Citation: Si-Cheng WAN, Bing-Qing XIONG, Yuan-Yuan PAN, Chang-Ding QIU, Fu-Sheng KE. Cu-Porphyrin Based Metal Organic Frameworks for High-Performance Lithium-Sulfur Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(9): 1642-1648. doi: 10.11862/CJIC.2021.125 shu

Cu-Porphyrin Based Metal Organic Frameworks for High-Performance Lithium-Sulfur Batteries

College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China

Corresponding author: Fu-Sheng KE, kefs@whu.edu.cn
Received Date: 19 March 2021
Revised Date: 13 April 2021

Figures(6)

Copper ions can be coordinated into porphyrin ligands of PCN-222 directly to form PCN-222-Cu, which is first used for lithium-sulfur batteries in this study. The crystal structure, morphology and electrochemical properties were characterized systematically by ultraviolet-visible (UV-Vis) spectra, powder X-ray diffraction (PXRD), N₂ adsorption-desorption test, scanning electron microscope (SEM), cyclic voltammetry (CV) and galvanostatic charge-discharge test. UV-Vis spectra indicate Cu²⁺ was successfully coordinated into the porphyrin. The electrochemical test results showed that the reversible specific capacity of S-in-PCN-222-Cu electrodes could maintain 840 mAh·g^-1 after 300 cycles at 1C. When the rate was increased to 3C, S-in-PCN-222-Cu electrode could still maintain a high reversible specific capacity of 430 mAh·g^-1 after 800 cycles, and the capacity decay rate was only 0.042% per cycle, which was much better than that of S-in-PCN-222 electrode. This result indicates that the synergistic effect of Cu²⁺ and N atoms in the porphyrin rings can effectively decrease the electrochemical polarization, thus significantly improve the electrochemical performance and cycling stability of the porphyrin-based metal-organic framework as sulfur hosts.
- metal-organic framework,
- porphyrin ligand,
- Cu²⁺,
- lithium-sulfur battery
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