Citation: Lu LIU, Ping-Ning JIN, Jie YANG, Li-Xing SONG, Bo ZHAO, Jin-Ke LI, Bin HUANG, Yu-Ping ZHANG, Xiao-Xun YANG. Structure and Fluorescence Properties of Three 1D/2D/3D Zn(Ⅱ)/Co(Ⅱ) Complexes Based on Flexible Tetracarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(5): 921-928. doi: 10.11862/CJIC.2021.101 shu

Structure and Fluorescence Properties of Three 1D/2D/3D Zn(Ⅱ)/Co(Ⅱ) Complexes Based on Flexible Tetracarboxylic Acid

Lu LIU ¹ ,
Ping-Ning JIN ² ,
Jie YANG ³ ,
Li-Xing SONG ¹ ,
Bo ZHAO ¹ ,
Jin-Ke LI ¹ ,
Bin HUANG ¹ ,
Yu-Ping ZHANG ¹ ,
Xiao-Xun YANG ^1,,

1.
School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang, Henan 453003, China
2.
Department of Basic Medical Science, Xinxiang Medical University, Xinxiang, Henan 453000, China
3.
Anyang Vocational and Technical College, Anyang, Henan 455008, China

Corresponding author: Xiao-Xun YANG, liululiulu2012@126.com
Received Date: 16 October 2020
Revised Date: 11 January 2021

Figures(6)

Three complexes, namely {[Zn(H₂L) (H₂O)₃]·H₂O·0.5H₄L}_n (1), {[Co(L)_0.5(4, 4'-bpy)]·0.5H₂O}_n (2) and {[Co(L)_0.5(pbmb)(H₂O)]·H₂O}_n (3) (H₄L=5, 5'-(hexane-1, 6-diyl)-bis(oxy)diisophthalic acid, 4, 4'-bpy=4, 4'-bipyridine, pbmb=1, 1'-(1, 3-propane)bis-(2-methylbenzimidazole)), have been prepared by solvo-/hydrothermal reactions. Complex 1 belongs to a 1D chain structure. Complex 2 presents a 3D 3-fold interpenetrating framework with the Schläfli symbol (6⁴·7·8)(6·7²). Complex 3 features a (3, 4)-connected 2D network with the Schläfli symbol (4·6²) (4²·6²·8²). Complex 1 exhibited better fluorescence properties. CCDC: 1968748, 1; 1968750, 2; 1968751, 3.
- Zn(Ⅱ),
- Co(Ⅱ),
- crystal structure,
- topology,
- fluorescence
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沈阳化工大学材料科学与工程学院沈阳 110142