs.inorgchem.8b03553
35. [35]
  Pan F P, Zhang H G, Liu K X, Cullen D, More K, Wang M Y, Feng Z X, Wang G F, Wu G, Li Y. ACS Catal. , 2018, 8(4): 3116-3122 doi: 10.1021/acscatal.8b00398
36. [36]
  Chang K, Zhang H C, Chen J G, Lu Q, Cheng M J. ACS Catal. , 2019, 9(9): 8197-8207 doi: 10.1021/acscatal.9b01318
37. [37]
  An B, Cheng K, Wang C, Wang Y, Lin W B. ACS Catal. , 2016, 6(6): 3610-3618 doi: 10.1021/acscatal.6b00464
38. [38]
  Zhang M H, Ren J, Yu Y Z. ACS Catal. , 2020, 10(1): 689-701 doi: 10.1021/acscatal.9b03639
39. [39]
  GUO W, GAO W G, WANG H, TIAN J J, HAN C, QIN Z Q. Materials Review, 2013, 27(20): 44-47
40. [40]
  Li S G, Guo H J, Luo C R, Zhang H R, Xiong L, Chen X D, Ma L L. Catal. Lett. , 2013, 143(4): 345-355 doi: 10.1007/s10562-013-0977-7
41. [41]
  Xu D, Ding M Y, Hong X L, Liu G L. ACS Catal. , 2020, 10(24): 14516-14526 doi: 10.1021/acscatal.0c03575
1. [1]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004
2. [2]
  Aili Feng , Xin Lu , Peng Liu , Dongju Zhang . Computational Chemistry Study of Acid-Catalyzed Esterification Reactions between Carboxylic Acids and Alcohols. University Chemistry, 2025, 40(3): 92-99. doi: 10.12461/PKU.DXHX202405072
3. [3]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
4. [4]
  Yueguang Chen , Wenqiang Sun . “Carbon” Adventures. University Chemistry, 2024, 39(9): 248-253. doi: 10.3866/PKU.DXHX202308074
5. [5]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
6. [6]
  Jie ZHAO , Huili ZHANG , Xiaoqing LU , Zhaojie WANG . Theoretical calculations of CO₂ capture and separation by functional groups modified 2D covalent organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 275-283. doi: 10.11862/CJIC.20240213
7. [7]
  Wei HE , Jing XI , Tianpei HE , Na CHEN , Quan YUAN . Application of solar-driven inorganic semiconductor-microbe hybrids in carbon dioxide fixation and biomanufacturing. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 35-44. doi: 10.11862/CJIC.20240364
8. [8]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . 软模板法诱导Cu/Al₂O₃深孔道结构促进等离子催化CO₂加氢制二甲醚. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-. doi: 10.1016/j.actphy.2025.100054
9. [9]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
10. [10]
  Rui HUANG , Shengjie LIU , Qingyuan WU , Nanfeng ZHENG . Enhanced selectivity of catalytic hydrogenation of halogenated nitroaromatics by interfacial effects. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 201-212. doi: 10.11862/CJIC.20240356
11. [11]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
12. [12]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
13. [13]
  Xinhao Yan , Guoliang Hu , Ruixi Chen , Hongyu Liu , Qizhi Yao , Jiao Li , Lingling Li . Polyethylene Glycol-Ammonium Sulfate-Nitroso R Salt System for the Separation of Cobalt (II). University Chemistry, 2024, 39(6): 287-294. doi: 10.3866/PKU.DXHX202310073
14. [14]
  Yifeng TAN , Ping CAO , Kai MA , Jingtong LI , Yuheng WANG . Synthesis of pentaerythritol tetra(2-ethylthylhexoate) catalyzed by h-MoO₃/SiO₂. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2155-2162. doi: 10.11862/CJIC.20240147
15. [15]
  Zijuan LI , Xuan LÜ , Jiaojiao CHEN , Haiyang ZHAO , Shuo SUN , Zhiwu ZHANG , Jianlong ZHANG , Yanling MA , Jie LI , Zixian FENG , Jiahui LIU . Synthesis of visual fluorescence emission CdSe nanocrystals based on ligand regulation. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 308-320. doi: 10.11862/CJIC.20240138
16. [16]
  Xue Dong , Xiaofu Sun , Shuaiqiang Jia , Shitao Han , Dawei Zhou , Ting Yao , Min Wang , Minghui Fang , Haihong Wu , Buxing Han . 碳修饰的铜催化剂实现安培级电流电化学还原CO₂制C₂₊产物. Acta Physico-Chimica Sinica, 2025, 41(3): 2404012-. doi: 10.3866/PKU.WHXB202404012
17. [17]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
18. [18]
  Zhuoming Liang , Ming Chen , Zhiwen Zheng , Kai Chen . Multidimensional Studies on Ketone-Enol Tautomerism of 1,3-Diketones By ¹H NMR. University Chemistry, 2024, 39(7): 361-367. doi: 10.3866/PKU.DXHX202311029
19. [19]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
20. [20]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271

Get Citation

PDF

XML

Metrics

PDF Downloads(12)
Abstract views(1275)
HTML views(280)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effect of Component Control of Catalysts with Dual Ligand CuFe@MOFs as Precursor on Performance of CO2 Hydrogenation to C2+ Alcohol

Metrics

通讯作者: 陈斌, bchen63@163.com

Effect of Component Control of Catalysts with Dual Ligand CuFe@MOFs as Precursor on Performance of CO₂ Hydrogenation to C₂₊ Alcohol