Citation: Jie LEI, Tao-Xiang WANG, Zhi LI, Hui CHEN, Song YANG, Hai-Bo HAN, Kang LI. Synthesis of Multi-stage Pore Carbon Material with Large Spacing of Carbon Layers from Asphalt for Supercapacitors[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(7): 1218-1226. doi: 10.11862/CJIC.2021.126 shu

Synthesis of Multi-stage Pore Carbon Material with Large Spacing of Carbon Layers from Asphalt for Supercapacitors

Jie LEI ¹ ,
Tao-Xiang WANG ¹ ,
Zhi LI ¹ ,
Hui CHEN ² ,
Song YANG ³ ,
Hai-Bo HAN ¹ ,
Kang LI ^1,,

1.
Luoyang R & D Center of Technology of SINOPEC Engineering(Group) Co. Ltd., Luoyang, Henan 471003, China
2.
China Petroleum & Chemical Corporation, Beijing 100027, China
3.
China University of Petroleum(Beijing), Beijing 102249, China

Corresponding author: Kang LI, likang.segr@sinopec.com
Received Date: 3 February 2021
Revised Date: 23 April 2021

Figures(7)

Based on the nanoscale lamellar porous MgO as template, a facile method of petroleum pitch via in-situ KOH activation was designed to obtain multi-stage pore carbon material with large spacing or carbon layers. Meanwhile, the effect of the amount of template on the physicochemical and chemical properties of porous carbon materials, such as pore distribution, carbon layer spacing and electrochemical properties were investigated. The results showed that the specific surface area and pore volume of the carbon material were 2 634 m²·g^-1, 1.12 cm³·g^-1 respectively. What's more, the spacing of carbon layers was 0.374 nm, when the dosage of template was 25% of the quality of asphalt. As electrodes for supercapacitors, 338 F·g^-1 at 1 A·g^-1, 277 F·g^-1 at 20 A·g^-1, and superior cycle stability with 93.5% capacitance retention at 1 A·g^-1 after 10 000 cycles in 6 mol·L^-1 KOH electrolyte, demonstrating excellent electrochemical performance.
- template method,
- spacing of carbon layers,
- lamellar porous MgO,
- specific capacity,
- supercapacitor
1. [1]
  Wang Y G, Song Y F, Xia Y Y. Chem. Soc. Rev. , 2016, 45: 5925-5950 doi: 10.1039/C5CS00580A
2. [2]
  Miller J R. J. Power Sources, 2016, 326: 726-735 doi: 10.1016/j.jpowsour.2016.04.020
3. [3]
  Beguin F, Presser V, Balducci A, Frackowiak E. Adv. Mater. , 2014, 26: 2219-2251 doi: 10.1002/adma.201304137
4. [4]
  Wang G P, Zhang L, Zhang J J. Chem. Soc. Rev. , 2012, 41: 797-828 doi: 10.1039/C1CS15060J
5. [5]
  Gu J, Zhang H F, He X J, Yu M X, Wang X T, Xiao N, Qiu J S. J. Porous Mater. , 2020, 27: 487-494 doi: 10.1007/s10934-019-00831-w
6. [6]
  Chang J L, Gao Z Y, Wang X R, Wu D P, Xu F, Wang X, Guo Y M, Jiang K. Electrochim. Acta, 2015, 157: 290-298 doi: 10.1016/j.electacta.2014.12.169
7. [7]
  Jin Z, Yan X D, Yu Y H, Zhao G J. J. Mater. Chem. A, 2014, 2: 11706-11715 doi: 10.1039/C4TA01413H
8. [8]
  Wang Z Q, Wu Z Q, Di Benedetto G, Zunino J L, Mitra S. Carbon, 2015, 91: 103-113 doi: 10.1016/j.carbon.2015.04.045
9. [9]
  Yang H, Kannappan S, Panduab A S, Jang J H, Lee Y S, Lu W. J. Power Sources, 2015, 284: 146-153 doi: 10.1016/j.jpowsour.2015.03.015
10. [10]
  Pan L, Li X X, Wang Y X, Liu J L, Tian W, Ning H, Wu M B. Appl. Surf. Sci. , 2018, 444: 739-746 doi: 10.1016/j.apsusc.2018.03.122
11. [11]
  Yang X Y, Chen L H, Li Y, Rooke J C, Sanchez C, Su B L. Chem. Soc. Rev. , 2017, 46: 481-558 doi: 10.1039/C6CS00829A
12. [12]
  Enayat S, Tran M K, Salpekar D, Kabbani M A, Babu G, Ajayan P M, Vargas F M. Fuel, 2020, 263: 116641 doi: 10.1016/j.fuel.2019.116641
13. [13]
  Wang L X, Wang R R, Zhao H Y, Liu L, Jia D Z. Mater. Lett. , 2015, 149: 85-88 doi: 10.1016/j.matlet.2014.11.051
14. [14]
  Guan L, Pan L, Peng T Y, Qian T, Huang Y C, Li X X, Gao C, Li Z, Hu H, Wu M B. Carbon, 2019, 152: 537-544 doi: 10.1016/j.carbon.2019.06.059
15. [15]
  Pan L, Wang Y X, Hu H, Li X X, Liu J L, Guan L, Tian W, Wang X B, Li Y P, Wu M B. Carbon, 2018, 134: 345-353 doi: 10.1016/j.carbon.2018.04.008
16. [16]
  Abudu P, Wang L, Xu M, Jia D, Wang X, Jia L. Chem. Phys. Lett. , 2018, 702: 1-7 doi: 10.1016/j.cplett.2018.04.055
17. [17]
  Tang H L, Zeng Y, Gao X, Yao B, Liu D, Wu J B, Qu D Y, Liu K, Xie Z Z, Zhang H N, Pan M, Huang L, Jiang S P. Electrochim. Acta, 2016, 194: 143-150 doi: 10.1016/j.electacta.2016.02.111
18. [18]
  Ruzi-Rosas R, Valero-Romero M J, Salinas-Torres D, Rodriguez-Mirasol J, Cordero T, Morallon E, Cazorla-Amoros D. ChemSusChem, 2014, 7: 1458-1467 doi: 10.1002/cssc.201301408
19. [19]
  Wang X F, Chen M M, Matsumura K, Toyoda M, Wang C Y. RSC Adv. , 2016, 6(102): 100546-100553 doi: 10.1039/C6RA20389B
20. [20]
  Shao J Q, Ma F W, Wu G, Dai C C, Geng W D, Song S J, Wan J F. Chem. Eng. J. , 2017, 321: 301-313 doi: 10.1016/j.cej.2017.03.092
21. [21]
  He X J, Liu Z D, Ma H, Zhang N, Yu M X, Wu M B. Microporous Mesoporous Mater. , 2016, 236: 134-140 doi: 10.1016/j.micromeso.2016.08.045
22. [22]
  He X J, Li X J, Wang J X, Ma H, Zhang H, Xie Y Y, Xiao N, Qiu J S. Microporous Mesoporous Mater. , 2017, 245: 73-81 doi: 10.1016/j.micromeso.2017.02.078
23. [23]
  Wang X F, Chen M M, Matsumura K, Toyoda M, Wang C Y. RSC Adv. , 2016, 6: 100546-100553 doi: 10.1039/C6RA20389B
24. [24]
  Wu M B, Zhang Q F, Qiu J S, Guo Y S, Shang H Y, Yuan A J. Carbon, 2004, 42: 205-210 doi: 10.1016/j.carbon.2003.10.025
25. [25]
  Wei F, He X J, Zhang H F, Liu Z D, Xiao N, Qiu J S. J. Power Sources, 2019, 428: 8-12 doi: 10.1016/j.jpowsour.2019.04.096
26. [26]
  Zhao Y Q, Lu M, Tao P Y, Zhang Y J, Gong X T, Yang Z, Zhang G Q, Li H L. J. Power Sources, 2016, 307: 391-400 doi: 10.1016/j.jpowsour.2016.01.020
27. [27]
  Dong X M, Jin H L, Wang R Y, Zhang J J. Adv. Energy Mater. , 2018, 8: 1702695 doi: 10.1002/aenm.201702695
28. [28]
  Alhumaidan F S, Hauser A, Rana M S, Lababidi H M S, Behbehani M. Fuel, 2015, 150: 558-564 doi: 10.1016/j.fuel.2015.02.076
29. [29]
  Yen T F, Erdman J G, Pollack S S. Anal. Chem. , 1961, 33: 1587-1594 doi: 10.1021/ac60179a039
30. [30]
  Geng W D, Ma F W, Wu G, Song S J, Wan J F, Ma D. Electrochim. Acta, 2016, 10: 854-863
31. [31]
  Liu S M, Liang Y R, Zhou W, Hu W Q, Dong H W, Zheng M T, Hu H, Lei B F, Xiao Y, Liu Y L. J. Mater. Chem. A, 2018, 6: 12046-12055 doi: 10.1039/C8TA02838A
32. [32]
  Zhang Y T, Zhang K B, Ren S Z, Jia K L, Dang Y Q, Liu G Y, Li K, Long X Y, Qiu J S. J. Alloys Compd. , 2019, 792: 828-834 doi: 10.1016/j.jallcom.2019.04.011
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